Palladium catalyzed hydrodechlorination of *-chloroacetophenones by hydrogen transfer from the H2O-CO system

Advertisements for gambling products have historically been restricted due to their potential to normalize gambling and contribute to excessive gambling behaviours among vulnerable populations. However, social media enables gambling operators to promote products and brands with fewer constraints than in traditional forms of media. This study investigated how social media is used by gambling operators to promote gambling activities including an analysis of the latent messages that are conveyed. A representative sample of major land-based and online gambling venues and operators, including casinos, clubs, hotels, lottery and wagering operators (n = 101), was obtained. Websites and social media profiles of gambling operators were audited to investigate the types of social media used, content of promotions, and prevalence of responsible gambling messaging. The results showed that Facebook and Twitter were the dominant platforms used, most commonly by casinos and online wagering operators. A key finding was that online gambling operators included gambling content in conjunction with related news and events, as well as unrelated content, as way of normalizing gambling within a broader social context. Unlike land-based gambling promotions, responsible gambling information tended not to feature in operators’ posts and profiles. The key messages propagated in social media gambling promotions were positively framed, and tended to encourage gambling using a range of cross-promotional tactics to emphasize the winning aspect of gambling. The implications of freely accessible and pervasive gambling promotions via social media are discussed with respect to the general community as well as vulnerable populations.This study was commissioned by Gambling Research Australia—a partnership between the Commonwealth, State and Territory Governments. GRA had no involvement in the research design, conduct, analysis or the preparation of this paper

Assessment of ground-motion amplification in the Fucino Basin (Central Italy) through seismic data

The Fucino basin (Central Italy) is one of the largest intermountain alluvial plain in the Appennines range. It has a tectonic origin related to the presence of important systems of faults located in its northern and eastern edges. Some of these faults are still active and capable of generating strong seismic events as the January 13th 1915 Ms 7.0 Avezzano earthquake (about 30000 casualties). Site effects related to the soft soils filling the basin can be very important also taking into account the presence of historical villages located at the edges of the basin and new settlements developed in the area. In this paper we show the preliminary results of a seismic network installed in the Fucino area in order to collect information about site amplification effects and geometry of the basin. A lake occupied the Fucino basin for many thousands of years and it was completely drained at the end of the 19th century. We analyze ambient seismic vibrations and recordings of about 150 local earthquakes mainly related to the seismic sequence of the April 6th 2009 Mw 6.3 L’Aquila event. Moreover the strongest events of L’Aquila sequence were analyzed at the three strong-motion permanent stations operating in the area. Using standard spectral techniques we investigate the variation of resonance frequencies within the basin. The ground motion recorded in the Fucino plain is mainly characterized by strong energy at low-frequencies (f < 1 Hz) affecting both horizontal and vertical components. This is particularly evident for stations deployed in correspondence of very thick deposits of sedimentary filling, where a significant increase of ground-motion amplitude and duration is caused by locally generated surface waves. The amplification at low-frequencies (< 1 Hz) on the horizontal components can reach up a factor of 10 in comparison to nearby stiff sites. However, we found evidences of seismic amplification phenomena also for stiff sites surrounding the basin, including stations of the Italian strong motion network. The independent geological information, the shallow shear-velocity profiles available for the basin can be combined with resonance frequencies of the sites for deriving representative geological sections to be used as base for future numerical 2D-3D modeling of the seismic wave propagation in the basin. Seismic modeling can be important to reduce the seismic hazard in the area

Semi-continuous Chlorella vulgaris Cultivation Using Anaerobic Digestate Liquid Fraction Pre-treated by Ultrasonic Cavitation to Improve Carbon Dioxide Solubilization

Nutrients-enriched effluents such as digestate can represent a suitable and economically appealing substrate for microalgae growth since they combine the effluent treatment with biomass production. Then, microalgae biomass can be exploited to produce several bio-based compounds. However, the use of digestate for microalgae cultivation can be challenging due to its high levels of ammonia nitrogen and its low C/N ratio. For this reason, an ultrasonic cavitation (UC) process combined with carbon dioxide (CO2) insufflation was tested on digestate, in order to obtain a faster solubilization of the CO2 in the medium and thus an increase in the C/N ratio. The test was carried out growing Chlorella vulgaris on both digestate (mixotrophic condition) and BG-11 medium (autotrophic condition) in 1 L photobioreactors. For the first 14 days of the experiment the reactors were maintained in batch conditions to acclimatize microalgae. Then, they were switched to semi-continuous for 32 days. The reactors were fed three times a week, with an HRT (Hydraulic Retention Time) of 10.5 d as weekly average. Regarding the test on digestate, both UC pre-treated and untreated conditions reached the highest biomass production at the end of the batch (4.8 and 4.1 g L-1 respectively) and a complete ammonium (NH4+) removal after 9 days. The switch to semi-continuous caused an increase in NH4+ concentration and a consistent decrease in biomass concentration. Biomass production reached the steady-state, with a concentration of 1.9 and 1.2 g L-1 for the UC pre-treated and untreated digestate, respectively (+55.6 % biomass production obtained with UC pre-treated digestate). Moreover, an NH4+ removal of 93.5 % and 92.3 % was reached for UC pre-treated and untreated conditions, respectively

