Investigations of nickel (II) removal from aqueous effluents using electric arc furnace slag

The tendency of electric arc furnace (EAF) slag to the adsorb nickel(II) from aqueous solution has been investigated through batch experiments. Scanning electron microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR) and Energy Dispersive X-Ray (EDX) Analysis. Analysis was characterized in order to give inside to the properties of electric arc furnace slag (EAFS). The adsorption result revealed that the maximum up take by the EAFS was 160.92mg/g at an equilibrium time of 216hr. The pseudo-second order kinetic fitted well with the kinetic data, showing a high determination coefficient (R2) of over 0.996. The adsorption isotherms of nickel(II) on this adsorbent for both linear and non linear isotherms were well described by Langmuir model, this is because it shown a good fitting to the experimental data when compared to other isotherm models. Moreover the nickel(II) adsorption was found to be dependent on the adsorbent dosage, contact time and initial metal ion concentration. From the result it can be deduced that EAFS could be used to effectively adsorb nickel(II) from aqueous solution

Dirac operators and the Very Strange Formula for Lie superalgebras

Using a super-affine version of Kostant's cubic Dirac operator, we prove a very strange formula for quadratic finite-dimensional Lie superalgebras with a reductive even subalgebra.Comment: Latex file, 25 pages. A few misprints corrected. To appear in the forthcoming volume "Advances in Lie Superalgebras", Springer INdAM Serie

Recent trends in biodiesel production from commonly used animal fats

Changes in climate due to the enormous amount of carbon dioxide emissions have really encouraged the development of energy sources that are renewable, sustainable, and eco-friendly. The development of alternative energy sources can also be attributed to the rapid decrease in resources of fossil energy. Biodiesel has gained significant interest in recent years due to its fossil fuel–like properties and sustainable and eco-friendly characteristics. However, most biodiesels are expensive because of the high cost of feedstock largely based on edible vegetable oil sources. The use of animal fats waste as cost effective feedstock in biodiesel production has gained considerable attention in recent years. Although, most studies regarding the use of animal wastes as feedstock in biodiesel production are still in the early stages, the advantages of this type of feedstock have been highlighted in the literature. However, most studies have not focus on the recent advances in the use of animal fats waste. The studies on the use of novel approach have been reported in isolation. Therefore, this current study attempts to highlight recent developments of the most commonly used animal fats waste in the production of biodiesel. In addition, emphasis was given to the most appropriate production technique, catalyst, energy requirement, and optimum reaction conditions

Whole exome sequencing of extreme morbid obesity patients: translational implications for obesity and related disorders

Whole-exome sequencing (WES) is a new tool that allows the rapid, inexpensive and accurate exploration of Mendelian and complex diseases, such as obesity. To identify sequence variants associated with obesity, we performed WES of family trios of one male teenager and one female child with severe early-onset obesity. Additionally, the teenager patient had hypopituitarism and hyperprolactinaemia. A comprehensive bioinformatics analysis found de novo and compound heterozygote sequence variants with a damaging effect on genes previously associated with obesity in mice (LRP2) and humans (UCP2), among other intriguing mutations affecting ciliary function (DNAAF1). A gene ontology and pathway analysis of genes harbouring mutations resulted in the significant identification of overrepresented pathways related to ATP/ITP (adenosine/inosine triphosphate) metabolism and, in general, to the regulation of lipid metabolism. We discuss the clinical and physiological consequences of these mutations and the importance of these findings for either the clinical assessment or eventual treatment of morbid obesity.Gilberto Paz-Filho, Margaret C.S. Boguszewski, Claudio A. Mastronardi, Hardip R. Patel, Angad S. Johar, Aaron Chuah, Gavin A. Huttley, Cesar L. Boguszewski, Ma-Li Wong, Mauricio Arcos-Burgos and Julio Licini

LEAF: Logger for ecological and atmospheric factors

The fields of meteorology, surface- and groundwater hydrology, and forestry are often decoupled despite the fact that they occur simultaneously at the intersection of living systems and the physical environment. In this work, we describe a system that allows concurrent measurement of canopy throughfall, transpiration, air temperature, pressure, and humidity at multiple heights, in addition to soil moisture and several surface water parameters. LEAF is designed to be generalizable to many other hydrology and meteorology applications, and is modular such that it is easily adaptable for use with additional, diverse environmental monitoring sensors. This low-cost, light-weight, solar-powered system is capable of simultaneous streaming telemetry as well as local data logging via SD card.Office of the VP for Researc

Effect of dilution and operating parameters on ammonia removal from scheduled waste landfill leachate in a lab-scale ammonia stripping reactor

