228 research outputs found
Size Segregation of Granular Matter in Silo Discharges
We present an experimental study of segregation of granular matter in a
quasi-two dimensional silo emptying out of an orifice. Size separation is
observed when multi-sized particles are used with the larger particles found in
the center of the silo in the region of fastest flow. We use imaging to study
the flow inside the silo and quantitatively measure the concentration profiles
of bi-disperse beads as a function of position and time. The angle of the
surface is given by the angle of repose of the particles, and the flow occurs
in a few layers only near the top of this inclined surface. The flowing region
becomes deeper near the center of the silo and is confined to a parabolic
region centered at the orifice which is approximately described by the
kinematic model. The experimental evidence suggests that the segregation occurs
on the surface and not in the flow deep inside the silo where velocity
gradients also are present. We report the time development of the
concentrations of the bi-disperse particles as a function of size ratios, flow
rate, and the ratio of initial mixture. The qualitative aspects of the observed
phenomena may be explained by a void filling model of segregation.Comment: 6 pages, 10 figures (gif format), postscript version at
http://physics.clarku.edu/~akudrolli/nls.htm
Long-lived quantum coherence in photosynthetic complexes at physiological temperature
Photosynthetic antenna complexes capture and concentrate solar radiation by
transferring the excitation to the reaction center which stores energy from the
photon in chemical bonds. This process occurs with near-perfect quantum
efficiency. Recent experiments at cryogenic temperatures have revealed that
coherent energy transfer - a wavelike transfer mechanism - occurs in many
photosynthetic pigment-protein complexes (1-4). Using the Fenna-Matthews-Olson
antenna complex (FMO) as a model system, theoretical studies incorporating both
incoherent and coherent transfer as well as thermal dephasing predict that
environmentally assisted quantum transfer efficiency peaks near physiological
temperature; these studies further show that this process is equivalent to a
quantum random walk algorithm (5-8). This theory requires long-lived quantum
coherence at room temperature, which never has been observed in FMO. Here we
present the first evidence that quantum coherence survives in FMO at
physiological temperature for at least 300 fs, long enough to perform a
rudimentary quantum computational operation. This data proves that the
wave-like energy transfer process discovered at 77 K is directly relevant to
biological function. Microscopically, we attribute this long coherence lifetime
to correlated motions within the protein matrix encapsulating the chromophores,
and we find that the degree of protection afforded by the protein appears
constant between 77 K and 277 K. The protein shapes the energy landscape and
mediates an efficient energy transfer despite thermal fluctuations. The
persistence of quantum coherence in a dynamic, disordered system under these
conditions suggests a new biomimetic strategy for designing dedicated quantum
computational devices that can operate at high temperature.Comment: PDF files, 15 pages, 3 figures (included in the PDF file
Excitation energy transfer in light-harvesting system: Effect of initial state
The light-harvesting is a problem of long interest. It becomes active again
in recent years stimulated by suggestions of quantum effects in energy
transport. Recent experiments found evidence that BChla 1 and BChla 6 are the
first to be excited in the Fenna-Matthews-Olson(FMO) protein, theoretical
studies, however, are mostly restricted to consider the exciton in BChla 1
initially. In this paper, we study the energy transport in the FMO complex by
taking different initial states into account. Optimizations are performed for
the decoherence rates as to maximal transport efficiency. Dependence of the
energy transfer efficiency on the initial states is given and discussed.
Effects of fluctuations in the site energies and couplings are also examined.Comment: 6 pages, 6 figures, J Phys B accepte
Distribution of entanglement in light-harvesting complexes and their quantum efficiency
Recent evidence of electronic coherence during energy transfer in
photosynthetic antenna complexes has reinvigorated the discussion of whether
coherence and/or entanglement has any practical functionality for these
molecular systems. Here we investigate quantitative relationships between the
quantum yield of a light-harvesting complex and the distribution of
entanglement among its components. Our study focusses on the entanglement yield
or average entanglement surviving a time scale comparable to the average
excitation trapping time. As a prototype system we consider the
Fenna-Matthews-Olson (FMO) protein of green sulphur bacteria and show that
there is an inverse relationship between the quantum efficiency and the average
entanglement between distant donor sites. Our results suggest that longlasting
electronic coherence among distant donors might help modulation of the
lightharvesting function.Comment: Version accepted for publication in NJ
The effect of Zr and Sn additions on the microstructure of Ti-Nb-Fe gum metals with high elastic admissible strain
An open challenge on structural biomaterials is to obtain low-cost Ti-alloys with high elastic admissible strength (the ratio of yield strength to modulus). To reach this goal, we designed and characterized three quaternary alloys from the Ti-Nb-Fe system with additions of Zr and Sn. The samples were solution-treated and tested under two conditions: water-quenched and aged at 450 °C. Microstructures were analyzed with aid of scanning and transmission electron microscopy. Tensile tests performed at room-temperature confirmed a remarkable yield strength of 1271 MPa with an elastic modulus close to 90 GPa among aged Ti-19Nb-2.5Fe-6Sn (wt%) samples. Solution-treated Ti-19Nb-2.5Fe-10Zr samples presented a good combination of yield-strength and elastic modulus (1027 MPa and 69 GPa, respectively), displaying an elastic admissible strength close to 1.5. Although Zr and Sn are equally distributed between matrix and precipitates, the diffusion of Nb and Fe seem to be inhibited by the presence of Sn. As a result, Sn allows higher yield-strengths and more refined secondary α-phase, while Zr has a stronger effect on reducing the elastic modulus. In the end, a materials selection chart is presented to help designers to select materials for orthopedic implants considering the elastic admissible strain and cost as major guidelines16011861195CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQFUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESPNão tem2014/24449-0; 2016/22714-3; 2016/24693-3Funding: This work was supported by FAPESP (São Paulo State Research Foundation, grants numbers 2014/24449-0, 2016/22714-3 and 2016/24693-3) and CNPq (National Council for Scientific and Technological Development). The authors gratefully acknowledge Prof. Hamish Fraser for the use of experimental facilities at the Center for Electron Microscopy and Analysis (CEMAS), at the Ohio State University, USA, and thank CBMM Co. for the Nb supply. The raw/processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study. Data will be made available upon reques
