2,097 research outputs found
Elastic response of [111]-tunneling impurities
We study the dynamic response of a [111] quantum impurity, such as lithium or
cyanide in alkali halides, with respect to an external field coupling to the
elastic quadrupole moment. Because of the particular level structure of a
eight-state system on a cubic site, the elastic response function shows a
biexponential relaxation feature and a van Vleck type contribution with a
resonance frequency that is twice the tunnel frequency . This
basically differs from the dielectric response that does not show relaxation.
Moreover, we show that the elastic response of a [111] impurity cannot be
reduced to that of a two-level system. In the experimental part, we report on
recent sound velocity and internal friction measurements on KCl doped with
cyanide at various concentrations. At low doping (45 ppm) we find the dynamics
of a single [111] impurity, whereas at higher concentrations (4700 ppm) the
elastic response rather indicates strongly correlated defects. Our theoretical
model provides a good description of the temperature dependence of
and at low doping, in particular the relaxation peaks, the absolute
values of the amplitude, and the resonant contributions. From our fits we
obtain the value of the elastic deformation potential eV.Comment: 19 pages, 5 figure
The challenge of modelling nitrogen management at the field scale : simulation and sensitivity analysis of N2O fluxes across nine experimental sites using DailyDayCent
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Soft Interaction Between Dissolved Dendrimers: Theory and Experiment
Using small-angle neutron scattering and liquid integral equation theory, we
relate the structure factor of flexible dendrimers of 4th generation to their
average shape. The shape is measured as a radial density profile of monomers
belonging to a single dendrimer. From that, we derive an effective interaction
of Gaussian form between pairs of dendrimers and compute the structure factor
using the hypernetted chain approximation. Excellent agreement with the
corresponding experimental results is obtained, without the use of adjustable
parameters. The present analysis thus strongly supports the previous finding
that flexible dendrimers of low generation present fluctuating structures akin
to star polymers.Comment: 20 pages, 4 figures, submitted to Macromolecules on July 24, 200
Restoration of CD28 Expression in CD28â CD8+ Memory Effector T Cells Reconstitutes Antigen-induced IL-2 Production
The control of many persistent viral infections by Ag-specific cytolytic CD8+ T cells requires a concurrent virus-specific CD4+ Th cell response. This reflects in part a requirement of activated effector CD8+ T cells for paracrine IL-2 production as a growth and survival factor. In human CMV and HIV infection, the majority of differentiated virus-specific CD8+ T cells notably lose the ability to produce IL-2 but also lose expression of CD28, a costimulatory molecule. Analysis of the fraction of memory CD8+ T cells that continue to express CD28 revealed these cells retain the ability to produce IL-2. Therefore, we examined if IL-2 production by CD28â CD8+ T cells could be restored by introduction of a constitutively expressed CD28 gene. Expression of CD28 in CD28â CD8+ CMV- and HIV-specific CD8+ T cells reconstituted the ability to produce IL-2, which could sustain an autocrine proliferative response after Ag recognition. These results suggest that the loss of CD28 expression during differentiation of memory/effector CD8+ T cells represents a decisive step in establishing regulation of responding CD8+ T cells, increasing the dependence on CD4+ Th for proliferation after target recognition, and has implications for the treatment of viral disease with adoptively transferred CD8+ T cells
Spectral Shape of Relaxations in Silica Glass
Precise low-frequency light scattering experiments on silica glass are
presented, covering a broad temperature and frequency range (9 GHz < \nu < 2
THz). For the first time the spectral shape of relaxations is observed over
more than one decade in frequency. The spectra show a power-law low-frequency
wing of the relaxational part of the spectrum with an exponent
proportional to temperature in the range 30 K < T < 200 K. A comparison of our
results with those from acoustic attenuation experiments performed at different
frequencies shows that this power-law behaviour rather well describes
relaxations in silica over 9 orders of magnitude in frequency. These findings
can be explained by a model of thermally activated transitions in double well
potentials.Comment: 4 pages, 3 figures, submitted to Phys. Rev. Let
Low temperature acoustic properties of amorphous silica and the Tunneling Model
Internal friction and speed of sound of a-SiO(2) was measured above 6 mK
using a torsional oscillator at 90 kHz, controlling for thermal decoupling,
non-linear effects, and clamping losses. Strain amplitudes e(A) = 10^{-8} mark
the transition between the linear and non-linear regime. In the linear regime,
excellent agreement with the Tunneling Model was observed for both the internal
friction and speed of sound, with a cut-off energy of E(min) = 6.6 mK. In the
non-linear regime, two different behaviors were observed. Above 10 mK the
behavior was typical for non-linear harmonic oscillators, while below 10 mK a
different behavior was found. Its origin is not understood.Comment: 1 tex file, 6 figure
Mechanical Relaxation in Glasses and at the Glass Transition
