How to minimize the environmental contamination caused by hydrocarbon releases by onshore pipelines: The key role of a three-dimensional three-phase fluid flow numerical model

The contamination impact and the migration of the contaminant into the surrounding environment due to the presence of a spilled oil pipeline will cause significant damage to the natural ecosystem. For this reason, it is decisive to develop a rapid response strategy that might include accurate predictions of oil migration trajectories from numerical simulation modeling. In this paper, a three-dimensional model based on a high-resolution shock-capturing conservative method to resolve the nonlinear governing partial differential equations of the migration of a spilled light nonaqueous liquid oil contaminant in a variably saturated zone is employed to investigate the migration of the oil pipeline leakage with great accuracy. The effects on the oil type density, gasoline and diesel oil, the unsaturated zone depth, its saturation, the hydraulic gradient, and the pressure oil pipeline are investigated through the temporal evolution of the contaminant migration following the saturation profiles of the three-phase fluids flow in the variably saturated zone. The calculation results indicate that the leaking oil's pressure is the parameter that significantly affects the contaminants' arrival time to the groundwater table. Also, the water saturation of the unsaturated zone influences the arrival time as the water saturation increases for a fixed depth. The unsaturated zone depth significantly influences the contaminant migration unsaturated zone. At the same time, the oil density and the hydraulic gradient have limited effects on the contaminant migration in the variably saturated zone.Comment: 46 pages, 19 figure

THE GREY WATERFOOTPRINT OF CATTLE GRAZING: A CASE OF STUDY FOR ITALY

Water footprint accounting has contributed to show that livestock production, and dairy production in particular, have a non-negligible impact in terms of freshwater appropriation (Palhares and Mezzopane, 2015). In this line of research, Allocca et al (2018) have contributed to the scientific debate pointing out that livestock grazing can have a substantial effect in terms of the environment-related grey water footprint (GWFenv) originating from microbial contamination. However, cattle grazing can be a source of contamination also for chemical parameters, precisely nitrate, nitrite and ammonium. Albeit the microbial impact of cattle grazing has been documented by Allocca et al. (2018), they did not take into account possible consequences of the grazing activity in terms of chemical contamination, namely nitrates. This aspect is worth to be examined, since nitrates are important parameters to be evaluated when establishing guidelines for protecting aquatic life and/or ambient water quality for recreation use

Application of QUAL2Kw to the Oglio River (Northern Italy) to assess diffuse N pollution via river-groundwater interaction

Water quality modeling is increasingly recognized as a useful tool for obtaining valuable information for optimal water quality management. In this study, the free software QUAL2Kw was used to evaluate the impacts of agricultural nitrogen (N) excess on river nitrate (NO3-N) concentrations. We explored the possibility to use QUAL2Kw in order to back calculate the exchange of water and N from the groundwater to the Oglio River, northern Italy, which drains a heavily irrigated and fertilized agricultural land. Along the river course water monitoring activities carried out in the dry, summer period revealed steep increases of NO3-N in different sectors, by up to 2 orders of magnitude, not explained by any significant point inputs. Such increases suggest the occurrence of large water exchange with nitrate-polluted groundwater and diffuse inputs. In turn, groundwater pollution is due to high N excess in the watershed (~200 kg N ha-1 yr-1), flood-based irrigation techniques and soil permeability. The QUAL2Kw model was calibrated using the average of 2 years' data collected in winter 2010 and 2011 and validated using the data of winter 2012. To minimize the error between simulation results and measured data, the constants of inorganic suspended solid (ISS), ammonium (NH4-N), nitrate and organic N were calibrated. The calibration and validation results showed a good correspondence between the calculated and measured values for most of water-quality variables. QUAL2Kw was then run separately with three years' summer data (2009, 2010 and 2011), and large gaps were found between the measured and predicted values of discharge, electrical conductivity, NO3-N and total N. Such gaps are discussed in terms of river-groundwater interactions, limited to the summer period and following irrigation by flooding, rise of the groundwater table and vertical transport of N. The gaps allowed to back calculate the volumes of water and the amount of N exchanged. The total load of NO3-N entering into the river from groundwater was estimated in 25.17, 25.63 and 29.89 ton per day for NO3-N in 2009, 2010 and 2011, respectively. Similar results were obtained in another study based on mass balance of N isotopes. The combination of experimental and QUAL2Kw modelled data proved to be a simple, low cost but effective tool in the estimation of NO3-N exchange between the surface and groundwater

Groundwater quality assessment for different uses using various water quality indices in semi-arid region of central Tunisia

