Kinetic modeling of microscopic processes during electron cyclotron resonance microwave plasma-assisted molecular beam epitaxial growth of GaN/GaAs-based heterostructures

Microscopic growth processes associated with GaN/GaAs molecular beam epitaxy (MBE) are examined through the introduction of a first-order kinetic model. The model is applied to the electron cyclotron resonance microwave plasma-assisted MBE (ECR-MBE) growth of a set of delta-GaNyAs1–y/GaAs strained-layer superlattices that consist of nitrided GaAs monolayers separated by GaAs spacers, and that exhibit a strong decrease of y with increasing T over the range 540–580 °C. This y(T) dependence is quantitatively explained in terms of microscopic anion exchange, and thermally activated N surface-desorption and surface-segregation processes. N surface segregation is found to be significant during GaAs overgrowth of GaNyAs1–y layers at typical GaN ECR-MBE growth temperatures, with an estimated activation energy Es ~ 0.9 eV. The observed y(T) dependence is shown to result from a combination of N surface segregation/desorption processes

Observation of a (2X8) surface reconstruction on Si_(1-x)Ge_x alloys grown on (100) Si by molecular beam epitaxy

We present evidence supporting the formation of a new, (2×8) surface reconstruction on Si_(1−x)Ge_x alloys grown on (100) Si substrates by molecular‐beam epitaxy. Surfaces of Si_(1−x)Ge_x alloys were studied using reflection high‐energy electron diffraction (RHEED) and low‐energy electron diffraction (LEED) techniques. RHEED patterns from samples with Ge concentrations, x, falling within the range 0.10–0.30 and grown at temperatures between 350 and 550 °C, exhibit n/8 fractional‐order diffraction streaks in addition to the normal (2×1) pattern seen on (100) Si. The presence of fractional‐order diffracted beams is indicative of an eight‐fold‐periodic modulation in electron scattering factor across the alloy surface. LEED patterns from surfaces of samples grown under similar conditions are entirely consistent with these results. In addition, the LEED patterns support the conclusion that the modulation is occurring in the direction of the dimer chains of a (2×1) reconstruction. We have examined the thermal stability of the (2×8) reconstruction and have found that it reverts to (2×1) after annealing to 700 °C and reappears after the sample temperature is allowed to cool below 600 °C. Such behavior suggests that the reconstruction is a stable, ordered phase for which the pair‐correlation function of surface Ge atoms exhibits an eightfold periodicity in the "1" direction of a Si‐like (2×1) reconstruction. We also present a simulation in the kinematic approximation, confirming the validity of our interpretation of these finding

Microscopic processes during electron cyclotron resonance microwave nitrogen plasma-assisted molecular beam epitaxial growth of GaN/GaAs heterostructures: Experiments and kinetic modeling

A set of delta-GaNyAs1–y/GaAs strained-layer superlattices grown on GaAs (001) substrates by electron cyclotron resonance (ECR) microwave plasma-assisted molecular beam epitaxy (MBE) was characterized by ex situ high resolution X-ray diffraction (HRXRD) to determine nitrogen content y in the nitrided GaAs monolayers as a function of growth temperature T. A first order kinetic model is introduced to quantitatively explain this y(T) dependence in terms of an energetically favorable N for As anion exchange and thermally activated N-surface desorption and surface segregation processes. The nitrogen surface segregation process, with an estimated activation energy Es ~ 0.9 eV appears to be significant during the GaAs overgrowth of GaNyAs1–y layers, and is shown to be responsible for strong y(T) dependence

SM-2 CLUTCH TESTING

The criteria and methods for test evaluation of electromagnetic clutch characteristics are discussed. An evaluation of the relative merits of two commercial clutches, both of the multiple disk friction type, is presented with test results. One of these clutches was incorporated in the clutch assembly design for the Array Reactor (SM-2). (auth

Accommodation of lattice mismatch in Ge_(x)Si_(1−x)/Si superlattices

We present evidence that the critical thickness for the appearance of misfit defects in a given material and heteroepitaxial structure is not simply a function of lattice mismatch. We report substantial differences in the relaxation of mismatch stress in Ge_(0.5)Si_(0.5)/Si superlattices grown at different temperatures on (100) Si substrates. Samples have been analyzed by x‐ray diffraction, channeled Rutherford backscattering, and transmission electron microscopy. While a superlattice grown at 365 °C demonstrates a high degree of elastic strain, with a dislocation density <10^5 cm^(−2) , structures grown at higher temperatures show increasing numbers of structural defects, with densities reaching 2×10^(10) cm^(−2) at a growth temperature of 530 °C. Our results suggest that it is possible to freeze a lattice‐mismatched structure in a highly strained metastable state. Thus it is not surprising that experimentally observed critical thicknesses are rarely in agreement with those predicted by equilibrium theories

