Supermassive black hole pairs in clumpy galaxies at high redshift: delayed binary formation and concurrent mass growth

Massive gas-rich galaxy discs at $z \sim 1-3$ host massive star-forming clumps with typical baryonic masses in the range $10^7-10^8$~M$_{\odot}$ which can affect the orbital decay and concurrent growth of supermassive black hole (BH) pairs. Using a set of high-resolution simulations of isolated clumpy galaxies hosting a pair of unequal-mass BHs, we study the interaction between massive clumps and a BH pair at kpc scales, during the early phase of the orbital decay. We find that both the interaction with massive clumps and the heating of the cold gas layer of the disc by BH feedback tend to delay significantly the orbital decay of the secondary, which in many cases is ejected and then hovers for a whole Gyr around a separation of 1--2 kpc. In the envelope, dynamical friction is weak and there is no contribution of disc torques: these lead to the fastest decay once the orbit of the secondary BH has circularised in the disc midplane. In runs with larger eccentricities the delay is stronger, although there are some exceptions. We also show that, even in discs with very sporadic transient clump formation, a strong spiral pattern affects the decay time-scale for BHs on eccentric orbits. We conclude that, contrary to previous belief, a gas-rich background is not necessarily conducive to a fast BH decay and binary formation, which prompts more extensive investigations aimed at calibrating event-rate forecasts for ongoing and future gravitational-wave searches, such as with Pulsar Timing Arrays and the future evolved Laser Interferometer Space Antenna.Comment: Accepted by MNRA

Growth and activity of black holes in galaxy mergers with varying mass ratios

We study supermassive black holes (BHs) in merging galaxies, using a suite of hydrodynamical simulations with very high spatial (~10 pc) and temporal (~1 Myr) resolution, where we vary the initial mass ratio, the orbital configuration, and the gas fraction. (i) We address the question of when and why, during a merger, increased BH accretion occurs, quantifying gas inflows and BH accretion rates. (ii) We also quantify the relative effectiveness in inducing AGN activity of merger-related versus secular-related causes, by studying different stages of the encounter: the stochastic (or early) stage, the (proper) merger stage, and the remnant (or late) stage. (iii) We assess which galaxy mergers preferentially enhance BH accretion, finding that the initial mass ratio is the most important factor. (iv) We study the evolution of the BH masses, finding that the BH mass contrast tends to decrease in minor mergers and to increase in major mergers. This effect hints at the existence of a preferential range of mass ratios for BHs in the final pairing stages. (v) In both merging and dynamically quiescent galaxies, the gas accreted by the BH is not necessarily the gas with $low$ angular momentum, but the gas that $loses$ angular momentum.Comment: Accepted for publication in MNRAS, 23 pages, 22 figures, 3 table

The birth of a supermassive black hole binary

We study the dynamical evolution of supermassive black holes, in the late stage of galaxy mergers, from kpc to pc scales. In particular, we capture the formation of the binary, a necessary step before the final coalescence, and trace back the main processes causing the decay of the orbit. We use hydrodynamical simulations of galaxy mergers with different resolutions, from $20\,\rm pc$ down to $1\,\rm pc$, in order to study the effects of the resolution on our results, remove numerical effects, and assess that resolving the influence radius of the orbiting black hole is a minimum condition to fully capture the formation of the binary. Our simulations include the relevant physical processes, namely star formation, supernova feedback, accretion onto the black holes and the ensuing feedback. We find that, in these mergers, dynamical friction from the smooth stellar component of the nucleus is the main process that drives black holes from kpc to pc scales. Gas does not play a crucial role and even clumps do not induce scattering or perturb the orbits. We compare the time needed for the formation of the binary to analytical predictions and suggest how to apply such analytical formalism to obtain estimates of binary formation times in lower resolution simulations.Comment: 12 pages, 12 Figures, submitted to MNRA

A comparison of black hole growth in galaxy mergers with Gasoline and Ramses

Supermassive black hole dynamics during galaxy mergers is crucial in determining the rate of black hole mergers and cosmic black hole growth. As simulations achieve higher resolution, it becomes important to assess whether the black hole dynamics is influenced by the treatment of the interstellar medium in different simulation codes. We here compare simulations of black hole growth in galaxy mergers with two codes: the Smoothed Particle Hydrodynamics code Gasoline, and the Adaptive Mesh Refinement code Ramses. We seek to identify predictions of these models that are robust despite differences in hydrodynamic methods and implementations of sub-grid physics. We find that the general behavior is consistent between codes. Black hole accretion is minimal while the galaxies are well-separated (and even as they "fly-by" within 10 kpc at first pericenter). At late stages, when the galaxies pass within a few kpc, tidal torques drive nuclear gas inflow that triggers bursts of black hole accretion accompanied by star formation. We also note quantitative discrepancies that are model-dependent: our Ramses simulations show less star formation and black hole growth, and a smoother gas distribution with larger clumps and filaments, than our Gasoline simulations. We attribute these differences primarily to the sub-grid models for black hole fueling and feedback and gas thermodynamics. The main conclusion is that differences exist quantitatively between codes, and this should be kept in mind when making comparisons with observations. However, reassuringly, both codes capture the same dynamical behaviors in terms of triggering of black hole accretion, star formation, and black hole dynamics.Comment: 11 pages, 7 figures. Submitted to A&A. Comments welcom

