2,251 research outputs found
Imine Azaenolates: Synthesis, Reactivity, and Outlook
Azaenolates are, quite simply, the aza variant of enolates. Compared to their oxygen counterparts, additional control of the reactivity of azaenolates can be achieved by altering the substituent on the nitrogen atom as well as the metal counterion. Since the seminal examples reported in the early 1960s, azaenolates of various metals have been shown to react with a diverse set of electrophilic partners, including challenging electrophiles such as alkyl fluorides, epoxides, and oxetanes. This review describes in detail the current state of the art of the chemistry of azaenolates derived from imines, with a particular focus on the comparison of the reactivity exhibited with different metal counterions
Preliminary Analysis of the Metabolic Rate Monitor System
Metabolic rate monitor system analysi
Validation of a fiducial-based atlas localization method for deep brain stimulation contacts in the area of the subthalamic nucleus
Gluon fusion contribution to W+W- + jet production
We describe the computation of the process that contributes
to the production of two -bosons and a jet at the CERN Large Hadron Collider
(LHC). While formally of next-to-next-to-leading order (NNLO) in QCD, this
process can be evaluated separately from the bulk of NNLO QCD corrections
because it is finite and gauge-invariant. It is also enhanced by the large
gluon flux and by selection cuts employed in the Higgs boson searches in the
decay channel , as was first pointed out by Binoth {\it et al.}
in the context of production. For cuts employed by the ATLAS
collaboration, we find that the gluon fusion contribution to
enhances the background by about ten percent and can lead to moderate
distortions of kinematic distributions which are instrumental for the ongoing
Higgs boson searches at the LHC. We also release a public code to compute the
NLO QCD corrections to this process, in the form of an add-on to the package
{\tt MCFM}.Comment: 13 pages, 4 figures, 3 table
Cerebral blood flow responses to dorsal and ventral STN DBS correlate with gait and balance responses in Parkinson\u27s disease
Recovery-oriented practices within the Dartmouth Wellness Court: The Wall of Hope
This paper describes the Wall of Hope art installation as a product of recovery-oriented practices within the Dartmouth Wellness Court that contributes to a culture and language of hope within the courtroom environment
Organized crime and preventive justice
By comparison with the prevention of terrorism, the prevention of acts of organizedcrime might be thought easier to conceptualize precisely and less controversial to legislate against and police. This impression is correct up to a point, because it is possible to arrive at some general characteristics of organized crime, and because legislation against it is not obviously bedevilled by the risk of violating civil or political rights, as in the case of terrorism. But there is a significant residue of legal, moral and political difficulty: legislation against organized crime is hard to make effective; the harm of organized crime is not uniform, and so some preventive legislation seems too sweeping and potentially unjust. More fundamentally, the scale and rewards of organized crime are often dependent on mass public participation in markets for proscribed goods, which may point to a hidden public consensus in favour of some of what is criminalized. Preventive policing and legislation in both areas, then, are less easily justified than first appears
In Tribute: M. Katherine B. Darmer
The editors of the Chapman Law Review respectfully dedicate this issue to Professor M. Katherine B. Darmer
2003 Manifesto on the California Electricity Crisis
The authors, an ad-hocgroup of professionals with experience in regulatory and energy economics, share a common concern with the continuing turmoil facing the electricity industry ("the industry") in California. Most ofthe authorsendorsed the first California Electricity Manifesto issued on January 25, 2001. Almost two years have passed since that first Manifesto. While wholesale electric prices have moderated and California no longer faces the risk of blackouts, in many ways the industry is in worse shape now than it was at the start of 2001. As a result, the group of signatories continues to have a deep concern with the conflicting policy directions being pursued for the industry at both the State and Federal levels of government and the impact the uncertainties associated with these conflicting policies will have, long term, on the economy of California. Theauthorshave once again convened under the auspices of the Institute of Management, Innovation and Organization at the University of California, Berkeley, to put forward ourtheir ideas on a basic set of necessary policies to move the industry forward for the benefit of all Californians and the nation. The authors point out that theydo not pretend to be "representative." They do bring, however, a very diverse range of backgrounds and expertise.Technology and Industry, Regulatory Reform
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