14,201 research outputs found
Theoretical study of the finite temperature spectroscopy in van der Waals clusters. III Solvated Chromophore as an effective diatomics
The absorption spectroscopy of calcium-doped argon clusters is described in
terms of an effective diatomics molecule Ca-(Ar_n), in the framework of
semiclassical vertical transitions. We show how, upon choosing a suitable
reaction coordinate, the effective finite-temperature equilibrium properties
can be obtained for the ground- and excited-surfaces from the potential of mean
force (PMF). An extension of the recent multiple range random-walk method is
used to calculate the PMF over continuous intervals of distances. The
absorption spectra calculated using this single-coordinate description are
found to be in good agreement with the spectra obtained from high-statistics
Monte Carlo data, in various situations. For CaAr, we compare the
performances of two different choices of the reaction coordinate. For CaAr_37,
the method is seen to be accurate enough to distinguish between different
low-energy structures. Finally, the idea of casting the initial many-body
problem into a single degree of freedom problem is tested on the spectroscopy
of calcium in bulk solid argon.Comment: 8 pages, 9 figure
Theoretical study of finite temperature spectroscopy in van der Waals clusters. I. Probing phase changes in CaAr_n
The photoabsorption spectra of calcium-doped argon clusters CaAr_n are
investigated at thermal equilibrium using a variety of theoretical and
numerical tools. The influence of temperature on the absorption spectra is
estimated using the quantum superposition method for a variety of cluster sizes
in the range 6<=n<=146. At the harmonic level of approximation, the absorption
intensity is calculated through an extension of the Gaussian theory by Wadi and
Pollak [J. Chem. Phys. vol 110, 11890 (1999)]. This theory is tested on simple,
few-atom systems in both the classical and quantum regimes for which highly
accurate Monte Carlo data can be obtained. By incorporating quantum anharmonic
corrections to the partition functions and respective weights of the isomers,
we show that the superposition method can correctly describe the
finite-temperature spectroscopic properties of CaAr_n systems. The use of the
absorption spectrum as a possible probe of isomerization or phase changes in
the argon cluster is discussed at the light of finite-size effects.Comment: 17 pages, 9 figure
Manipulation of single-photon states encoded in transverse spatial modes: possible and impossible tasks
Controlled generation and manipulation of photon states encoded in their
spatial degrees of freedom is a crucial ingredient in many quantum information
tasks exploiting higher-than-two dimensional encoding. Here, we prove the
impossibility to arbitrarily modify -level state superpositions (quits)
for , encoded in the transverse modes of light, with optical components
associated to the group of symplectic transforms (Gaussian operations).
Surprisingly, we also provide an explicit construction of how non-Gaussian
operations acting on mode subspaces do enable to overcome the limit . In
addition, this set of operations realizes the full SU(3) algebra.Comment: Published in PR
Uniform non-stoichiometric titanium nitride thin films for improved kinetic inductance detector array
We describe the fabrication of homogeneous sub-stoichiometric titanium
nitride films for microwave kinetic inductance detector (mKID) arrays. Using a
6 inch sputtering target and a homogeneous nitrogen inlet, the variation of the
critical temperature over a 2 inch wafer was reduced to <25 %. Measurements of
a 132-pixel mKID array from these films reveal a sensitivity of 16 kHz/pW in
the 100 GHz band, comparable to the best aluminium mKIDs. We measured a noise
equivalent power of NEP = 3.6e-15 W/Hz^(1/2). Finally, we describe possible
routes to further improve the performance of these TiN mKID arrays.Comment: 7 pages, 4 figures, submitted to Journal of low temperature physics,
Proceedings of LTD-1
Measuring two-photon orbital angular momentum entanglement
We put forward an approach to estimate the amount of bipartite spatial
entanglement of down-converted photon states correlated in orbital angular
momentum and the magnitude of the transverse (radial) wave vectors. Both
degrees of freedom are properly considered in our framework, which only
requires azimuthal local linear optical transformations and mode selection
analysis with two fiber detectors. The coincidence distributions predicted by
our approach give an excellent fit to the distributions measured in a recent
experiment aimed to show the very high-dimensional transverse entanglement of
twin photons from a down-conversion source. Our estimate for the Schmidt number
is substantially lower but still confirms the presence of high-dimensional
entanglement.Comment: Extended paper of a published version in PRA, with some extra
appendice
Mapping the structural diversity of C60 carbon clusters and their infrared spectra
The current debate about the nature of the carbonaceous material carrying the
infrared (IR) emission spectra of planetary and proto-planetary nebulae,
including the broad plateaus, calls for further studies on the interplay
between structure and spectroscopy of carbon-based compounds of astrophysical
interest. The recent observation of C60 buckminsterfullerene in space suggests
that carbon clusters of similar size may also be relevant. In the present work,
broad statistical samples of C60 isomers were computationally determined
without any bias using a reactive force field, their IR spectra being
subsequently obtained following local optimization with the
density-functional-based tight-binding theory. Structural analysis reveals four
main structural families identified as cages, planar polycyclic aromatics,
pretzels, and branched. Comparison with available astronomical spectra
indicates that only the cage family could contribute to the plateau observed in
the 6-9 micron region. The present framework shows great promise to explore and
relate structural and spectroscopic features in more diverse and possibly
hydrogenated carbonaceous compounds, in relation with astronomical
observations
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