Second-harmonic generation of ZnO nanoparticles synthesized by laser ablation of solids in liquids

We report the synthesis of small zinc oxide nanoparticles (ZnO NPs) based colloidal suspensions and the study of second-harmonic generation from aggregated ZnO NPs deposited on glass substrates. The colloidal suspensions were obtained using the laser ablation of solids in liquids technique, ablating a Zn solid target immersed in acetone as the liquid medium, with ns-laser pulses (1064 nm) of a Nd-YAG laser. The per pulse laser fluence, the laser repetition rate frequency and the ablation time were kept constant. The absorption evolution of the obtained suspensions was optically characterized through absorption spectroscopy until stabilization. Raman spectroscopy, SEM and HRTEM were used to provide evidence of the ZnO NPs structure. HRTEM results showed that 5–8 nm spheroids ZnO NPs were obtained. Strong second-harmonic signal is obtained from random ZnO monocrystalline NPs and from aggregated ZnO NPs, suggesting that the high efficiency of the nonlinear process may not depend on the NPs size or aggregation state

Synthesis of molybdenum oxide nanoparticles by nanosecond laser ablation

Phothermal therapy (PTT) is one of the most promising techniques to treat cancer. Finding the ideal PTT agent nanomaterial has remained a challenge and has brought the interest of several researchers. In this work, we report the synthesis of molybdenum oxide (MoOx) nanoparticles (NPs), which exhibit absorption in the biological optical window ~840 nm, by using the laser ablation of solids in liquids (LASL) technique with nanosecond (ns) pulses. A Nd:YAG laser was used to synthesize the NPs in deionized (DI) water, free of surfactants or additives, which were optically characterized by absorption spectroscopy and TEM-EDX microscopy. Semi spherical NPs with a suitable average size and shape for potential use as PTT agents were obtained by laser ablation and ablation + fragmentation. The calculated band gap is 3.1 eV, which corresponds to MoO3. Micro-Raman spectroscopy studies determined that these NPs are composed of amorphous molybdenum oxide hydrates (MoO3 · xH2O)

Influence of oxygen pressure on the fs laserinduced oxidation of molybdenum thin films

We present a study of femtosecond (1028 nm, 230 fs, 54.7 MHz) laser processing on molybdenum (Mo) thin films. Irradiations were done under ambient air as well as pure oxygen (O2) at various gauge pressures (4, 8, 12 and 16 psi). Our results indicate that the high heating rates associated with laser processing allow the production of different molybdenum oxides. Raman spectroscopy and scanning electron microscopy are used to characterize the molybdenum oxidation for the different irradiation and oxygen pressures parameters chosen showing a high correlation between well-defined oxidation zones and the oxygen pressure surrounding the samples during the irradiation of the Mo thin films

Spontaneous patterns in coherently driven polariton microcavities

We consider a polariton microcavity resonantly driven by two external lasers which simultaneously pump both lower and upper polariton branches at normal incidence. In this setup, we study the occurrence of instabilities of the pump-only solutions towards the spontaneous formation of patterns. Their appearance is a consequence of the spontaneous symmetry breaking of translational and rotational invariance due to interaction induced parametric scattering. We observe the evolution between diverse patterns which can be classified as single-pump, where parametric scattering occurs at the same energy as one of the pumps, and as two-pump, where scattering occurs at a different energy. For two-pump instabilities, stripe and chequerboard patterns become the dominant steady-state solutions because cubic parametric scattering processes are forbidden. This contrasts with the single-pump case, where hexagonal patterns are the most common arrangements. We study the possibility of controlling the evolution between different patterns. Our results are obtained within a linear stability analysis and are confirmed by finite size full numerical calculations.Comment: 15 pages, 9 figure

Pt-impregnated catalysts on powdery SiC and other commercial supports for the combustion of hydrogen under oxidant conditions

We report the study of the catalytic hydrogen combustion over Pt-impregnated powdery silicon carbide (SiC) using H2PtCl6 as precursor. The reaction was conducted in excess of oxygen. β-SiC was selected for the study because of its thermal conductivity, mechanical properties, chemical inertness and surface area. The obtained Pt particles over SiC were medium size (average particle diameter of 5 nm for 0.5 wt% Pt). The activity of the Pt-impregnated catalyst over SiC was compared to those obtained in oxidized form over TiO2 and Al2O3 commercial supports (Pt particles very small in size, average particle diameter of 1 nm for 0.5 wt% Pt in both cases). The case of a SiO2 support was also discussed. Those Pt/SiC particles were the most active because of their higher contribution of surface Pt0, indicating that partially oxidized surfaces have better activity than those totally oxidized in these conditions. SiC was modified with an acid treatment and thus bigger (average particle diameter of 7 nm for 0.5 wt% Pt) and more active Pt particles were obtained. Durability of the SiC and TiO2 supported catalysts was tested upon 5 cycles and both have shown to be durable and even more active than initially. Exposure to the oxidative reaction mixture activates the catalysts and the effect is more pronounced for the completely oxidized particles. This is due to the surface oxygen chemisorption which activates catalystś surface.Junta de Andalucía PE2012-TEP862Ministerio de Economía y Competitividad CTQ2012-32519, CTQ2015-65918-RConsejo Superior de Investigaciones Científicas PIE-201460E01

