Mechanical Performance of Fiber Reinforced Cement Composites Including Fully-Recycled Plastic Fibers

The use of virgin and recycled plastic macro fibers as reinforcing elements in construction materials has recently gained increasing attention from researchers. Specifically, recycled fibers have become more attractive owing to their large-scale availability, negligible cost, and low environmental footprint. In this work, we investigate the benefits related to the use of fully-recycled synthetic fibers as dispersed reinforcement in Fiber Reinforced Cement Composites (FRCCs). In light of the reference performance of FRCCs including virgin polypropylene (PP) fibers only, the mechanical response of composites reinforced with polyolefin filaments treated with a sol-gel silica coating and polyethylene terephthalate (PET)/polyethylene (PE) cylindrical draw-wire fibers is here assessed through three-point bending tests. Remarkably, recycled polyolefins lead to a notable enhancement in terms of peak strength and post-crack energy dissipation capability. This improvement is ascribed to both the flattened shape of fibers and the surface coating, which turns out to be very effective at strengthening the fiber-to-matrix bond. On the other hand, PET/PE fibrous reinforcement generally leads to a lower toughness, if compared to the virgin fibers. However, no reduction in terms of peak stress is evidenced. Balancing the significance of mechanical performance and environmental sustainability in the framework of a circular economy approach, both fully-recycled fibers at hand can be regarded as promising candidates for innovative structural application

Mineral-bonded composites for enhanced structural impact safety: The vision of the DFG GRK 2250

Existing reinforced concrete structures feature, as a rule, a relatively low resistance to various sorts of impact loading, such as shock, collision, or explosion. To this aim, the primary goal of the Research Training Group (in German: Graduiertenkolleg, GRK) 2250, funded by the Deutsche Forschungsgemeinschaft (DFG), is to bring substantial improvements in the impact resistance of existing buildings by applying thin layers of strengthening material. By using innovative mineralbonded composites, public safety and reliability of vitally important existing structures and infrastructure should be significantly enhanced. The scientific basis to be developed will additionally enable to build new, impact-resistant structures economically and ecologically. The framework of the GRK 2250 as well as some achievements are herein briefly presented

On the effect of curing time and environmental exposure on impregnated Carbon Fabric Reinforced Cementitious Matrix (CFRCM) composite with design considerations

This paper investigates the effect of curing time and aggressive environmental exposure on the mechanical performance of impregnated Carbon Fabric Reinforced Cementitious Matrix (CFRCM) composite. Following the recently published IIC-ES AC434 guidelines, saltwater, distilled water, alkali and acid resistance are investigated together with freeze-thaw cycles. Mechanical characterization is based on tensile uni-axial tests under deformation control of rectangular-base prismatic specimens. 28- and 60-day curing times are considered for the control environment as well as for saltwater and alkali resistance. Deformation is monitored via digital acquisition. Besides uni-axial tests, experimental results comprise optical and scanning electron microscopy, crack pattern analysis and failure mechanism assessment. Focus is set on the determination of the design limits for the composite system at failure for the tested environments and curing times. In particular, a comparison is drawn with established design criteria already coded for FRP systems, which introduce the concept of safety (or partial) factors. Environmental conversion factors are also defined and calculated on a statistical basis in a twofold manner, as a mean to determine the design strain and strength limits of exposed specimens from the control (unexposed) data. It is found that they provide a convenient method for assessing the composite vulnerability to the aggressive environments at different curing times

Durability of fibre-reinforced cementitious composites (FRCC) including recycled synthetic fibres and rubber aggregates

We discuss mechanical performance of fibre-reinforced cementitious composites under exposure to four aggressive environments, namely alkaline, saline, sulphuric acid and distilled water immersion. A standard commercial Portland cement based matrix is considered alongside its lightweight modification wherein quarzitic sand is partially replaced by recycled rubber crumbs. Also, virgin polypropylene fibres are contrasted to PP+PET blended fibres where the PET fraction is obtained from recycling food packaging waste. Performance is assessed in bending as well as in compression. We find that recycled based specimens perform surprisingly well and that exposure to the aggressive environments mainly affects the matrix and it is not necessarily more detrimental to the lightweight partially recycled phase. A one-way analysis of variance (ANOVA) confirms the statistical significance of the results, which fully support the idea that the adoption of a substantial recycled fraction in construction materials still allows for high performance and durability standards

Mineral-bonded composites for enhanced structural impact safety: The vision of the DFG GRK 2250

Existing reinforced concrete structures feature, as a rule, a relatively low resistance to various sorts of impact loading, such as shock, collision, or explosion. To this aim, the primary goal of the Research Training Group (in German: Graduiertenkolleg, GRK) 2250, funded by the Deutsche Forschungsgemeinschaft (DFG), is to bring substantial improvements in the impact resistance of existing buildings by applying thin layers of strengthening material. By using innovative mineralbonded composites, public safety and reliability of vitally important existing structures and infrastructure should be significantly enhanced. The scientific basis to be developed will additionally enable to build new, impact-resistant structures economically and ecologically. The framework of the GRK 2250 as well as some achievements are herein briefly presented

Mechanical performance and crack pattern analysis of aged Carbon Fabric Cementitious Matrix (CFRCM) composites

