388 research outputs found

    Simulations of Extreme-Mass-Ratio Inspirals Using Pseudospectral Methods

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    Extreme-mass-ratio inspirals (EMRIs), stellar-mass compact objects (SCOs) inspiralling into a massive black hole, are one of the main sources of gravitational waves expected for the Laser Interferometer Space Antenna (LISA). To extract the EMRI signals from the expected LISA data stream, which will also contain the instrumental noise as well as other signals, we need very accurate theoretical templates of the gravitational waves that they produce. In order to construct those templates we need to account for the gravitational backreaction, that is, how the gravitational field of the SCO affects its own trajectory. In general relativity, the backreaction can be described in terms of a local self-force, and the foundations to compute it have been laid recently. Due to its complexity, some parts of the calculation of the self-force have to be performed numerically. Here, we report on an ongoing effort towards the computation of the self-force based on time-domain multi-grid pseudospectral methods.Comment: 6 pages, 4 figures, JPCS latex style. Submitted to JPCS (special issue for the proceedings of the 7th International LISA Symposium

    Electrochemical synthesis of peroxomonophosphate using boron-doped diamond anodes

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    A new method for the synthesis of peroxomonophosphate, based on the use of boron-doped diamond electrodes, is described. The amount of oxidant electrogenerated depends on the characteristics of the supporting media (pH and solute concentration) and on the operating conditions (temperature and current density). Results show that the pH, between values of 1 and 5, does not influence either the electrosynthesis of peroxomonophosphate or the chemical stability of the oxidant generated. Conversely, low temperatures are required during the electrosynthesis process to minimize the thermal decomposition of peroxomonophosphate and to guarantee significant oxidant concentration. In addition, a marked influence of both the current density and the initial substrate is observed. This observation can be explained in terms of the contribution of hydroxyl radicals in the oxidation mechanisms that occur on diamond surfaces. In the assays carried out below the water oxidation potential, the generation of hydroxyl radicals did not take place. In these cases, peroxomonophosphate generation occurs through a direct electron transfer and, therefore, at these low current densities lower concentrations are obtained. On the other hand, at higher potentials both direct and hydroxyl radical-mediated mechanisms contribute to the oxidant generation and the process is more efficient. In the same way, the contribution of hydroxyl radicals may also help to explain the significant influence of the substrate concentration. Thus, the coexistence of both phosphate and hydroxyl radicals is required to ensure the generation of significant amounts of peroxomonophosphoric acid

    Absence of charge backscattering in the nonequilibrium current of normal-superconductor structures

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    We study the nonequilibrium transport properties of a normal-superconductor-normal structure, focussing on the effect of adding an impurity in the superconducting region. Current conservation requires the superfluid velocity to be nonzero, causing a distortion of the quasiparticle dispersion relation within the superconductor. For weakly reflecting interfaces we find a regime of intermediate voltages in which Andreev transmission is the only permitted mechanism for quasiparticles to enter the superconductor. Impurities in the superconductor can only cause Andreev reflection of these quasiparticles and thus cannot degrade the current. At higher voltages, a state of gapless superconductivity develops which is sensitive to the presence of impurities.Comment: Latex file, 11 pages, 2 figures available upon request [email protected], to be published in Journal of Physics: Condensed Matte

    Method for monitoring urea and ammonia in wine and must by flow injection-pervaporation

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    An easy to automate flow-injection-pervaporation method for monitoring urea and ammonia in must and wine was developed. The method is based on separation of the ammonia from the sample matrix by pervaporation followed by its reaction with salicylate, hypochlorite and nitroprusside to form a diazonium salt with maximum absorption at 647 nm. Conversion of urea into ammonia catalysed by urease was mandatory before pervaporation. After optimisation by either the univariate or multivariate approaches as required, the linear range was established (between 0 and 25 mg l-1) for both analytes. Then, the assessment of the proposed method versus a reference one for urea and ammonia was studied in terms of repeatability (0.52 mg l-1 and 0.43 mg l-1, respectively), reproducibility (1.34 mg l-1 and 1.21 mg l-1, respectively), detection and quantification limits (LOD=0.9 and 0.6 mg l-1, LQ=1.02 and 0.67 mg l-1, respectively) and traceability. The sample throughput was 16 samples h-1. The method can be applied to the monitoring of the target analytes in must and young wine in order to control their contents, preventing formation of ethyl carbamate

    A comparison of electrochemical degradation of phenol on boron doped diamond and lead dioxide anodes

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    This work compares two electrode materials used to mineralize phenol contained in waste waters. Two disks covered with either boron doped diamond (BDD) or PbO2 were used as anodes in a one compartment flow cell under the same hydrodynamic conditions. Efficiencies of galvanostatic electrolyses are compared on the basis of measurements of Total Organic Carbon (TOC) and Chemical Oxygen Demand (COD). Galvanostatic electrolyses were monitored by analysis of phenol and of its oxidation derivatives to evaluate the operating time needed for complete elimination of toxic aromatics. The experimental current efficiency is close to the theoretical value for the BDD electrode. Other parameters being equal, phenol species disappeared at the same rate using the two electrode materials but the BDD anode showed better efficiency to eliminate TOC and COD. Moreover, during the electrolysis less intermediates are formed with BDD compared to PbO2 whatever the current density. A comparison of energy consumption is given based on the criterion of 99% removal of aromatic compounds

