Investigating photocatalytic activity of titania coated fresh water diatom frustules by the degradation of polluting dye

Silica frustules of diatoms contain nanoscale pores arranged in periodic order. In this report we have synthesized TiO2 nanoparticles coated diatom frustules followed by annealing at 500ºC. The as synthesized DT500 catalyst is characterized by X-ray diffraction (XRD), Scanning electron microscope (SEM) and EDX. UV-visible spectroscopy is performed to analyze the band gap (BG) energy of the material which is found to lie in the visible light range. The photocatalytic properties of the catalysts are investigated via typical polluting dye as a model organic compound under visible light irradiation. The as synthesized DT500 catalyst contains anatase phase of titania exhibited more light absorption in the visible region and found to have higher photocatalytic efficiency due to morphology of frustules and TiO2 coating

Photocatalytic Degradation of Methyl Orange using MoS2 nanoparticles as catalyst

MoS2 is a semiconductor transition metal dichalcogenide material (TMD) which has exciting optoelectronic properties. Due to its band gap (BG) energy lying in the visible range it shows good photocatalytic behavior. In this report, we have synthesized MoS2 nanoparticles (NPs) and its morphology is characterized using XRD and SEM. EDX is performed to analyze the composition of the as-synthesized material. Multiple BG energy in the visible light range is observed from the analysis of UV-Visible spectroscopy. We have investigated the photocatalytic property by the degradation of Methyl Orange (MO) using MoS2 nanoparticles as catalyst. It is observed that the as-synthesized MoS2 NPs degrade MO very efficiently with 98% degradation using 1mg in 1ml 10μM dye solution in 2hr

Microwave-promoted one-pot synthesis of 4H-thiopyrans from a,b-unsaturated ketones via a three-component reaction

—An efficient one-pot synthesis of substituted 4H-thiopyrans has been accomplished from a three-component reaction of a,b-unsaturated ketones, Lawesson’s reagent and alkynes under microwave irradiation

Short and Long-Term Sensitivity of Lab-Scale Thermocline Based Thermal Storage to Flow Disturbances

Molten-salt thermocline-based systems are a low-cost option for single-tank thermal energy storage in concentrated solar power plants. Due to the high variability in solar energy availability, these energy storage devices are subject to transient heat loads during charging that can affect the storage efficiency. Numerical simulations were conducted to analyze the stability characteristics of a lab-scale thermocline tank subject to a flow disturbance during charging under different operating temperatures. The charging process was first simulated at a constant Reynolds number for three different Atwood numbers; a stably stratified fluid layer develops inside the storage tank in all cases. A flow disturbance was then introduced at the inlet of the stratified thermocline tank by inserting colder fluid for a short period of time. The disturbance interacts with the thermocline and causes oscillations and mixing. The thermocline oscillations are under-damped and lead to an increase in thermocline region thickness. The transient behavior of the thermocline and the decay rate in its oscillations were analyzed; the damping time depends on the Atwood number. The persistence of flow disturbance effects during long-term cyclical operation was also investigated. Several charge/discharge cycles were simulated at constant Reynolds number to obtain a time-periodic thermal response for each Atwood number. The characteristic flow disturbance was introduced at the inlet during a single charging process, and the thermocline region was observed during several subsequent charge/discharge cycles to assess the long-term temporal attenuation of the disturbance. The thermocline almost fully recovers to the time-periodic behavior after a single cycle

Decision making under incompleteness based on soft set theory

[EN]Decision making with complete and accurate information is ideal but infrequent. Unfortunately, in most cases the available infor- mation is vague, imprecise, uncertain or unknown. The theory of soft sets provides an appropriate framework for decision making that may be used to deal with uncertain decisions. The aim of this paper is to propose and analyze an effective algorithm for multiple attribute decision-making based on soft set theory in an incomplete information environment, when the distribution of incomplete data is unknown. This procedure provides an accurate solution through a combinatorial study of possible cases in the unknown data. Our theoretical development is complemented by practical examples that show the feasibility and implementability of this algorithm. Moreover, we review recent research on decision making from the standpoint of the theory of soft sets under incomplete information

Synthesis of Ag nanoparticles using diatom cells for ammonia sensing

Growth of silver nanoparticles through photo induced bioreduction mechanism on the surface of diatom cells, which is a kind of photosensitive fresh water organism containing hydrated amorphous silica structure, has been found to be a cost-effective, rapid, non-toxic, eco-friendly, photo-induced bottom-up process. This material shows broad absorbance in the visible light spectra. Light sensitive fucoxanthin pigment of diatoms that contain hydroxyl (−OH) groups, play a vital role in the formation of silver cluster on the surface of diatom cells and its growth process. Involvement of the compounds and proteins of the diatoms which are responsible for reduction of metal ions and stabilization of the grown nanoparticles on diatom cells, are confirmed by FTIR analysis. Investigations are done to see if the synthesized samples acted as sensing material in the fabrication of a room temperature sensor of dissolved ammonia. With increase in ammonia concentration the visible light absorption peaks tend to higher intensity with blue shift due to the formation of [Ag(NH3)2]+ complexes causing repulsion between the Ag nanoparticles and consequently lead to the formation of smaller Ag nanoparticles. The intensity of absorption of the as-synthesized material is linearly correlated with the concentration of dissolved ammonia as observed from 0 to 100ppm. The use of naturally occurring diatoms for Ag nanoparticles synthesis has the benefits of amenability for large-scale easy production. Also the experimental findings indicate that the as-synthesized material can act as fast and reliable sensing material. Keywords: Diatoms, Fucoxanthin, Silver nanoparticles, Ammonia senso

Ionic liquid accelerated intramolecular hetero-Diels-Alder reactions: a protocol for the synthesis of octahydroacridines

2-Azadienes derived in situ from arylamines and (R)-(+)-citronellal/3-methylcitronellal undergo intramolecular [4+2] hetero-Diels-Alder reactions in the air and moisture stable ionic liquid [bmim]BF4 in the absence of any acid catalyst to afford 1,2,3,4,4a,9,9a,10-octahydroacridine derivatives in high to quantitative yields

Ruthenium monoterpyridine complexes with 2,6-bis(benzimidazol-2-yl)pyridine: Synthesis, spectral properties and structure

Ruthenium monoterpyridine complexes with the tridentate 2,6-bis(benzimidazol-2-yl)pyridine (LH2), [Ru(trpy)(LH2)](2+), [1](2+) and [Ru(trpy)(L2-)], 2 (trpy = 2,2':6',2 ''-terpyridine) have been synthesized. The complexes have been authenticated by elemental analyses, UV-Vis, FT-IR, H-1 NMR spectra and their single crystal X-ray structures. Complexes [1](2+) and 2 exhibit strong MLCT band near 475 and 509 nm, respectively, and are found to be very much dependent on solution pH. The successive pH dependent dissociations of the N-H protons of benzimidazole moiety of LH2 in [1](2+) lead to the formation of 2. The proton induced inter-convertibility of [1](2+) and 2 has been monitored via UV-Vis spectroscopy and redox features. The two pK(a) values, 5.75 and 7.70, for complex [1](2+) have been determined spectroscopically. (C) 200