Assessment of ground-motion amplification in the Fucino Basin (Central Italy) through seismic data

The Fucino basin (Central Italy) is one of the largest intermountain alluvial plain in the Appennines range. It has a tectonic origin related to the presence of important systems of faults located in its northern and eastern edges. Some of these faults are still active and capable of generating strong seismic events as the January 13th 1915 Ms 7.0 Avezzano earthquake (about 30000 casualties). Site effects related to the soft soils filling the basin can be very important also taking into account the presence of historical villages located at the edges of the basin and new settlements developed in the area. In this paper we show the preliminary results of a seismic network installed in the Fucino area in order to collect information about site amplification effects and geometry of the basin. A lake occupied the Fucino basin for many thousands of years and it was completely drained at the end of the 19th century. We analyze ambient seismic vibrations and recordings of about 150 local earthquakes mainly related to the seismic sequence of the April 6th 2009 Mw 6.3 L’Aquila event. Moreover the strongest events of L’Aquila sequence were analyzed at the three strong-motion permanent stations operating in the area. Using standard spectral techniques we investigate the variation of resonance frequencies within the basin. The ground motion recorded in the Fucino plain is mainly characterized by strong energy at low-frequencies (f < 1 Hz) affecting both horizontal and vertical components. This is particularly evident for stations deployed in correspondence of very thick deposits of sedimentary filling, where a significant increase of ground-motion amplitude and duration is caused by locally generated surface waves. The amplification at low-frequencies (< 1 Hz) on the horizontal components can reach up a factor of 10 in comparison to nearby stiff sites. However, we found evidences of seismic amplification phenomena also for stiff sites surrounding the basin, including stations of the Italian strong motion network. The independent geological information, the shallow shear-velocity profiles available for the basin can be combined with resonance frequencies of the sites for deriving representative geological sections to be used as base for future numerical 2D-3D modeling of the seismic wave propagation in the basin. Seismic modeling can be important to reduce the seismic hazard in the area

Regional Seismic Characterization of Shallow Subsoil of Northern Apulia (Southern Italy)

A first-order seismic characterization of Northern Apulia (Southern Italy) has been provided by considering geological information and outcomes of a low-cost geophysical survey. In particular, 403 single-station ambient vibration measurements (HVSR techniques) distributed within the main settlements of the area have been considered to extract representative patterns deduced by Principal Component Analysis. The joint interpretation of these pieces of information allows the identification of three main domains (Gargano Promontory, Bradanic Through and Southern Apennines Fold and Thrust Belt), each characterized by specific seismic resonance phenomena. In particular, the Bradanic Through is homogeneously characterized by low frequency (&lt; 1 Hz) resonance effects associated with relatively deep (&gt; 100 m) seismic impedance, which is contrasting corresponding to the buried Apulian carbonate platform and/or sandy horizons located within the Plio-Pleistocene deposits. In the remaining ones, relatively high frequency (&gt; 1 Hz) resonance phenomena are ubiquitous due to the presence of shallower impedance contrasts (&lt; 100 m), which do not always correspond to the top of the geological bedrock. These general indications may be useful for a preliminary regional characterization of seismic response in the study area, which can be helpful for an effective planning of more detailed studies targeted to engineering purposes

Carbon monoxide–ethylene copolymerization catalyzed by a Pd(OAc)2/dppp/formic acid system [dppp=1,3-bis(diphenylphosphino)propane]

none3Polyketones are obtained by the copolymerization of carbon monoxide and ethylene in the presence of a palladium catalyst formed in situ from Pd(OAc)2, dppp and formic acid in methanol which acted as a solvent. The productivity (g polymer/g Pd* h) is significantly influenced by the concentration of formic acid. Using the ratio Pd/dppp/HCOOH=1/1/3000 at 90 °C and 45 atm, a productivity of 7500 h−1 is obtained. It is suggested that the efficiency of HCOOH as a promoter is due to its capability to act as a source of Pd-hydride species, which initiates the catalytic cycle.noneA. VAVASORI; CAVINATO G.; L. TONIOLOA., Vavasori; Cavinato, Gianni; L., Toniol