46,926 research outputs found
Metallopolymer Organohydrogels with Photo-Controlled Coordination Crosslinks Work Properly Below 0 degrees C
Theoretical analysis of dynamic chemical imaging with lasers using high-order harmonic generation
We report theoretical investigations of the tomographic procedure suggested
by Itatani {\it et al.} [Nature, {\bf 432} 867 (2004)] for reconstructing
highest occupied molecular orbitals (HOMO) using high-order harmonic generation
(HHG). Using the limited range of harmonics from the plateau region, we found
that under the most favorable assumptions, it is still very difficult to obtain
accurate HOMO wavefunction, but the symmetry of the HOMO and the internuclear
separation between the atoms can be accurately extracted, especially when
lasers of longer wavelengths are used to generate the HHG. We also considered
the possible removal or relaxation of the approximations used in the
tomographic method in actual applications. We suggest that for chemical
imaging, in the future it is better to use an iterative method to locate the
positions of atoms in the molecule such that the resulting HHG best fits the
macroscopic HHG data, rather than by the tomographic method.Comment: 13 pages, 14 figure
Theory for high spin systems with orbital degeneracy
High-spin systems with orbital degeneracy are studied in the large spin
limit. In the absence of Hund's coupling, the classical spin model is mapped
onto disconnected orbital systems with spins up and down, respectively. The
ground state of the isotropic model is an orbital valence bond state where each
bond is an orbital singlet with parallel spins, and neighbouring bonds interact
antiferromagnetically. The possible relevance to the transition metal oxides
are discussed.Comment: 4 page, three figures, to appear in Phys. Rev. Let
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Connected OFCity Challenge: Addressing the Digital Divide in the Developing World
Over the past 50 years, the development of information and communications technology has provided unprecedented support to the steady economic growth of developed countries. In recent years, some of the largest growth has been reported in emerging economies, which, however, often lack adequate telecommunications infrastructure to further sustain their development. Although a number of service providers and system vendors have started to address the issue, the challenges they encounter are substantially different from those in the developed world, including an unreliable electricity grid, poor fiber infrastructure, low revenue expectations, and often a harsh climate environment. This paper reports use cases and solutions pertinent to the development of the networking infrastructure in emerging economies, provided by organizations directly involved in such activities. After providing some background information on the current state of network infrastructure and the main challenges for Africa and rural China, the paper provides details on two proposed solutions. The first focuses on the provisioning of services and network infrastructure through the development of low-cost data centers, whereas the second proposes cost-effective adaptation of both fiber and hybrid copper-fiber technology to rural areas. The article is concluded with a brief discussion on the complementarity of the two approaches
NOTATIONAL ANALYSIS OF INTERNATIONAL BADMINTON COMPETITIONS
Notational analysis of competitions is a widely used method for observing the playing patterns of many sports. An experiment was carried out to determine the playing tactics adopted by athletes in international badminton competitions. A total of 10 major competitions were recorded and the data was processed using a generic notational analysis software. The types of techniques used, the success and failure rates of the various shots were computed and compared using statistical methods of analysis. The results showed that the top three most popular shots used were Lift, Net and Clear. It was also found' that there were significant differences among the percentage of shots used in the three court areas as well, as the type of shots used by males and females
Local Structure and It's Effect on The Ferromagnetic Properties of LaSrCoO thin films}
We have used high-resolution Extended X-ray Absorption Fine-Structure and
diffraction techniques to measure the local structure of strained
LaSrCoO films under compression and tension. The lattice
mismatch strain in these compounds affects both the bond lengths and the bond
angles, though the larger effect on the bandwidth is due to the bond length
changes. The popular double exchange model for ferromagnetism in these
compounds provides a correct qualitative description of the changes in Curie
temperature , but quantitatively underestimates the changes. A microscopic
model for ferromagnetism that provides a much stronger dependence on the
structural distortions is needed.Comment: 4 pages, 4 figure
Symmetry-breaking skyrmion states in fractional quantum Hall systems
We calculate in an analyical fashion the energies and net spins of skyrmions
in fractional quantum Hall systems, based on the suggestion that skyrmion
states are spontaneously and symmetry-breaking states. The
quasihole-skyrmion state with a charge around = 1/3, where the
ground state is known as a spin-polarized ferromagnetic state, is found to
exist even in high magnetic fields up to about 7 T for GaAs samples.Comment: There is conceptual change. To appear in Phys. Rev.
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