Kinetics and mechanism of the formation of water cluster ions from O2(plus) and H2O in He, Ar, N2, and O2 at 296 K

The reaction sequence leading from O2(+) to H3O(+)-H2O was examined in He, Ar, N2 and O2 carrier gases in a flowing afterglow system. The rate constants for the reactions were measured and the kinetic analysis for their determination is presented. For M = N2, two new steps involving the formation and reaction of O2(+)-N2 were proposed and examined. The rate constants are discussed and compared with other experimental values

Digital Repository of Mathematical Formulae

The purpose of the NIST Digital Repository of Mathematical Formulae (DRMF) is to create a digital compendium of mathematical formulae for orthogonal polynomials and special functions (OPSF) and of associated mathematical data. The DRMF addresses needs of working mathematicians, physicists and engineers: providing a platform for publication and interaction with OPSF formulae on the web. Using MediaWiki extensions and other existing technology (such as software and macro collections developed for the NIST Digital Library of Mathematical Functions), the DRMF acts as an interactive web domain for OPSF formulae. Whereas Wikipedia and other web authoring tools manifest notions or descriptions as first class objects, the DRMF does that with mathematical formulae. See http://gw32.iu.xsede.org/index.php/Main_Page

Ultrafine particle levels measured on board short-haul commercial passenger jet aircraft

Abstract Background Airline crew members report adverse health effects during and after inhalation exposure to engine oil fumes sourced to the air supply system onboard commercial and military aircraft. Most investigations into the causal factors of their reported symptoms focus on specific chemical contaminants in the fumes. The adverse health effects reported in aircrew exposed to the aircraft air supply, bled unfiltered off the engine or Auxiliary Power Unit (APU) may be related to particulate exposures, which are widely known to effect health. While oil contaminates the aircraft air supply, some suggest that this will only occur when there is a bearing seal failure, others document that there is low level oil contamination of the air supply during normal engine operation. This brief pilot study explores whether particulate exposure may be associated with the normal engine/APU and air supply operation and to therefore increase the understanding that UFP exposures may have on crew and passengers. Methods An ultrafine particle counter was utilised by an experienced airline captain in the passenger cabin of four short-haul commercial passenger aircraft. All flights were under 90 min on aircraft from two different carriers ranging from 7 months to 14 years old. Results UFP concentrations showed maximum concentrations ranging from 31,300 to 97,800 particles/cm3 when APU was selected on as a source of air on the ground and with engine bleed air and the air conditioning packs selected on during the climb. In 2 of the 4 flights the peaks were associated with an engine oil smell. Increases in UFP particle concentrations occurred with changes in engine/APU power and air supply configuration changes. Conclusions This study identified increases in UFP concentrations associated with engine and APU power changes and changes in air supply configuration. These results correlated with times when engine and APU oil seals are known to be less effective, enabling oil leakage to occur. The concentrations reached in the passenger cabins exceeded those taken in other ground-based environments. UFP exposures in aircraft cabins during normal flight indicates there will be health consequences for long serving aircrew and some passengers

Constraints on Omega_m and sigma_8 from weak lensing in RCS fields

We have analysed 53 square degrees of imaging data from the Red-Sequence Cluster Survey (RCS), and measured the excess correlations in the shapes of galaxies on scales out to ~1.5 degrees. We separate the signal into an ``E''- (lensing) and ``B''-mode (systematics), which allows us to study residual systematics. On scales larger than 10 arcminutes, we find no ``B''-mode. On smaller scales we find a small, but significant ``B''-mode. This signal is also present when we select a sample of bright galaxies. These galaxies are rather insensitive to observational distortions, and we therefore conclude that the oberved ``B''-mode is likely to be caused by intrinsic alignments. We therefore limit the cosmic shear analysis to galaxies with 22<R_C<24. We derive joint constraints on Omega_m and sigma_8, by marginalizing over Gamma, Omega_Lambda and the source redshift distribution, using different priors. We obtain a conservative constraint of $\sigma_8=0.45^{+0.09}_{-0.12} \Omega_m^{-0.55}$ (95% confidence). A better constraint is derived when we use Gaussian priors redshift distribution. For this choice of priors, we find $\sigma_8=(0.46^{+0.05}_{-0.07})\Omega_m^{-0.52}$ (95% confidence). Using our setof Gaussian priors, we find that we can place a lower bound on Gamma: Gamma>0.1+0.16\Omega_m$ (95% confidence). Comparison of the RCS results with three other recent cosmic shear measurements shows excellent agreement. The current weak lensing results are also in good agreement with CMB measurements, when we allow the reionization optical depth tau and the spectral index n_s to vary. We present a simple demonstration of how the weak lensing results can be used as a prior in the parameter estimation from CMB measurements to derive constraints on the reionization optical depth tau. (abridged)Comment: 9 pages, 6 figures, Accepted for publication in the Astrophysical Journa

The effect of farming system on dairy cow cleanliness in the UK and implications to udder health

The cleanliness of dairy cows was assessed using a 20 point hygiene score system at different times in the year on 14 organic and 14 conventional farms in the UK. Overall, cows were dirtier during winter housing compared to summer grazing. Farming system had no effect on cow cleanliness when cows were at grass, but when housed in the winter, organic cows were more likely to be cleaner. There was a link between cow hygiene scores and milk hygiene, with herds having lower bulk tank somatic cell counts (BTSCC) tending to have cleaner cows. This relationship was strongest for the organic herds. There was no significant link between hygiene score and Bactoscan (BS) count or mastitis incidence

Superconductivity in Ca-doped graphene

Graphene, a zero-gap semimetal, can be transformed into a metallic, semiconducting or insulating state by either physical or chemical modification. Superconductivity is conspicuously missing among these states despite considerable experimental efforts as well as many theoretical proposals. Here, we report superconductivity in calcium-decorated graphene achieved by intercalation of graphene laminates that consist of well separated and electronically decoupled graphene crystals. In contrast to intercalated graphite, we find that Ca is the only dopant that induces superconductivity in graphene laminates above 1.8 K among intercalants used in our experiments such as potassium, caesium and lithium. Ca-decorated graphene becomes superconducting at ~ 6 K and the transition temperature is found to be strongly dependent on the confinement of the Ca layer and the induced charge carrier concentration. In addition to the first evidence for superconducting graphene, our work shows a possibility of inducing and studying superconductivity in other 2D materials using their laminates

Finding the center reliably: robust patterns of developmental gene expression

We investigate a mechanism for the robust identification of the center of a developing biological system. We assume the existence of two morphogen gradients, an activator emanating from the anterior, and a co-repressor from the posterior. The co-repressor inhibits the action of the activator in switching on target genes. We apply this system to Drosophila embryos, where we predict the existence of a hitherto undetected posterior co-repressor. Using mathematical modelling, we show that a symmetric activator-co-repressor model can quantitatively explain the precise mid-embryo expression boundary of the hunchback gene, and the scaling of this pattern with embryo size.Comment: 4 pages, 3 figure