    An Efficient Pseudospectral Method for the Computation of the Self-force on a Charged Particle: Circular Geodesics around a Schwarzschild Black Hole

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    The description of the inspiral of a stellar-mass compact object into a massive black hole sitting at a galactic centre is a problem of major relevance for the future space-based gravitational-wave observatory LISA (Laser Interferometer Space Antenna), as the signals from these systems will be buried in the data stream and accurate gravitational-wave templates will be needed to extract them. The main difficulty in describing these systems lies in the estimation of the gravitational effects of the stellar-mass compact object on his own trajectory around the massive black hole, which can be modeled as the action of a local force, the self-force. In this paper, we present a new time-domain numerical method for the computation of the self-force in a simplified model consisting of a charged scalar particle orbiting a nonrotating black hole. We use a multi-domain framework in such a way that the particle is located at the interface between two domains so that the presence of the particle and its physical effects appear only through appropriate boundary conditions. In this way we eliminate completely the presence of a small length scale associated with the need of resolving the particle. This technique also avoids the problems associated with the impact of a low differentiability of the solution in the accuracy of the numerical computations. The spatial discretization of the field equations is done by using the pseudospectral collocation method and the time evolution, based on the method of lines, uses a Runge-Kutta solver. We show how this special framework can provide very efficient and accurate computations in the time domain, which makes the technique amenable for the intensive computations required in the astrophysically-relevant scenarios for LISA.Comment: 15 pages, 9 figures, Revtex 4. Minor changes to match published versio

    Voltage Stability Analysis of Grid-Connected Wind Farms with FACTS: Static and Dynamic Analysis

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    Recently, analysis of some major blackouts and failures of power system shows that voltage instability problem has been one of the main reasons of these disturbances and networks collapse. In this paper, a systematic approach to voltage stability analysis using various techniques for the IEEE 14-bus case study, is presented. Static analysis is used to analyze the voltage stability of the system under study, whilst the dynamic analysis is used to evaluate the performance of compensators. The static techniques used are Power Flow, V–P curve analysis, and Q–V modal analysis. In this study, Flexible Alternating Current Transmission system (FACTS) devices- namely, Static Synchronous Compensators (STATCOMs) and Static Var Compensators (SVCs) - are used as reactive power compensators, taking into account maintaining the violated voltage magnitudes of the weak buses within the acceptable limits defined in ANSI C84.1. Simulation results validate that both the STATCOMs and the SVCs can be effectively used to enhance the static voltage stability and increasing network loadability margin. Additionally, based on the dynamic analysis results, it has been shown that STATCOMs have superior performance, in dynamic voltage stability enhancement, compared to SVCs

    Electron Probe Microanalysis of the Otolithic Membrane. A Methodological and Quantitative Study

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    The effect of tissue preparation on calcium and potassium weight percents in the otoconial layer in the utricle and saccule was studied in four groups of OF1 mice with electron probe X-ray microanalysis. Glutaraldehyde and freeze-drying, glutaraldehyde and air-drying, air-drying, and cryo-fixation and freeze-drying were compared. Ca and K changed significantly in the utricle depending on the method used (P \u3c 0.001), and K changed significantly in the saccule (P \u3c 0.001 ). We chose cryo-fixation with freeze-drying for the quantitative analysis of the otolithic membrane because this method provided the highest values of Ca and K with minimum loss of Ca and K . Microcrystalline salt standards mounted on scanning electron microscopy holders were used for the quantification of Ca and K by the peak-to-local-background (P/B) ratio method. The P/B ratio in standards with reproducible results, when plotted against weight percent, gave a straight line for Ca (r = 0.99, P \u3c 0.001) and K (r = 0.98, P \u3c 0.001). The Ca and K weight percents in otoconia showed similar frequency distributions in the utricle and saccule

    Understanding the importance of transient resonances in extreme mass ratio inspirals

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    Extreme mass ratio inspirals (EMRIs) occur when a compact object orbits a much larger one, like a solar-mass black hole around a supermassive black hole. The orbit has 3 frequencies which evolve through the inspiral. If the orbital radial frequency and polar frequency become commensurate, the system passes through a transient resonance. Evolving through resonance causes a jump in the evolution of the orbital parameters. We study these jumps and their impact on EMRI gravitational-wave detection. Jumps are smaller for lower eccentricity orbits; since most EMRIs have small eccentricities when passing through resonances, we expect that the impact on detection will be small. Neglecting the effects of transient resonances leads to a loss of ~4% of detectable signals for an astrophysically motivated population of EMRIs.Comment: 2 pages, 0 figures; to appear in the proceedings of the 11th International LISA Symposiu
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