Nitrous oxide generation in denitrifying phosphorus removal process: Main causes and control measures

Despite the many benefits of denitrifying phosphorus removal process, the significant generation of nitrous oxide (N2O), a potent greenhouse gas, remains a problem for this innovative and promising process. To better understand and more effectively control N2O generation in denitrifying phosphorus removal process, batch experiments were carried out to investigate the main causes of N2O generation, based on which the control measures were subsequently proposed. The results showed that N2O generation accounted for 0.41 % of the total nitrogen removal in denitrifying phosphorus removal process, whereas, in contrast, almost no N2O was generated in conventional denitrification process. It was further demonstrated that the weak competition of N2O reductase for electrons and the high nitrite accumulation were the two main causes for N2O generation, evidenced by N2O production and reduction rates under different conditions. Accordingly, the reduction of N2O generation was successfully achieved via two control measures: (1) the use of continuous nitrate addition reducing N2O generation by around 91.4 % and (2) the use of propionate as the carbon source reducing N2O generation by around 69.8 %. © 2013 Springer-Verlag Berlin Heidelberg

Characteristics of electron transport chain and affecting factors for thiosulfate-driven perchlorate reduction

© 2017 Elsevier Ltd The mechanism for perchlorate reduction was investigated using thiosulfate-driven (T-driven) perchlorate reduction bacteria. The influences of various environmental conditions on perchlorate reduction, including pH, temperature and electron acceptors were examined. The maximum perchlorate removal rate was observed at pH 7.5 and 40 °C. Perchlorate reduction was delayed due to the coexistence of perchlorate-chlorate and perchlorate-nitrate. The mechanism of the T-driven perchlorate reduction electron transport chain (ETC) was also investigated by utilizing different inhibitors. The results were as follows: firstly, the NADH dehydrogenase was not involved in the ETC; secondly, the FAD dehydrogenase and quinone loop participated in the ETC; and thirdly, cytochrome oxidase was the main pathway in the ETC. Meanwhile, microbial consortium structure analysis indicated that Sulfurovum which can oxidize sulfur compounds coupled to the reduction of nitrate or perchlorate was the primary bacterium in the T-driven and sulfur-driven consortium. This study generates a better understanding of the mechanism of T-driven perchlorate reduction

Automatic summarization of rushes video using bipartite graphs

In this paper we present a new approach for automatic summarization of rushes, or unstructured video. Our approach is composed of three major steps. First, based on shot and sub-shot segmentations, we filter sub-shots with low information content not likely to be useful in a summary. Second, a method using maximal matching in a bipartite graph is adapted to measure similarity between the remaining shots and to minimize inter-shot redundancy by removing repetitive retake shots common in rushes video. Finally, the presence of faces and motion intensity are characterised in each sub-shot. A measure of how representative the sub-shot is in the context of the overall video is then proposed. Video summaries composed of keyframe slideshows are then generated. In order to evaluate the effectiveness of this approach we re-run the evaluation carried out by TRECVid, using the same dataset and evaluation metrics used in the TRECVid video summarization task in 2007 but with our own assessors. Results show that our approach leads to a significant improvement on our own work in terms of the fraction of the TRECVid summary ground truth included and is competitive with the best of other approaches in TRECVid 2007

Removal of antibiotics (sulfamethazine, tetracycline and chloramphenicol) from aqueous solution by raw and nitrogen plasma modified steel shavings

© 2017 Elsevier B.V. The removal of sulfamethazine (SMT), tetracycline (TC) and chloramphenicol (CP) from synthetic wastewater by raw (M3) and nitrogen plasma modified steel shavings (M3-plN2) was investigated using batch experiments. The adsorption kinetics could be expressed by both pseudo-first-order kinetic (PFO) and pseudo-second-order kinetic (PSO) models, where correlation coefficient r2 values were high. The values of PFO rate constant k1p and PSO rate constant k2p decreased as SMT-M3 > SMT-M3-plN2 > TC-M3-plN2 > TC-M3 > CP-M3 > CP-M3-plN2 and SMT-M3 > SMT-M3-plN2 > TC-M3 > TC-M3-plN2 > CP-M3 > CP-M3-plN2, respectively. Solution pH, adsorbent dose and temperature exerted great influences on the adsorption process. The plasma modification with nitrogen gas cleaned and enhanced 1.7-fold the surface area and 1.4-fold the pore volume of steel shavings. Consequently, the removal capacity of SMT, TC, CP on the adsorbent rose from 2519.98 to 2702.55, 1720.20 to 2158.36, and 2772.81 to 2920.11 μg/g, respectively. Typical chemical states of iron (XPS in Fe2p3 region) in the adsorbents which are mainly responsible for removing antibiotics through hydrogen bonding, electrostatic and non- electrostatic interactions and redox reaction were as follows: Fe3O4/Fe2 +, Fe3O4/Fe3 +, FeO/Fe2 + and Fe2O3/Fe3 +