We discuss the effect of environmental exposure on mechanical performance of impregnated Carbon Fabric Reinforced Cementitious Matrix (CFRCM) composite. Following the recently published ICC-ES AC434 guidelines, mechanical performance of prismatic composite specimens is determined on the basis of tensile uni-axial tests. Exposure to saline and alkaline aqueous solutions is considered at 28- as well as 60-day curing time. Special emphasis is placed on crack pattern evaluation as a mean to gain better insight into matrix/fabric bond quality. To this aim, the evolution of the average crack spacing and of the average crack width is determined as a function of strain for all test environments and curing times. It is found that curing time plays a significant role in mitigating the detrimental effect of aggressive environments. Furthermore, the average crack spacing provides a very reliable measure of matrix/fabric bond degradation at all test stages

Lime-cement textile reinforced mortar (TRM) with modified interphase

Background: Lack of interphase compatibility between the fabric and the matrix significantly impairs the load-bearing capacity of textile reinforced mortar (TRM). In this study, we consider the application of two inorganic surface coatings for enhancing the interphase bond properties. Methods: Either of two silica-based coatings, namely nano- and micro-silica, were applied to alkali-resistant glass (ARG) and to hybrid carbon–ARG woven fabric. Mechanical performance of TRM reinforced with the uncoated and the coated fabric was compared in uniaxial tensile tests. Results: Mechanical testing provides evidence of a remarkable enhancement in terms of ultimate strength and deformability for the coated specimens. This effect can be ascribed to the improved hydrophilicity of the fibers’ surface and to the activation of pozzolanic reaction at the interphase. In addition, penetration of nano- and microparticles in the bundle of the textile yarns reduces the occurrence of telescopic failure

Mechanical performance of epoxy coated AR-glass fabric Textile Reinforced Mortar: Influence of coating thickness and formulation

The mechanical performance of epoxy coated AR-glass fabric reinforced composite is investigated. A three-stage manufacturing process is considered, which involves fabric surface functionalization, liquid coating deposition and long-term setting and finally fabric embedment in the mortar matrix. Two epoxy coatings are considered, which only differ by the hardening agent. However, coating thickness is significantly diverse as a result of modified viscosity during liquid deposition. Performance is assessed in uni-axial tension as well as in three-point bending and it is expressed in terms of strength curves, data dispersion, crack pattern and failure mechanism. Remarkably, despite being very similar, the analyzed coatings produce a significantly different performance, especially when data dispersion is incorporated and design limits are considered. Indeed, although both coatings are able to consistently deliver fabric rupture at failure, only the thinnest is associated with small data scattering and an almost plastic post-peak behavior in bending. The associated design elongation limit reaches the maximum allowed value according to the ICC guidelines. In fact, it appears that coating thickness plays a crucial role in determining mechanical performance and fabric flexibility. The proposed manufacturing process proves extremely effective at enhancing matrix-to-fabric adhesion and thereby prevent telescopic failure

Performance of concrete reinforced with synthetic fibres obtained from recycling end-of-life sport pitches

Micro-plastics pollution has risen at an alarming pace over the last decades and it is now recognised as a leading environmental emergency. Indeed, only a very small fraction of annual plastic production is successfully reused, while the vast majority is either disposed of (mainly through incineration or landfilling) or dispersed into the environment. In this paper, polyolefins synthetic fibres, obtained from processing disposed artificial turf pitches aimed at paving sport facilities, are studied. Focus is set on assessing their potential for the Fibre Reinforced Concrete (FRC) technology. Mechanical performance is discussed at two fibre volume fractions, namely 3% and 5% vol., alongside environmental impact. The former is assessed in bending and reveals a significant enhancement of the post-crack energy dissipation capability, whose extent is compatible with what is usually obtained by the adoption of virgin fibres. This is especially significant in consideration of the light processing operated on the waste material. Indeed, life cycle assessment is adopted to evaluate the environmental impact of fibre reuse against fibre manufacturing from either virgin materials or plastic waste. It clearly appears that fibre reuse brings a double environmental benefit: on the one side, it decreases the need for new plastics and, on the other, it reduces plastic waste, whose traditional disposal technique, through incineration, entails a considerable footprint

Pro-Atherogenic and Pro-Oxidant Diets Influence Semen and Blood Traits of Rabbit Bucks

: Many dietary factors can affect sperm traits. We compared the effect of diets rich in pro-oxidant (flaxseed oil) and pro-atherogenic (coconut oil) substances without added antioxidants on semen traits, using the rabbit as an animal model. Thirty rabbit bucks (8 months old) were fed three diets for 150 days: CNT (control) a standard diet; HA (high-atherogenic) standard diet + 3% coconut oil, and HO (high-oxidizing) standard diet + 3% flaxseed oil. Semen samples were collected weekly for the evaluation of qualitative traits (kinetics, viability) and the oxidative damage (MDA and cytokines). Blood was collected at the start (T0) and end (T8) of the experimental period for the assessment of the oxidative damage (MDA and isoprostanoids), lipid profile, and testosterone. A worsening of sperm kinetics and viability was recorded in the HA group. Lipid oxidation in seminal plasma, as well as isoprostanoids in blood (F3-IsoPs and F4-NeuroPs), increased in both the HO and HA groups. A high level of TNF-α, a marker of inflammatory status, was recorded in the seminal plasma of the HA group. The resulting outcomes were mainly attributable to the different fatty acid profiles (SFA vs. PUFA) of the diets, which modulated an inflammatory/oxidative response