1,928 research outputs found
Calibration of oxygen 1s ionization energies. Accurate energies for CO2, H2O, CO, and O2
Access to accurate reference data is a prerequisite in order to translate chemical shifts to an absolute scale for inner-shell ionization energies. Calibration standards for oxygen 1s (O 1s) ionization energies are less well established than, for instance, for carbon 1s. To improve upon this situation, adiabatic and vertical O 1s ionization energies for gaseous carbon dioxide (CO2) are critically reviewed and used to establish the most accurate values currently available: 541.085(17) and 541.253(17) eV, respectively. Combining these with new precise measurements of shifts in O 1s ionization energies for H2O, CO, and O2 allows us to establish equally accurate absolute ionization energies for these molecules as for CO2. The resulting adiabatic and vertical energies are 539.728(17) and 539.827(17) eV for H2O, 542.439(17) and 542.495(17) eV for CO, 543.285(17) and 543.294(17) eV for O2 (4Σ final state), and 544.338(17) and 544.423(17) eV for O2 (2Σ final state). It is proposed that O 1s in CO2 be adopted as a standard of higher precedence, and that H2O, CO, and O2 be used also. The O 1s ionization energies in these molecules occur in the range 540–543 eV. These proposed standards should provide optimal internal calibration for a wide range of oxygen-containing compounds.publishedVersio
The nearly Newtonian regime in Non-Linear Theories of Gravity
The present paper reconsiders the Newtonian limit of models of modified
gravity including higher order terms in the scalar curvature in the
gravitational action. This was studied using the Palatini variational principle
in [Meng X. and Wang P.: Gen. Rel. Grav. {\bf 36}, 1947 (2004)] and
[Dom\'inguez A. E. and Barraco D. E.: Phys. Rev. D {\bf 70}, 043505 (2004)]
with contradicting results. Here a different approach is used, and problems in
the previous attempts are pointed out. It is shown that models with negative
powers of the scalar curvature, like the ones used to explain the present
accelerated expansion, as well as their generalization which include positive
powers, can give the correct Newtonian limit, as long as the coefficients of
these powers are reasonably small. Some consequences of the performed analysis
seem to raise doubts for the way the Newtonian limit was derived in the purely
metric approach of fourth order gravity [Dick R.: Gen. Rel. Grav. {\bf 36}, 217
(2004)]. Finally, we comment on a recent paper [Olmo G. J.: Phys. Rev. D {\bf
72}, 083505 (2005)] in which the problem of the Newtonian limit of both the
purely metric and the Palatini formalism is discussed, using the equivalent
Brans--Dicke theory, and with which our results partly disagree.Comment: typos corrected, replaced to match published versio
Vibrational Structure and Vibronic Coupling in the Carbon 1s Photoelectron Spectra of Ethane and Deuteroethane
Statefinder diagnostic and stability of modified gravity consistent with holographic and new agegraphic dark energy
Recently one of us derived the action of modified gravity consistent with the
holographic and new-agegraphic dark energy. In this paper, we investigate the
stability of the Lagrangians of the modified gravity as discussed in [M. R.