Food waste based biochars for ammonia nitrogen removal from aqueous solutions

© 2019 Elsevier Ltd Biochar derived from waste has been increasingly considered as a potential green adsorbent due to its significant ability and affordable production costs. This study prepared and evaluated 7 types of food waste-based biochars (FWBBs) (including meat and bone, starchy staples, leafy stemmed vegetables, nut husks, fruit pericarp, bean dreg and tea leaves). The impacts of raw materials, pyrolysis temperatures (300, 400, 500, 600 and 700 °C), and residence time (2 h and 4 h) on the removal of ammonia nitrogen at different ammonia nitrogen concentrations (5, 10, 20, 50, 100, 150 mg/L) were investigated. The batch equilibrium and kinetic experiments confirmed that a FWBB dosage of 3 g/L at 25 °C could remove up to 92.67% ammonia nitrogen. The Langmuir isotherm model had the best fit to equilibrium experimental data with a maximum adsorption capacity of 7.174 mg/g at 25 °C. The pseudo-second order kinetic model well describes the ammonia nitrogen adsorption

N<inf>2</inf>O reduction during municipal wastewater treatment using a two-sludge SBR system acclimatized with propionate

A two-sludge denitrifying phosphorus removal process (A2N-SBR), acclimatized with propionate, was proposed as an efficient method for nitrous oxide (N2O) reduction during municipal wastewater treatment. Compared with the conventional nitrification-denitrification process (AO-SBR) operated in parallel, the A2N-SBR not only significantly improved total nitrogen and soluble phosphorus removal efficiencies by around 32.3% and 23.5%, respectively, but also greatly reduced N2O generation by around 31.5%. Moreover, like the anoxic stage of AO-SBR, nearly zero N2O (merely 0.054% of the removed nitrogen) was generated during the anoxic stage of A2N-SBR. The substantial N2O reduction achieved in the proposed A2N-SBR can be reasonably explained by: (i) the use of independent nitrification reactor resulting in higher activity of nitrifying bacteria and no occurrence of heterotrophic denitrification in aerobic stage, and (ii) the use of propionate as carbon source decreasing nitrite accumulation in anoxic stage. © 2013 Elsevier B.V

In situ reconstruction of long-term extreme flooding magnitudes and frequencies based on geological archives

© 2019 Extreme flooding magnitudes and frequencies are essentially related to assessment of risk and reliability in hydrological design. Extreme flooding and its discharge are highly sensitive to regional climate change. Presently, its discharge can be reconstructed by a geological archive or record along the river valley. Two units of typical extreme flooding deposits (EFDs) carrying long-term information preserved in the Holocene loess–palaeosol sequence were found at Xipocun (XPC), which is located in Chengcheng County, China. It is situated in the downstream section of the Beiluohe (hereafter BLH) River. Based on multiple sedimentary proxy indices (grain-size distribution (GSD), magnetic susceptibility (MS), and loss-on-ignition (LOI), etc.), EFDs were interpreted as well-sorted clayey silt in suspension. They were then deposited as a result of riverbank flooding in a stagnant environment during high water level. Through the Optically Stimulated Luminescence (OSL) dating technique and stratigraphic correlations, chronologies of two identified extreme flooding periods were 7600–7400 a B.P. and 3200–3000 a B.P. Two phases of extreme flooding occurrence under climate abnormality scenarios were characterized as having high frequencies of hydrological extremes in river systems. According to simulation and verification using the Slope–Area Method and Hydrologic Engineering Center's River Analysis System (HEC-RAS) model, the extreme flooding discharges at the XPC site were reconstructed between 9625 m 3 /s and 16,635 m 3 /s. A new long-term flooding frequency and peak discharge curve, involved gauged flooding, historical flooding at Zhuangtou station and in situ reconstructed extreme flooding events, was established for the downstream BLH River. The results improve the accuracy of low-frequency flooding risk assessment and provide evidence for predicting the response of fluvial systems to climate instability. Thus, this improves the analysis of the BLH River watershed