Nuclear coups: dynamics of black holes in galaxy mergers

We study the dynamical evolution of supermassive black holes (BHs) in merging galaxies on scales of hundreds of kpc to 10 pc, to identify the physical processes that aid or hinder the orbital decay of BHs. We present hydrodynamical simulations of galaxy mergers with a resolution of $\leq$20 pc, chosen to accurately track the motion of the nuclei and provide a realistic environment for the evolution of the BHs. We find that, during the late stages of the merger, tidal shocks inject energy in the nuclei, causing one or both nuclei to be disrupted and leaving their BH `naked', without any bound gas or stars. In many cases, the nucleus that is ultimately disrupted is that of the larger galaxy (`nuclear coup'), as star formation grows a denser nuclear cusp in the smaller galaxy. We supplement our simulations with an analytical estimate of the orbital-decay time required for the BHs to form a binary at unresolved scales, due to dynamical friction. We find that, when a nuclear coup occurs, the time-scale is much shorter than when the secondary's nucleus is disrupted, as the infalling BH is more massive, and it also finds itself in a denser stellar environment.Comment: Accepted for publication in MNRAS, 16 pages, 13 figures, 2 table

Rational design of multi-functional nanomaterials

FCT-MEC project PTDC/QEQMED/2118/2014publishersversionpublishe

Photocatalytic hydrogen production using noble and transition metals surface modified titania [Resumo]

ABSTRACT: A large number of photocatalytic materials have been studied for water splitting since the seminal work of Fujishima and Honda1, showing great potential for solar energy conversion, including H2 production. The irradiation of a suspension of semiconductor oxides, as is the case of TiO2, presents attracting features but also stringent requirements regarding materials properties, including the tailoring of the electronic structure. Furthermore, efficient charge transport is necessary, as well as effective charge separation and prevention of electron-hole pair recombination, before the redox reactions can proceed2,3. In this work, the catalytic activity under UV excitation of TiO2-Au photocatalyst for H2 production was undertaken using glycerol and ethanol as sacrificial agents. Furthermore, substitution of Au by transition metal Cu was attempted with good results. Comparison is made with results obtained using TiO2-rGO-Pt catalyst under analogous loading conditions.N/

Enhancing Pt electrocatalytic activity by surface functionalization of carbon support with aromatic sulphonic groups

Preliminary results are presented for Pt deposited on 4-aminobenzenesulphonic acid-functionalized carbon, Pt/C_ABSA. Vulcan XC-72R was functionalized with the objective of influencing the dispersion of catalyst nanoparticles and to decrease the resistance of three phase boundaries, by introducing sulphonic groups. Electrochemical characterization of the supported catalyst was done in a 0.5 M sulphuric acid solution with added chloride and also using methanol demonstrating well defined features and stable voltammograms after 30 cycles, with apparent higher currents when compared with commercial catalyst. The structure sensitive adsorption of anions on platinum is confirmed by the blocking effect of chloride ions in the hydrogen adsorption-desorption region as well as by the consequent dissolution of platinum, evident in both anodic and cathodic features of the voltammograms regarding surface oxide formation and reduction. The partial reversibility of the effect of chloride ions is discussed. Research is in progress in order to accomplish a comprenhensive characterization of the synthesized catalyst and to ascertain the effect of the sulphonic groups

Determination of phytoextraction potential of plant speciesfor toxic elements in soils of abandoned sulphide-mining areas

This study has determined contamination levels in soils and plants from the Sa˜o Domingos mining area, Portugal, by k0-INAA. Total concentrations of As, Sb, Cr, Hg, Cu, Zn and Fe in soils were very high, exceeding the maximum limits in Portuguese legislation. Concentrations of toxic elements like As, Sb and Zn were highest in roots of Erica andevalensis, Juncus acutus, Agrostis castellana and Nicotiana glauca. Additionally, As, Br, Cr, Fe, Sb and Zn in all organs of most plants were above toxicity levels. Those species that accumulated relatively high concentrations of toxic elements in roots (and tops) may be cultivated for phytostabilisation of similar areas