21 research outputs found

    Total Organic Carbon and the Contribution From Speciated Organics in Cloud Water: Airborne Data Analysis From the CAMP2Ex Field Campaign

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    This work focuses on total organic carbon (TOC) and contributing species in cloud water over Southeast Asia using a rare airborne dataset collected during NASA’s Cloud, Aerosol and Monsoon Processes Philippines Experiment (CAMP2Ex), in which a wide variety of maritime clouds were studied, including cumulus congestus, altocumulus, altostratus, and cumulus. Knowledge of TOC masses and their contributing species is needed for improved modeling of cloud processing of organics and to understand how aerosols and gases impact and are impacted by clouds. This work relies on 159 samples collected with an axial cyclone cloudwater collector at altitudes of 0.2–6.8 km that had sufficient volume for both TOC and speciated organic composition analysis. Species included monocarboxylic acids (glycolate, acetate, formate, and pyruvate), dicarboxylic acids (glutarate, adipate, succinate, maleate, and oxalate), methanesulfonic acid (MSA), and dimethylamine (DMA). TOC values range between 0.018 and 13.66 ppm C with a mean of 0.902 ppm C. The highest TOC values are observed below 2 km with a general reduction aloft. An exception is samples impacted by biomass burning for which TOC remains enhanced at altitudes as high as 6.5 km (7.048 ppm C). Estimated total organic matter derived from TOC contributes a mean of 30.7 % to total measured mass (inorganics + organics). Speciated organics contribute (on a carbon mass basis) an average of 30.0 % to TOC in the study region and account for an average of 10.3 % to total measured mass. The order of the average contribution of species to TOC, in decreasing contribution of carbon mass, is as follows (±1 standard deviation): acetate (14.7 ± 20.5 %), formate (5.4 ± 9.3 %), oxalate (2.8 ± 4.3 %), DMA (1.7 ± 6.3 %), succinate (1.6 ± 2.4 %), pyruvate (1.3 ± 4.5 %), glycolate (1.3 ± 3.7 %), adipate (1.0 ± 3.6 %), MSA (0.1 ± 0.1 %), glutarate (0.1 ± 0.2 %), and maleate (\u3c 0.1 ± 0.1 %). Approximately 70 % of TOC remains unaccounted for, highlighting the complex nature of organics in the study region; in samples collected in biomass burning plumes, up to 95.6 % of TOC mass is unaccounted for based on the species detected. Consistent with other regions, monocarboxylic acids dominate the speciated organic mass (∼ 75 %) and are about 4 times more abundant than dicarboxylic acids. Samples are categorized into four cases based on backtrajectory history, revealing source-independent similarity between the bulk contributions of monocarboxylic and dicarboxylic acids to TOC (16.03 %–23.66 % and 3.70 %–8.75 %, respectively). Furthermore, acetate, formate, succinate, glutarate, pyruvate, oxalate, and MSA are especially enhanced during biomass burning periods, which is attributed to peat emissions transported from Sumatra and Borneo. Lastly, dust (Ca2+) and sea salt (Na+/Cl−) tracers exhibit strong correlations with speciated organics, supporting how coarse aerosol surfaces interact with these water-soluble organics

    Tradiciones hispanas en las Filipinas

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    Hispanic influences on the West Visayan folk song tradition of the Philippines / by Enrique Cantel Cainglet

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    Typescript (photocopy)2 v. : ill., (part col.), maps (part fold.), music ; 30 cm.Thesis (Ph.D.)--University of Adelaide, Elder Conservatorium of Music, 198

    EC4IT - A Guide to European Commission Projects for CERN/IT department

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    European Commission (EC) projects represent an important source of external funding for a number of activities in which IT department is involved. The EC has a set of procedures and formalities for the preparation, negotiation, execution and completion of projects that are different to those normally used at CERN. This document gives an overview of the administrative, financial, reporting and managerial steps involved in participating in an EC project

    Regulation of biofilm formation via phosphorelay and quorum-sensing system in Vibrio cholerae

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    内容の要約博士(学術)Doctor of Philosophy広島大学Hiroshima Universit

    Organic polyelectrolytes as the sole precipitation agent in municipal wastewater treatment

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    Abstract In municipal wastewater treatment, inorganic coagulants (IC), e.g. polyaluminium chloride (PAC), are normally used to remove pollutants such as dissolved and particulate nutrients, in a process called coagulation/flocculation. However, IC use has been linked to issues e.g. in effluent water post-treatment, sludge management and disposal (IC increase sludge volume and metal concentrations in sludge), etc., raising uncertainties about their overall cost-efficiency and environmental benefits. In this study, the suitability of organic coagulants (OC) as sole precipitation agents to replace IC (PAC) was investigated. A total of 10 synthetic (i.e. polyDADMACs and polyamines) and semi-natural (chitosan, starch, and tannin-based) OC products were tested in treatment of samples from primary sedimentation and secondary sedimentation stages of municipal wastewater treatment, and their performance was compared with that of PAC. The study was conducted using the jar test methodology. The coagulants were tested for their ability to remove target pollutants (e.g. BOD₇, COD, SS, tot-P, PO₄-P, tot-N) and form rapidly settling flocs. In general, higher (up to 60%) coagulant doses were needed in treatment of secondary wastewater samples than primary samples. In comparison with the OC doses required for effective treatment, the PAC doses were higher (up to 80%). In treatment of secondary wastewater samples, OC with high molecular weight (MW) and high charge density (CD) (e.g. pAmine1) achieved best removal of target pollutants (e.g. 72% SS, 87% PO₄-P, 88% BOD₇), followed by PAC. In treatment of primary wastewater, PAC performed best (removing e.g. 96% SS, 96% PO₄-P), closely followed by chitosan and polyamine products. Based on these results, polyamine products with high MW and (very) high CDs have the potential to act as the sole precipitation agent in both primary and secondary stages of municipal wastewater treatment. Further research is needed to determine the effect of residual coagulant on downstream water and sludge treatment processes (e.g. activated sludge process, sludge dewatering, etc.)

    A systematic review on preferred aided augmentative and alternative communication system for requesting desired actions and objects by school-aged children with developmental disabilities

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    A systematic review was conducted to identify which aided augmentative and alternative communication (AAC) system (high technology or low technology) was more preferred by school-aged children with developmental disabilities when requesting for desired objects and actions. Inclusion and exclusion criteria and quality indicators had been set to filter journals to be used in the systematic review. Eleven (11) journals were gathered at the start of the study. After three (3) levels of review, six (6) journals satisfied the set inclusion and exclusion criteria. Among the 6 journals, a total of 25 children with varying cases, such as autism spectrum disorder, global developmental delay and intellectual disability, were assessed to find out the type of aided AAC system was most preferred. Children with development disabilities preferred using high technology AAC systems, such as a speech generating device (SGD), compared to low technology AAC systems, such as a picture exchange communication system (PECS), in which 64 (n=16) of the participants preferred high technology AAC system. Thirty-two percent (32%, n=8) of the participants chose low technology AAC system while one (1) child withdrew from the study. This research may not conclusively say that children with developmental disabilities preferred using high tech when requesting due to the type of journals gathered. However, it may be concluded that children with previous experience with the use of iPad, functional fine motor skills and high cognitive ability preferred high technology systems. More studies should be conducted for more valid and reliable results as there were only 25 participants in this study that did not represent quarter of the population of children with developmental disabilities
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