1,568 research outputs found
Influence of the Ion Coordination Number on Cation Exchange Reactions with Copper Telluride Nanocrystals
Cu2-xTe nanocubes were used as starting seeds to access metal telluride
nanocrystals by cation exchanges at room temperature. The coordination number
of the entering cations was found to play an important role in dictating the
reaction pathways. The exchanges with tetrahedrally coordinated cations (i.e.
with coordination number 4), such as Cd2+ or Hg2+, yielded monocrystalline CdTe
or HgTe nanocrystals with Cu2-xTe/CdTe or Cu2-xTe/HgTe Janus-like
heterostructures as intermediates. The formation of Janus-like architectures
was attributed to the high diffusion rate of the relatively small tetrahedrally
coordinated cations, which could rapidly diffuse in the Cu2-xTe NCs and
nucleate the CdTe (or HgTe) phase in a preferred region of the host structure.
Also, with both Cd2+ and Hg2+ ions the exchange led to wurtzite CdTe and HgTe
phases rather than the more stable zinc-blende ones, indicating that the anion
framework of the starting Cu2- xTe particles could be more easily deformed to
match the anion framework of the metastable wurtzite structures. As hexagonal
HgTe had never been reported to date, this represents another case of
metastable new phases that can only be accessed by cation exchange. On the
other hand, the exchanges involving octahedrally coordinated ions (i.e. with
coordination number 6), such as Pb2+ or Sn2+, yielded rock-salt polycrystalline
PbTe or SnTe nanocrystals with Cu2-xTe@PbTe or Cu2-xTe@SnTe core@shell
architectures at the early stages of the exchange process. In this case, the
octahedrally coordinated ions are probably too large to diffuse easily through
the Cu2-xTe structure: their limited diffusion rate restricts their initial
reaction to the surface of the nanocrystals, where cation exchange is initiated
unselectively, leading to core@shell architectures.Comment: 11 pages, 7 figures in J. Am. Chem. Soc, 13 May 201
AffineGlue: Joint Matching and Robust Estimation
We propose AffineGlue, a method for joint two-view feature matching and
robust estimation that reduces the combinatorial complexity of the problem by
employing single-point minimal solvers. AffineGlue selects potential matches
from one-to-many correspondences to estimate minimal models. Guided matching is
then used to find matches consistent with the model, suffering less from the
ambiguities of one-to-one matches. Moreover, we derive a new minimal solver for
homography estimation, requiring only a single affine correspondence (AC) and a
gravity prior. Furthermore, we train a neural network to reject ACs that are
unlikely to lead to a good model. AffineGlue is superior to the SOTA on
real-world datasets, even when assuming that the gravity direction points
downwards. On PhotoTourism, the AUC@10{\deg} score is improved by 6.6 points
compared to the SOTA. On ScanNet, AffineGlue makes SuperPoint and SuperGlue
achieve similar accuracy as the detector-free LoFTR
Skyline Tensile Forces in Cable Logging: Field Observations vs. Software Calculations
Skyline tensile forces have been shown to frequently exceed the recommended safety limits during ordinary cable logging operations. Several models for skyline engineering analyses have been proposed. Although skyline tensile forces assume a dynamic behaviour, practical solutions are based on a static approach without consideration of the dynamic nature of the cable systems. The aim of this study was to compare field data of skyline tensile forces with the static calculations derived by dedicated available software such as SkylineXL. To overcome the limitation of static calculation, this work also aimed to simulate the actual response of the tensile fluctuations measured in the real environment by mean of a finite element model (FEM). Field observations of skyline tensile forces included 103 work cycles, recorded over four different cable lines in standing skyline configuration. Payload estimations, carriages positions, and time study of the logging operations were also collected in the field. The ground profiles and the cable line geometries were analysed using digital elevation models. The field data were then used to simulate the work cycles in SkylineXL. The dynamic response of six fully-suspended loads in a single-span cable line was also simulated by a dedicated FEM built through ANSYS ®. The observed data and the software calculations were then compared. SkylineXL resulted particularly reliable in the prediction of the actual tensile forces, with RMSE ranging between 7.5 and 13.5 KN, linked to an average CV(RMSE) of 7.24%. The reliability in predicting the peak tensile forces was lower, reporting CV(RMSE) of 10.12%, but still not likely resulting in a safety or performance problem. If properly set-up and used, thus, SkylineXL could be considered appropriate for operational and practical purposes. This work, however, showed that finite element models could be successfully used for detailed analysis and simulation of the skyline tensile forces, including the dynamic oscillations due to the motion of the carriage and payload along the cable line. Further developments of this technique could also lead to the physical simulation and analysis of the log-to-ground interaction and the investigation of the breakout force during lateral skidding
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