59 research outputs found

    Temporal dynamics of IR-to-visible up-conversion in LiNbO3:Er3+/Yb3+: a path to phosphors with tunable chromaticity

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    This paper was published in Optical Materials Express and is made available as an electronic reprint with the permission of OSA. The paper can be found at the following URL on the OSA website: http://dx.doi.org/10.1364/OME.2.001529. Systematic or multiple reproduction or distribution to multiple locations via electronic or other means is prohibited and is subject to penalties under la

    Continuous-wave laser action at λ = 1064.3nm in proton- and carbon- implanted Nd:YAG waveguides

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    Copyright (2003) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Applied Physics Letters 83.20 (2003): 4110-4112 and may be found at http://apl.aip.org

    Continuous-wave laser oscillation at 1.3 μm in Nd:YAG proton-implanted planar waveguides

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    Copyright (2005) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Applied Physics Letters 86 (2005): 151108 and may be found at http://apl.aip.org

    Micro-Raman characterization of Zn-diffused channel waveguides in Tm3+: LiNbO3

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    This paper was published in Optics Express and is made available as an electronic reprint with the permission of OSA. The paper can be found at the following URL on the OSA website: http://dx.doi.org/10.1364/OE.18.005449. Systematic or multiple reproduction or distribution to multiple locations via electronic or other means is prohibited and is subject to penalties under la

    Quantification of the resonant energy transfer processes in Er3+/Yb3+ co-doped Ca3Al2Si3O12 glasses

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    The resonant cross relaxation processes between Yb3+ and Er3+ ions in calcium alumino-silicate glasses have been quantified under selective Er3+ excitation. The infrared emission spectra, measured under steady state conditions (CW excitation to the 4I9/2 erbium level), have allowed to obtain an experimental relationship linking the transfer (Yb3+ → Er3+) and back transfer (Er3+ → Yb3+) parameters. These measurements combined with the dynamics of the main emitting levels, measured under pulsed excitation to the 2H11/2 erbium level, have allowed the fully quantification of the energy transfer parameters. The obtained values, C25=5.5×10−18cm3s−1 (Yb3+ → Er3+), C52=1.5×10−18cm3s−1 (Er3+ → Yb3+) and C27=7.6×10−18cm3s−1 (up-conversion mechanism, estimated from the Judd-Ofelt analysis previously reported), can be used to predict the temporal evolution of the main luminescent emission band

    Single polarized Tm3+ laser in Zn-diffused LiNbO3 channel waveguides

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    Copyright (2005) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Applied Physics Letters 86 (2005): 161119 and may be found at http://apl.aip.org

    Red, green, and blue simultaneous generation in aperiodically poled Zn-diffused LiNbO3:Er3+/Yb3+ nonlinear channel waveguides

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    Copyright (2003) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Applied Physics Letters 83.15 (2003): 2991-2993 and may be found at http://apl.aip.org

    LaPO4:Er microspheres with high NIR luminescent quantum yield

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    Er-doped LaPO4 microspheres have been synthesized by spray pyrolysis and the near infrared (NIR) properties have been characterized. It has been found that, following an adequate post-annealing treatment, the emission properties are remarkably improved. The NIR luminescence intensity is highly enhanced and its decay time increases to a value almost coincident with the reported radiative lifetime, which implies that the quantum yield approaches η ≈ 100%. This improvement in luminescence characteristics is probably related to the suppression of residual OH- radicals, that otherwise act as NIR luminescence quenchers, and to the increase in material's crystallinityJunta de Andalucía FQM6090Madrid Ministerio de Ciencia e Innovación CRONOSOMATS MAT2009-14102 MICROSERES-CM P2009/TIC-147

    Structural, photoluminescent properties and Judd-Ofelt analysis of Eu3+-activated CaF2 nanocubes

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    Eu3+-doped CaF2 nanocubes with variable europium concentration, [Eu3+] = 0, 0.6, 1.3, 1.7, 2.2 and 5.4 mol%, have been synthesized by a direct precipitation route. It has been found that, within this concentration range, the nanoparticles present the fluoride-type crystalline structure and the characteristic cubic shape of CaF2 crystals. The nanoparticle size follows a log-normal distribution with a mean value decreasing with the Eu3+ content. Rietveld refinement has been performed to calculate the lattice parameter and crystallite size. Eu3+ concentration affects both parameters giving rise to an increase in the lattice parameter and a reduction of crystallite size. The luminescent properties of Eu3+ ions in these nanostructures have been investigated under CW and pulsed excitation. A Judd-Ofelt analysis, as function of the Eu3+ content, has been performed to determine the transition probabilities, radiative lifetimes and branching ratios of the 5D0 emitting level. It was found that and Judd-Ofelt intensity parameters are dependent on the doping level, showing an evolution that indicates a decrease in the Eu3+ site local symmetry with increasing Eu3+ concentration. Finally, it has been observed that the characteristic luminescence decay time of the 5D0 manifold is reduced with increasing Eu3+ concentration. This effect is partially due to an increase of radiative transition probability, associated with a reduction in the local symmetry of the lanthanide ions, and also to the occurrence of concentration quenching effectsThis work has been partially supported by Ministerio de Economía y Competitividad and Ministerio de Ciencia, Innovación y Universidades under projects MAT2016-75716-2-2-R and RTI2018- 101020-B-I00
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