A lab-scale ammonia stripping reactor was used to treat raw and diluted (1:1) scheduled waste landfill (SWL) leachate containing ammonia-nitrogen (NH3-N). Operating parameters such as air-liquid ratio, hydrated lime [Ca(OH)2] dosage, types of packing materials and packing heights were investigated with central composite design (CCD) of response surface methodology (RSM) was used to optimize the parameters affecting NH3-N removal from the leachate. The percentage removal on turbidity, colour and phosphate were also evaluated in this study. It was observed that the optimal conditions obtained from desirable response (NH3-N removal) for raw leachate were predicted at air–liquid ratio of 70, Ca(OH)2 dosage of 5 gL-1, packing height of 60 cm and types of packing material was number 3 (nonwoven polyester) while for diluted leachate these were 70, 6 gL-1, 60 cm and Type 3 (nonwoven polyester), respectively. Quadratic RSM predicted the maximum NH3-N removal to be 78% for raw leachate and 81% for diluted leachate at these optimal conditions concurred with the experiment which successfully removed 76% and 80% of NH3-N, respectively. However, higher removal efficiencies of turbidity (97%), colour (88%) and phosphate (93%) was observed in the treatment with diluted leachate compared to raw leachate merely up to 55%, 34% and 49%, respectively. The finding showed that the difference in the removal of NH3-N in diluted and raw SWL leachate was insignificant. However, turbidity, colour and phosphate showed a significant reduction in the diluted leachate during the treatment. The study suggests that the dilution of SWL leachate does not present a significant effect on the removal of ammonia in the stripping reactor

Structural thermal stability of graphene oxide-doped copper-cobalt oxide coatings as a solar selective surface

3d transition metal oxides based thin film coatings such as copper-cobalt oxides exhibit high absorption in the visible region and low emittance in the infra-red to far-infra-red region of the solar spectrum which is favourable for use as potential selective surface materials in photothermal devices. These materials have the potential to minimize heating while increasing absorption in the operative spectrum range and therefore achieve higher solar selectivity. A series of mixed copper-cobalt metal spinel oxides (CuxCoyOz) doped with graphene oxide thin films were deposited on commercial grade aluminium substrates using a sol–gel dip-coating technique at an annealing temperature of 500 °C in air for 1 h. Characterizations of the synthesized films were carried out by high temperature synchrotron radiation X-ray Diffraction (SR-XRD), UV-Vis, Fourier Transform infrared spectroscopy (FTIR) and X-ray photoelectron microscopy (XPS) techniques. High thermal stability of coatings with multiple phases, binary and ternary metal oxides, was defined through SR-XRD study. FTIR analysis shows moderate (<80%) to high (up to 99%) reflectance in the infra-red region while the UV-Vis investigations demonstrate that, in the visible region, solar absorption increases gradually (up to 95%) with the addition of graphene oxide to the CuxCoyOz coatings. With the incorporation of 1.5 wt% of graphene oxide to the copper-cobalt oxide coatings, a high solar selectivity of 29.01 (the ratio of the average solar absorptance in visible and the average thermal emittance in infra-red to far infra-red region; α/ε) was achieved

Modelling of rheological behaviour of pummelo juice concentrates using master-curve

The rheological behaviour of freeze-dried-concentrated pummelo juice was modelled to investigate the effects of temperature and concentration on its fluid type and viscosity using a rotational viscometer at shear rates ranging from 1 to 400 s-1. The effect of concentration measured by its total soluble solids content resulted in the juice concentrates behaving towards shear thinning or pseudoplastic behaviour with flow behaviour index values, n0.98

An Integrated TCGA Pan-Cancer Clinical Data Resource to Drive High-Quality Survival Outcome Analytics

For a decade, The Cancer Genome Atlas (TCGA) program collected clinicopathologic annotation data along with multi-platform molecular profiles of more than 11,000 human tumors across 33 different cancer types. TCGA clinical data contain key features representing the democratized nature of the data collection process. To ensure proper use of this large clinical dataset associated with genomic features, we developed a standardized dataset named the TCGA Pan-Cancer Clinical Data Resource (TCGA-CDR), which includes four major clinical outcome endpoints. In addition to detailing major challenges and statistical limitations encountered during the effort of integrating the acquired clinical data, we present a summary that includes endpoint usage recommendations for each cancer type. These TCGA-CDR findings appear to be consistent with cancer genomics studies independent of the TCGA effort and provide opportunities for investigating cancer biology using clinical correlates at an unprecedented scale. Analysis of clinicopathologic annotations for over 11,000 cancer patients in the TCGA program leads to the generation of TCGA Clinical Data Resource, which provides recommendations of clinical outcome endpoint usage for 33 cancer types