Setare, Int. J. Mod. Phys. D 17 (2008) 2219; M. R. Setare, Astrophys. Space
Sci. 326 (2010) 27]. We also calculate the statefinder parameters which
classify our dark energy model.Comment: 12 pages, 2 figures, accepted by Gen. Relativ. Gravi
Generalized Second Law of Thermodynamics on the Event Horizon for Interacting Dark Energy
Here we are trying to find the conditions for the validity of the generalized
second law of thermodynamics (GSLT) assuming the first law of thermodynamics on
the event horizon in both cases when the FRW universe is filled with
interacting two fluid system- one in the form of cold dark matter and the other
is either holographic dark energy or new age graphic dark energy. Using the
recent observational data we have found that GSLT holds both in quintessence
era as well as in phantom era for new age graphic model while for holographic
dark energy GSLT is valid only in phantom era.Comment: 8 pages, 2 figure
Phase Space Analysis of Quintessence Cosmologies with a Double Exponential Potential
We use phase space methods to investigate closed, flat, and open
Friedmann-Robertson-Walker cosmologies with a scalar potential given by the sum
of two exponential terms. The form of the potential is motivated by the
dimensional reduction of M-theory with non-trivial four-form flux on a
maximally symmetric internal space. To describe the asymptotic features of
run-away solutions we introduce the concept of a `quasi fixed point.' We give
the complete classification of solutions according to their late-time behavior
(accelerating, decelerating, crunch) and the number of periods of accelerated
expansion.Comment: 46 pages, 5 figures; v2: minor changes, references added; v3: title
changed, refined classification of solutions, 3 references added, version
which appeared in JCA
Cosmological evolution and statefinder diagnostic for new holographic dark energy model in non flat universe
In this paper, the holographic dark energy model with new infrared cut-off
proposed by Granda and Oliveros has been investigated in spatially non flat
universe. The dependency of the evolution of equation of state, deceleration
parameter and cosmological evolution of Hubble parameter on the parameters of
new HDE model are calculated. Also, the statefinder parameters and in
this model are derived and the evolutionary trajectories in plane are
plotted. We show that the evolutionary trajectories are dependent on the model
parameters of new HDE model. Eventually, in the light of SNe+BAO+OHD+CMB
observational data, we plot the evolutionary trajectories in and
planes for best fit values of the parameters of new HDE model.Comment: 11 pages, 5 figures, Accepted by Astrophys. Space Sc
A minimal set of invariants as a systematic approach to higher order gravity models: Physical and Cosmological Constraints
We compare higher order gravity models to observational constraints from
magnitude-redshift supernova data, distance to the last scattering surface of
the CMB, and Baryon Acoustic Oscillations. We follow a recently proposed
systematic approach to higher order gravity models based on minimal sets of
curvature invariants, and select models that pass some physical acceptability
conditions (free of ghost instabilities, real and positive propagation speeds,
and free of separatrices). Models that satisfy these physical and observational
constraints are found in this analysis and do provide fits to the data that are
very close to those of the LCDM concordance model. However, we find that the
limitation of the models considered here comes from the presence of
superluminal mode propagations for the constrained parameter space of the
models.Comment: 12 pages, 6 figure
Recurrent Modification of a Conserved Cis-Regulatory Element Underlies Fruit Fly Pigmentation Diversity
The development of morphological traits occurs through the collective action of networks of genes connected at the level of gene expression. As any node in a network may be a target of evolutionary change, the recurrent targeting of the same node would indicate that the path of evolution is biased for the relevant trait and network. Although examples of parallel evolution have implicated recurrent modification of the same gene and cis-regulatory element (CRE), little is known about the mutational and molecular paths of parallel CRE evolution. In Drosophila melanogaster fruit flies, the Bric-à -brac (Bab) transcription factors control the development of a suite of sexually dimorphic traits on the posterior abdomen. Female-specific Bab expression is regulated by the dimorphic element, a CRE that possesses direct inputs from body plan (ABD-B) and sex-determination (DSX) transcription factors. Here, we find that the recurrent evolutionary modification of this CRE underlies both intraspecific and interspecific variation in female pigmentation in the melanogaster species group. By reconstructing the sequence and regulatory activity of the ancestral Drosophila melanogaster dimorphic element, we demonstrate that a handful of mutations were sufficient to create independent CRE alleles with differing activities. Moreover, intraspecific and interspecific dimorphic element evolution proceeded with little to no alterations to the known body plan and sex-determination regulatory linkages. Collectively, our findings represent an example where the paths of evolution appear biased to a specific CRE, and drastic changes in function were accompanied by deep conservation of key regulatory linkages. © 2013 Rogers et al
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