Liquid flyback booster pre-phase: A study assessment
The concept of a flyback booster has been around since early in the shuttle program. The original two-stage shuttle concepts used a manned flyback booster. These boosters were eliminated from the program for funding and size reasons. The current shuttle uses two Redesigned Solid Rocket Motors (RSRM's), which are recovered and refurbished after each flight; this is one of the major cost factors of the program. Replacement options have been studied over the past ten years. The conclusion reached by the most recent study is that the liquid flyback booster (LFBB) is the only competitive option from a life-cycle cost perspective. The purpose of this study was to assess the feasibility and practicality of LFBB's. The study provides an expansion of the recommendations made during the aforementioned study. The primary benefits are the potential for enhanced reusability and a reduction of recurring costs. The potential savings in vehicle turnaround could offset the up-front costs. Development of LFBB's requires a commitment to the shuttle program for 20 to 30 years. LFBB's also offer enhanced safety and abort capabilities. Currently, any failure of an RSRM can be considered catastrophic, since there are no intact abort capabilities during the burn of the RSRM's. The performance goal of the LFBB's was to lift a fully loaded orbiter under optimal conditions, so as not to be the limiting factor of the performance capability of the shuttle. In addition, a final benefit is the availability of growth paths for applications other than shuttle
Motional effects on the efficiency of excitation transfer
Energy transfer plays a vital role in many natural and technological
processes. In this work, we study the effects of mechanical motion on the
excitation transfer through a chain of interacting molecules with application
to biological scenarios of transfer processes. Our investigation demonstrates
that, for various types of mechanical oscillations, the transfer efficiency is
significantly enhanced over that of comparable static configurations. This
enhancement is a genuine quantum signature, and requires the collaborative
interplay between the quantum-coherent evolution of the excitation and the
mechanical motion of the molecules; it has no analogue in the classical
incoherent energy transfer. This effect may not only occur naturally, but it
could be exploited in artificially designed systems to optimize transport
processes. As an application, we discuss a simple and hence robust control
technique.Comment: 25 pages, 11 figures; completely revised; version accepted for
publicatio
Traffic Equations and Granular Convection
We investigate both numerically and analytically the convective instability
of granular materials by two dimensional traffic equations. In the absence of
vibrations the traffic equations assume two distinctive classes of fixed bed
solutions with either a spatially uniform or nonuniform density profile. The
former one exists only when the function V(\rho) that monitors the relaxation
of grains assumes a cut off at the closed packed density, \rho_c, with
V(\rho_c)=0, while the latter one exists for any form of V. Since there is
little difference between the uniform and nonuniform solution deep inside the
bed, the convective instability of the bulk may be studied by focusing on the
stability of the uniform solution. In the presence of vibrations, we find that
the uniform solution bifurcates into a bouncing solution, which then undergoes
a supercritical bifurcation to the convective instability. We determine the
onset of convection as a function of control parameters and confirm this
picture by solving the traffic equations numerically, which reveals bouncing
solutions, two convective rolls, and four convective rolls. Further, convective
patterns change as the aspect ratio changes: in a vertically long container,
the rolls move toward the surface, and in a horizontally long container, the
rolls move toward the walls. We compare these results with those reported
previously with a different continuum model by Hayakawa, Yue and Hong[Phys.
Rev. Lett. 75,2328, 1995]. Finally, we also present a derivation of the traffic
equations from Enskoq equation.Comment: 34 pages, 10 figure
Exciton Dynamics in Photosynthetic Complexes: Excitation by Coherent and Incoherent Light
In this paper we consider dynamics of a molecular system subjected to
external pumping by a light source. Within a completely quantum mechanical
treatment, we derive a general formula, which enables to asses effects of
different light properties on the photo-induced dynamics of a molecular system.
We show that once the properties of light are known in terms of certain
two-point correlation function, the only information needed to reconstruct the
system dynamics is the reduced evolution superoperator. The later quantity is
in principle accessible through ultrafast non-linear spectroscopy. Considering
a direct excitation of a small molecular antenna by incoherent light we find
that excitation of coherences is possible due to overlap of homogeneous line
shapes associated with different excitonic states. In Markov and secular
approximations, the amount of coherence is significant only under fast
relaxation, and both the populations and coherences between exciton states
become static at long time. We also study the case when the excitation of a
photosynthetic complex is mediated by a mesoscopic system. We find that such
case can be treated by the same formalism with a special correlation function
characterizing ultrafast fluctuations of the mesoscopic system. We discuss
bacterial chlorosom as an example of such a mesoscopic mediator and propose
that the properties of energy transferring chromophore-protein complexes might
be specially tuned for the fluctuation properties of their associated antennae.Comment: 12 page
Density waves and density fluctuations in granular flow
We simulate the granular flow in a narrow pipe with a lattice-gas automaton
model. We find that the density in the system is characterized by two features.
One is that spontaneous density waves propagate through the system with
well-defined shapes and velocities. The other is that density waves are so
distributed to make the power spectra of density fluctuations as
noise. Three important parameters make these features observable and they are
energy dissipation, average density and the rougness of the pipe walls.Comment: Latex (with ps files appended
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