3,522 research outputs found
Strengthening measurements from the edges: application-level packet loss rate estimation
Network users know much less than ISPs, Internet exchanges and content providers about what happens inside the network. Consequently users cannot either easily detect network neutrality violations or readily exercise their market power by knowledgeably switching ISPs. This paper contributes to the ongoing efforts to empower users by proposing two models to estimate -- via application-level measurements -- a key network indicator, i.e., the packet loss rate (PLR) experienced by FTP-like TCP downloads. Controlled, testbed, and large-scale experiments show that the Inverse Mathis model is simpler and more consistent across the whole PLR range, but less accurate than the more advanced Likely Rexmit model for landline connections and moderate PL
2-(Phenylcarbonothioylsulfanyl)acetic acid
The title compound, C9H8O2S2, can be used as a chain transfer agent and may be used to control the behavior of polymerization reactions. O—H⋯O hydrogen bonds of moderate character link the molecules into dimers. In the crystal, the dimers are linked into sheets by C—H⋯O interactions, forming R
4
2(12) and R
2
2(8) edge-fused rings running parallel to [101]. There are no intermolecular interactions involving the S atoms
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New emissive mononuclear copper (I) complex: Structural and photophysical characterization focusing on solvatochromism, rigidochromism and oxygen sensing in mesoporous solid matrix
3-(2,4-Dibromoanilino)-2,2-dimethyl-2,3-dihydronaphtho[1,2-b]furan-4,5-dione: a new substituted arylamino nor-β-lapachone derivative
The title compound, C20H15Br2NO3, shows the furan ring to adopt a half-chair conformation and the two ring systems to be approximately perpendicular [dihedral angle = 71.0 (2)°]. In the crystal structure, intermolecular C—H⋯O contacts link the molecules
4-Methylphenyl 4-bromobenzoate
In the title compound, C14H11BrO2, an ester formed from the reaction of 4-methylphenol with 4-bromobenzoylchloride, the dihedral angle between the benzene rings is 54.43 (7)°, indicating a twist in the molecule. In the crystal, weak C—H⋯O interactions link the molecules into supramolecular layers in the bc plane, and these are connected along the a axis by Br⋯Br contacts [3.6328 (5) Å]
trans-5,6-Diphenylperhydropyran-2,4-dione
In the title compound, C17H14O3, the pyran ring adopts a boat conformation and the dihedral angle between the aromatic ring planes is 59.1 (1)°. In the crystal structure intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions link the molecules
1-(4-Bromophenyl)-2-ethylsulfinyl-2-(phenylselanyl)ethanone monohydrate
In the title hydrate, C16H15BrO2SSe·H2O, the sulfinyl O atom lies on the opposite side of the molecule to the Se and carbonyl O atoms. The benzene rings form a dihedral angle of 51.66 (17)° and are splayed with respect to each other. The observed conformation allows the water molecules to bridge sulfinyl O atoms via O—H⋯O hydrogen bonds, generating a linear supramolecular chain along the b axis; the chain is further stabilized by C—H⋯O contacts. The chains are held in place in the crystal structure by C⋯H⋯π and C—Br⋯π interactions
2-(4-Methylphenyl)-1H-anthraceno[1,2-d]imidazole-6,11-dione: a fluorescent chemosensor
In the title compound, C22H14N2O2, the five rings of the molecule are not coplanar. There is a significant twist between the four fused rings, which have a slightly arched conformation, and the pendant aromatic ring, as seen in the dihedral angle of 13.16 (8)° between the anthraquinonic ring system and the pendant aromatic ring plane
cis-Bis[1,1-dibenzyl-3-(furan-2-ylcarbonyl)thioureato-κ2 O,S]copper(II)
In the title compound, [Cu(C20H17N2O2S)2], the CuII atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-(furan-2-ylcarbonyl)thioureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Cu—S and Cu—O bond lengths lie within the ranges of those found in related structures. The dihedral angle between the planes of the two chelating rings is 26.15 (6)°
Conventional and microwave-assisted reaction of N-hydroxymethylphthalimide with arylamines: synthesis of N-(arylaminomethyl)-phthalimides
An efficient and easy synthesis of compounds: 2-Phenylaminomethyl-isoindole-1,3-dione (5a), 2-[(2-Clorophenylamino)methyl]-isoindole-1,3-dione (5b), 2-[(3-Clorophenylamino)methyl]-isoindole-1,3-dione (5c), 2-[(4-Clorophenylamino)methyl)-isoindole-1,3-dione (5d), 2-[(2-Fluorophenylamino)methyl]-isoindole-1,3-dione (5e), 2-[(3-fluorophenylamino)methyl]-isoindole-1,3-dione (5f), 2-[(4-Fluorophenylamino)methyl]-isoindole-1,3-dione (5g), 2-[(2-Nitrophenylamino)methyl]-isoindole-1,3-dione (5h), 2-[(3-Nitrophenylamino)methyl]-isoindole-1,3-dione (5i), 2-[(4-Nitrophenylamino)methyl]-isoindole-1,3-dione (5j), 2-[1H-(1,2,4)Triazol-3-yl-aminomethyl)-isoindole-1,3-dione (5k) and 2-([1,2,4]-Triazole-4-yl-aminomethyl)-isoindole-1,3-dione (5l), is described. The general synthesis procedure starts from N-hydroxymethylphthalimide 3 and aryl- and [1,2,4-triazol-3- and 4-yl]-amines 4a-l by conventional and solvent-free microwave-mediated. The reaction of 3 with 4l turned out to be a very rapid and high-yielding one. A comparison of these two methods has been made. Three probable mechanisms of formation of N-(arylaminomethyl)-phthalimides (one in the solution phase and two in the microwave-accelerated conditions are proposed. Crystallographic analyses of 5d furnished the correct conformation of this molecule. Ab initio molecular orbital calculations of 5d using 6-31G* basis set were performed and the results were comparable to the X-ray data
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