The Hajeb Layoun-Jelma basin, located in the central Tunisia, is the principal source of water supply for Sidi Bouzid and Sfax region. The over-abstraction from this groundwater, since 1970, and the intensive agriculture activities led to the degradation of the water quantity and quality. The quality evaluation for this groundwater is very important tool for sustainable development and decision for water management. A total of 28 groundwater samples, from shallow, springs, and deep aquifers, were collected, storage and analyzed to evaluate its quality suitability for domestic and agriculture purposes using geographic information system and geochemical methods. For the both aquifers, the abundance of cations: Na > Mg > Ca > K, and of anions in the order: Cl > HCO3 > SO4. The dominant hydrochemical facies, for the shallow aquifer and springs, are Na-Cl and Ca-Mg-Cl; for the deep aquifer, the geochemical facies are Na-Cl, Ca-Mg-Cl, and Ca-Cl. The comparison of the major parameters and the chemical data with the World Health Organization standards and the national standards indicate that this groundwater is suitable for drinking, except in some samples, with high salinity concentrations. The water quality was assessed, for drinking uses, using "water quality index," "entropy," and "improved water quality index." The results mentioned that the improved water quality index is the best method which indicated that the poor water quality coincide with the Na-Cl water type. The entropy method and the water quality index present the optimistic methods. The irrigation suitability assessment was made using various parameters (SAR, TH, % Na, PI, MH, KR, EC). The results revealed that the majority of samples in Hajeb Layoun-Jelma basin are not appropriate for irrigation uses

Hydrogeological mapping of heterogeneous and multi-layered ophiolitic aquifers (Mountain Prinzera, northern Apennines, Italy)

A few hydrogeological studies have been carried out worldwide in peridotite aquifer systems, despite their wide distribution. The ophiolites are one of the main groundwater reservoir within the northern Apennines (Italy). This paper suggests the graphical solution to set the hydrogeological map of heterogeneous, multi-layered ophiolitic aquifers mapped on large scale (1:1600). The site investigation area is an ophiolite outcrop of the External Ligurian of the northern Apennines: the Mountain Prinzera rock complex area (44°38′30′′N, 10°5′E; Parma Province, Emilia-Romagna Region). The hydrogeological characteristics of the tested aquifer system do not allow setting a hydrogeological map by applying usual graphical approaches. The hydrogeological map in such complex aquifer systems will show the classic hydrogeological data but must put in evidence above all (i) the main heterogeneities of the system, from the hydraulic point of view and (ii) the modifications of groundwater scenarios and pathways over time. The hydrogeological database of Mt Prinzera aquifer was managed in ESRI ArcGIS 10.0 software

Groundwater is a hidden global keystone ecosystem

Groundwater is a vital ecosystem of the global water cycle, hosting unique biodiversity and providing essential services to societies. Despite being the largest unfrozen freshwater resource, in a period of depletion by extraction and pollution, groundwater environments have been repeatedly overlooked in global biodiversity conservation agendas. Disregarding the importance of groundwater as an ecosystem ignores its critical role in preserving surface biomes. To foster timely global conservation of groundwater, we propose elevating the concept of keystone species into the realm of ecosystems, claiming groundwater as a keystone ecosystem that influences the integrity of many dependent ecosystems. Our global analysis shows that over half of land surface areas (52.6%) has a medium‐to‐high interaction with groundwater, reaching up to 74.9% when deserts and high mountains are excluded. We postulate that the intrinsic transboundary features of groundwater are critical for shifting perspectives towards more holistic approaches in aquatic ecology and beyond. Furthermore, we propose eight key themes to develop a science‐policy integrated groundwater conservation agenda. Given ecosystems above and below the ground intersect at many levels, considering groundwater as an essential component of planetary health is pivotal to reduce biodiversity loss and buffer against climate change

Groundwater is a hidden global keystone ecosystem

Groundwater is a vital ecosystem of the global water cycle, hosting unique biodiversity and providing essential services to societies. Despite being the largest unfrozen freshwater resource, in a period of depletion by extraction and pollution, groundwater environments have been repeatedly overlooked in global biodiversity conservation agendas. Disregarding the importance of groundwater as an ecosystem ignores its critical role in preserving surface biomes. To foster timely global conservation of groundwater, we propose elevating the concept of keystone species into the realm of ecosystems, claiming groundwater as a keystone ecosystem that influences the integrity of many dependent ecosystems. Our global analysis shows that over half of land surface areas (52.6%) has a medium-to-high interaction with groundwater, reaching up to 74.9% when deserts and high mountains are excluded. We postulate that the intrinsic transboundary features of groundwater are critical for shifting perspectives towards more holistic approaches in aquatic ecology and beyond. Furthermore, we propose eight key themes to develop a science-policy integrated groundwater conservation agenda. Given ecosystems above and below the ground intersect at many levels, considering groundwater as an essential component of planetary health is pivotal to reduce biodiversity loss and buffer against climate change.info:eu-repo/semantics/publishedVersio