Dynamics of the Atmospheric Boundary Layer over two middle-latitude rural sites with Doppler lidar

The Atmospheric Boundary Layer (ABL) over two middle-latitude rural sites was characterized in terms of mean horizontal wind and turbulence sources using a standard classification methodology based on Doppler lidar. The first location was an irrigated olive orchard in ubeda (Southern Spain), representing one of the most important crops in the Mediterranean basin and a typical site with Mediterranean climate. The second location was PolWET peatland site in Rzecin (Northwestern Poland), representing one of the largest natural terrestrial carbon storages that have a strong interaction with the climate system. The results showed typical situations for non cloud-topped ABL cases, where ABL is fully developed during daytime due to convection, with high turbulent activity and strong positive skewness indicating frequent and powerful updrafts. The cloud-topped cases showed the strong influence that clouds can have on ABL development, preventing it to reach the same maximum height and introducing top-down movements as an important contribution to mixing. The statistical analysis of turbulent sources allowed for finding a common diurnal cycle for convective mixing at both sites, but nocturnal wind shear driven turbulence with marked differences in its vertical distribution. This analysis demonstrates the Doppler lidar measurements and the classification algorithm strong potential to characterize the dynamics of ABL in its full extent and with high temporal resolution. Moreover, some recommendations for future improvement of the classification algorithm were provided on the basis of the experience gained.Peer reviewe

New particle formation at urban and high-altitude remote sites in the south-eastern Iberian Peninsula

A substantial fraction of the atmospheric aerosols originates from secondary new particle formation (NPF), where atmospheric vapours are transformed into particles that subsequently grow to larger sizes, affecting human health and the climate. In this study, we investigate aerosol size distributions at two stations located close to each other (similar to 20 km) but at different altitudes: urban (UGR; 680 m a.s.l., metres above sea level) and high-altitude remote (SNS; 2500 m a.s.1.) sites, both in the area of Granada, Spain, and part of AGORA observatory (Andalusian Global ObseRvatory of the Atmosphere). The analysis shows a significant contribution of nucleation mode aerosol particles to the total aerosol number concentration at both sites, with a contribution of 47 % and 48 % at SNS and UGR, respectively. Due to the important contribution of NPF events to the total aerosol number concentrations and their high occurrence frequency (> 70 %) during the study period, a detailed analysis of NPF events is done in order to get insight into the possible mechanisms and processes involved in NPF events at these contrastive sites. At SNS, NPF is found to be associated with the transport of gaseous precursors from lower altitudes by orographic buoyant upward flows. NPF events at the SNS site are always observed from the smallest measured sizes of the aerosol size distribution (4 nm), implying that NPF takes place in or in the vicinity of the high-altitude SNS station rather than being transported from lower altitudes. Although NPF events at the mountain site seem to be connected with those occurring at the urban site, growth rates (GRs) at SNS are higher than those at the UGR site (GR(7-25) of 6.9 and 4.5 nm h(-1) and GR(4-)(7 )of 4.1 and 3.6 nm h(-1) at SNS and UGR, respectively). This fact could have special importance for the production of cloud condensation nuclei (CCN) and therefore for cloud formations which may affect regional/global climate, since larger GRs at mountain sites could translate to a larger survival probability of NPF particles reaching CCN sizes, due to the shorter time period needed for the growth. The analysis of sulfuric acid (H2SO4) shows that the contribution of H2SO4 is able to explain a minimal fraction contribution to the observed GRs at both sites (<1 % and <10 % for the 7-25 and 4-7 nm size ranges, respectively), indicating that other condensing vapours are responsible for the majority of particle growth, as well as the differing growth rates between the two sites. Results also show that the condensation sink (CS) does not play a relevant role in NPF processes at both sites and points to the availability of volatile organic compounds (VOCs) as one of the main factors controlling the NPF events at both sites. Finally, a closer analysis of the NPF events that were observed at the SNS site during a Saharan dust episode that occurred during the field campaign was carried out, evidencing the role of TiO2 and F2O3 together with VOCs in promoting new particle formation during this dust intrusion event. Although further investigation is needed to improve our understanding in this topic, this result suggests that climate effects of mineral dust and NPF are not disconnected from each other as it was commonly thought. Therefore, since mineral dust contributes to a major fraction of the global aerosol mass load, dust-NPF interaction should be taken into account in global aerosol-climate modelling for better climate change prediction.Peer reviewe

Near-real-time processing of a ceilometer network assisted with sun-photometer data: monitoring a dust outbreak over the Iberian Peninsula

The interest in the use of ceilometers for optical aerosol characterization has increased in the last few years. They operate continuously almost unattended and are also much less expensive than lidars; hence, they can be distributed in dense networks over large areas. However, due to the low signal-to-noise ratio it is not always possible to obtain particle backscatter coefficient profiles, and the vast number of data generated require an automated and unsupervised method that ensures the quality of the profiles inversions. In this work we describe a method that uses aerosol optical depth (AOD) measurements from the AERONET Network that it is applied for the calibration and automated Quality assurance of inversion of ceilometer profiles. The method is compared with independent inversions obtained by colocated multiwavelength lidar measurements. A difference smaller than 15% in backscatter is found between both instruments. This method is continuously and automatically applied to the Iberian Ceilometer Network (ICENET) and a case example during an unusually intense dust outbreak affecting the Iberian Peninsula between 20 and 24 February 2016 is shown. Results reveal that it is possible to obtain quantitative optical aerosol properties (particle backscatter coefficient) and discriminate the quality of these retrievals with ceilometers over large areas. This information has a great potential for alert systems and model assimilation and evaluation

Near real time processing of ceilometer network data: characterizing an extraordinary dust outbreak over the Iberian Peninsula

Abstract. The interest on the use of ceilometers for optical aerosol characterization has increased in the last few years. They operate continuously almost unattended and are also much less expensive than lidars, hence they can be distributed in dense networks over large areas. However, due to the low signal-to-noise-ratio it is not always possible to obtain particle 20 backscatter coefficient profiles, and the vast amount of data generated requires an automated and unsupervised method that ensures the quality of the profiles inversions. In this work a method that uses aerosol optical depth (AOD) measurements from the AERONET network is applied for the calibration and automated quality assurance of inversion of ceilometer profiles. The method is compared with Independent inversions obtained by co-located multiwavelength lidar measurements and a difference up to 15% in backscatter is found 25 between both instruments. This method is continuously and automatically applied to the Iberian Ceilometer Network (ICENET) and a case example during an unusually intense dust outbreak affecting the Iberian Peninsula on 20 February 2016 and lasted until 24 February 2016 is shown. Results reveal that it is possible to obtain a quantitative optical Aerosol characterization (particle backscatter coefficient) with ceilometers over large areas and this information has a great potential for alert systems and model assimilation and evaluation