The Gilroy-Phillips model of relaxational jumps in asymmetric double-well
potentials, developed for the Arrhenius-type secondary relaxations of the glass
phase, is extended to a formal description of the breakdown of the shear
modulus at the glass transition, the flow process.Comment: 13 pages, 11 figures, 49 ref
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A High-Resolution Airborne Color-Infrared Camera Water Mask for the NASA ABoVE Campaign
The airborne AirSWOT instrument suite, consisting of an interferometric Ka-band synthetic aperture radar and color-infrared (CIR) camera, was deployed to northern North America in July and August 2017 as part of the NASA Arctic-Boreal Vulnerability Experiment (ABoVE). We present validated, open (i.e., vegetation-free) surface water masks produced from high-resolution (1 m), co-registered AirSWOT CIR imagery using a semi-automated, object-based water classification. The imagery and resulting high-resolution water masks are available as open-access datasets and support interpretation of AirSWOT radar and other coincident ABoVE image products, including LVIS, UAVSAR, AIRMOSS, AVIRIS-NG, and CFIS. These synergies offer promising potential for multi-sensor analysis of Arctic-Boreal surface water bodies. In total, 3167 km2 of open surface water were mapped from 23,380 km2 of flight lines spanning 23 degrees of latitude and broad environmental gradients. Detected water body sizes range from 0.00004 km2 (40 m2) to 15 km2. Power-law extrapolations are commonly used to estimate the abundance of small lakes from coarser resolution imagery, and our mapped water bodies followed power-law distributions, but only for water bodies greater than 0.34 (±0.13) km2 in area. For water bodies exceeding this size threshold, the coefficients of power-law fits vary for different Arctic-Boreal physiographic terrains (wetland, prairie pothole, lowland river valley, thermokarst, and Canadian Shield). Thus, direct mapping using high-resolution imagery remains the most accurate way to estimate the abundance of small surface water bodies. We conclude that empirical scaling relationships, useful for estimating total trace gas exchange and aquatic habitats on Arctic-Boreal landscapes, are uniquely enabled by high-resolution AirSWOT-like mappings and automated detection methods such as those developed here
Evaluating the Potential of Legumes to Mitigate NO Emissions From Permanent Grassland Using Process-Based Models
A potential strategy for mitigating nitrous oxide (NO) emissions from permanent grasslands is the partial substitution of fertilizer nitrogen (N) with symbiotically fixed nitrogen (N) from legumes. The input of N reduces the energy costs of producing fertilizer and provides a supply of nitrogen (N) for plants that is more synchronous to plant demand than occasional fertilizer applications. Legumes have been promoted as a potential NO mitigation strategy for grasslands, but evidence to support their efficacy is limited, partly due to the difficulty in conducting experiments across the large range of potential combinations of legume proportions and fertilizer N inputs. These experimental constraints can be overcome by biogeochemical models that can vary legumeâfertilizer combinations and subsequently aid the design of targeted experiments. Using two variants each of two biogeochemical models (APSIM and DayCent), we tested the NO mitigation potential and productivity of full factorial combinations of legume proportions and fertilizer rates for five temperate grassland sites across the globe. Both models showed that replacing fertilizer with legumes reduced NO emissions without reducing productivity across a broad range of legumeâfertilizer combinations. Although the models were consistent with the relative changes of NO emissions compared to the baseline scenario (200 kg N ha yr; no legumes), they predicted different levels of absolute NO emissions and thus also of absolute NO emission reductions; both were greater in DayCent than in APSIM. We recommend confirming these results with experimental studies assessing the effect of clover proportions in the range 30â50% and â€150 kg N ha yr input as these were identified as bestâbet climate smart agricultural practices
Global Research Alliance N2O chamber methodology guidelines : Summary of modeling approaches
Acknowledgements Funding for this publication was provided by the New Zealand Government to support the objectives of the Livestock Research Group of the Global Research Alliance on Agricultural Greenhouse Gases. Individual authors work contribute to the following projects for which support has been received: Climate smart use of Norwegian organic soils (MYR, 2017-2022) project funded by the Research Council of Norway (decision no. 281109); Scottish Government's Strategic Research Programme, SuperG (under EU Horizon 2020 programme); DEVIL (NE/M021327/1), Soils-R-GRREAT (NE/P019455/1) and the EU H2020 project under Grant Agreement 774378âCoordination of International Research Cooperation on Soil Carbon Sequestration in Agriculture (CIRCASA); to project J-001793, Science and Technology Branch, Agriculture and Agri-Food Canada; and New Zealand Ministry of Business, Innovation and Employment (MBIE) core funding. Thanks to Alasdair Noble and the anonymous reviewers for helpful comments on a draft of this paper and to Anne Austin for editing services.Peer reviewedPublisher PD
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