Frustration Effects in Antiferromagnetic FCC Heisenberg Films

We study the effects of frustration in an antiferromagnetic film of FCC lattice with Heisenberg spin model including an Ising-like anisotropy. Monte Carlo (MC) simulations have been used to study thermodynamic properties of the film. We show that the presence of the surface reduces the ground state (GS) degeneracy found in the bulk. The GS is shown to depend on the surface in-plane interaction $J_s$ with a critical value at which ordering of type I coexists with ordering of type II. Near this value a reentrant phase is found. Various physical quantities such as layer magnetizations and layer susceptibilities are shown and discussed. The nature of the phase transition is also studied by histogram technique. We have also used the Green's function (GF) method for the quantum counterpart model. The results at low-$T$ show interesting effects of quantum fluctuations. Results obtained by the GF method at high $T$ are compared to those of MC simulations. A good agreement is observed.Comment: 11 pages, 19 figures, submitted to J. Phys.: Condensed Matte

Challenges in biogas production from anaerobic membrane bioreactors

© 2016 Spectacular applications of anaerobic membrane bioreactors (AnMBRs) are emerging due to the membrane enhanced biogas production in the form of renewable bioresources. They produce similar energy derived from the world's depleting natural fossil energy sources while minimizing greenhouse gas (GHG) emissions. During the last decade, many types of AnMBRs have been developed and applied so as to make biogas technology practical and economically viable. Referring to both conventional and advanced configurations, this review presents a comprehensive summary of AnMBRs for biogas production in recent years. The potential of biogas production from AnMBRs cannot be fully exploited, since certain constraints still remain and these cause low methane yield. This paper addresses a detailed assessment on the potential challenges that AnMBRs are encountering, with a major focus on many inhibitory substances and operational dilemmas. The aim is to provide a solid platform for advances in novel AnMBRs applications for optimized biogas production

Characterization and sulfonamide antibiotics adsorption capacity of spent coffee grounds based biochar and hydrochar.

A large amount of spent coffee grounds is produced as a processing waste each year during making the coffee beverage. Sulfonamide antibiotics (SAs) are frequently detected in the environment and cause pollution problems. In this study, biochar (BC) and hydrochar (HC) were derived from spent coffee grounds through pyrolysis and hydrothermal carbonization, respectively. Their characteristics and sulfonamide antibiotics adsorption were investigated and compared with reference to adsorption capacity, adsorption isotherm and kinetics. Results showed BC possessed more carbonization and less oxygen-containing functional groups than HC when checked by Elemental Analysis, X-ray diffraction, X-ray photoelectron spectrometry and Fourier transform infrared. These groups affected the adsorption of sulfonamide antibiotics and adsorption mechanism. The maximum adsorption capacities of BC for sulfadiazine (SDZ) and sulfamethoxazole (SMX) were 121.5 μg/g and 130.1 μg/g at 25 °C with the initial antibiotic concentration of 500 μg/L, respectively. Meanwhile the maximum adsorption capacities of HC were 82.2 μg/g and 85.7 μg/g, respectively. Moreover, the adsorption mechanism for SAs adsorbed onto BC may be dominated by π-π electron donor-acceptor interactions, yet the SAs adsorption to HC may be attributed to hydrogen bonds. Further analysis of the adsorption isotherms and kinetics, found that physical and chemical interactions were involved in the SAs adsorption onto BC and HC. Overall, results suggested that: firstly, pyrolysis was an effective thermochemical conversion of spent coffee grounds; and secondly, BC was the more promising adsorbent for removing sulfonamide antibiotics