White dwarfs as test objects of Lorentz violations

In the present work the thermodynamical properties of bosonic and fermionic gases are analyzed under the condition that a modified dispersion relation is present. This last condition implies a breakdown of Lorentz symmetry. The implications upon the condensation temperature will be studied, as well, as upon other thermodynamical variables such as specific heat, entropy, etc. Moreover, it will be argued that those cases entailing a violation of time reversal symmetry of the motion equations could lead to problems with the concept of entropy. Concerning the fermionic case it will be shown that Fermi temperature suffers a modification due to the breakdown of Lorentz symmetry. The results will be applied to white dwarfs and the consequences upon the Chandrasekhar mass--radius relation will be shown. The possibility of resorting to white dwarfs for the testing of modified dispersion relations is also addressed. It will be shown that the comparison of the current observations against the predictions of our model allows us to discard some values of one of the parameters appearing in the modifications of the dispersion relation.Comment: Accepted in Classical and Quantum Gravitatio

Centralized vs Decentralized Markets in the Laboratory: The Role of Connectivity

This paper compares the performance of centralized and decentralized markets experimentally. We constrain trading exchanges to happen on an exogenously predetermined network, representing the trading relationships in markets with differing levels of connectivity. Our experimental results show that, despite having lower trading volumes, decentralized markets are generally not less efficient. Although information can propagate quicker through highly connected markets, we show that higher connectivity also induces informed traders to trade faster and exploit further their information advantages before the information becomes fully incorporated into prices. This not only reduces market efficiency, but it increases wealth inequality. We show that, in more connected markets, informed traders trade not only relatively quicker, but also more, in the right direction, despite not doing it at better prices

Teaching Early Prevention of Substance Abuse

There has been an increase in youth substance abuse in the US. Research shows that substance abuse leads to consequences such as lower education, lower opportunities to succeed, and overdoses (Freeman et al., 2018). Use of alcohol, marijuana and prescription drugs can also lead to use of heavier drugs like heroin, cocaine, and methenamine that have higher addiction rates (Freeman et al., 2018). One solution is to create early prevention programs that target children before they are heavily exposed to alcohol and drugs. For my capstone project, I presented a workshop to parents in South Monterey County on how they can communicate with their school-age children about alcohol and drugs and prevent them from using or abusing substances in the future. The workshop was designed for parents who work in agriculture and have low socioeconomic status. It was conducted through the non-profit organization, Sun Street Centers, in Gonzales, California

Pioneer Anomaly: Evaluating Newly Recovered Data

The Pioneer 10/11 spacecraft yielded the most precise navigation in deep space to date. However, their radio-metric tracking data received from the distances between 20--70 astronomical units from the Sun consistently indicated the presence of a small, anomalous, Doppler frequency drift. The drift is a blue frequency shift that can be interpreted as a sunward acceleration of a_P = (8.74 +/- 1.33) x 10^(-10) m/s^2 for each particular spacecraft. This signal has become known as the Pioneer anomaly; the nature of this anomaly remains unexplained. New Pioneer 10 and 11 radio-metric Doppler data recently became available. The much extended set of Pioneer Doppler data is the primary source for new upcoming investigation of the anomaly. We also have almost entire records of flight telemetry files received from the the Pioneers. Together with original project documentation and newly developed software tools, this additional information is now used to reconstruct the engineering history of both spacecraft. To that extent, a thermal model of the Pioneer vehicles is being developed to study possible contribution of thermal recoil force acting on the two spacecraft. In addition, to improve the accuracy of orbital reconstruction, we developed a new approach that uses actual flight telemetry data during trajectory analysis of radio-metric Doppler files. The ultimate goal of these efforts is to investigate possible contributions of the thermal recoil force to the detected anomalous acceleration.Comment: 12 pages, 15 figures, invited talk at the "III Mexican Meeting on Mathematical and Experimental Physics," Mexico City, Mexico, 10-14 September 200