Effects of exciton deconfinement on the transient photoluminescence from thermally activated delayed fluorescence host-guest systems

For thermally activated delayed fluorescence (TADF) host-guest systems used in organic light-emitting diodes, understanding of the transient photoluminescence (PL) measurements is crucial for accurate determination of the photophysical rates of the emitter. Here, we study how the PL is affected by triplet-exciton deconfinement from the guest to the host molecules. This deconfinement can complicate the analysis of the PL decay and potentially lead to a loss of efficiency. From an analytical model, we find that the transient PL intensity remains bi-exponential in the presence of exciton deconfinement for the case of fast triplet diffusion, albeit with a longer decay time of the delayed component. Deconfinement might, therefore, not always be recognizable from a single transient PL measurement. The role of deconfinement depends on the energetic disorder, the guest concentration, and the energy difference Δ E T between triplet-exciton energies on the host and guest molecules and is effectively suppressed for Δ E T &gt; - &gt; 0.2 eV. We find from analytical modeling and kinetic Monte Carlo simulations that the decay can become non-bi-exponential and even show a distinct third decay step. The shape of the decay curves depends on the characteristic times for guest-host transfer and host diffusion, relative to the prompt and delayed decay times of the TADF emitter. A comparison with available experimental data is included, finding qualitative agreement with dedicated deconfinement studies and indicating the influence of other processes for the often observed power-law decay at long time scales. </p

Composición y estructura de la vegetación epífita vascular en un bosque primario de Olivillo (Aextoxicon punctatum R. et P.) en el sur de Chile

Vascular epiphytes represent 10% of the total vascular plants of the world. Nevertheless, because it is hard to reach them in the forest upper-canopy where they usually live, there are few studies (especially in Chile) about them. With the objective of identifying the vascular epiphytes growing on tree stems (under 1.5 m height), we sampled three transects in an Olivillo old-growth stand, in the Rucamanque forest, in the central valley of south-central Chile, near the city of Temuco. Several variables were measured for both the vascular epiphytes and their host-trees. We studied the floristic composition of the vascular epiphytes community, and their relationship with their host-trees, as well as their sociability, cover, and frequency. Eight vascular epiphytes species were identified, corresponding to four genus distributed in three families: Hymenophyllum and Hymenoglossum (Hymenophyllaceae), Asplenium (Aspleniaceae) and Sarmienta (Gesneriaceae). We found only a non-statistically significant linear correlation between vascular epiphytes and their host-trees. We determined that Hymenophyllum cuneatum was the most important vascular epiphytes species

2,6-Dipicolinoylbis(N,N-dialkylthioureas) as versatile building blocks for oligo- and polynuclear architectures

Similar reactions of 2,6-dipicolinoylbis(N,N-diethylthiourea) (H2La) with: (i) Ni(NO3)2·6H2O, (ii) a mixture of Ni(NO3)2·6H2O and AgNO3, (iii) a mixture of Ni(OAc)2·4H2O and PrCl3·7H2O and (iv) a mixture of Ni(OAc)2·4H2O and BaCl2·2H2O give the binuclear complex [Ni2(La)2(MeOH)(H2O)], the polymeric compound [NiAg2(La)2]∞, and the heterobimetallic complexes [Ni2Pr(La)2(OAc)3] and [Ni2Ba(La)3], respectively. The obtained assemblies can be used for the build up of supramolecular polymers by means of weak and medium intermolecular interactions. Two prototype examples of such compounds, which are derived from the trinuclear complexes of the types [MII2LnIII(L)2(OAc)3] and [MII2Ba(L)3], are described with the compounds {[CuII2DyIII(La)2(p-O2C-C6H4-CO2)(MeOH)4]Cl}∞ and [MnII2Ba(MeOH)(Lb)3]∞, H2Lb = 2,6-dipicolinoylbis(N,N-morpholinoylthiourea)

Probing the Deuteron at Very Large Internal Momenta

We measure 2H(e,e′p)n cross sections at 4-momentum transfers of Q2 = 4.5 ± 0.5   (GeV/c)2 over a range of neutron recoil momenta pr, reaching up to ∼1.0  GeV/c. We obtain data at fixed neutron recoil angles θnq = 35°, 45°, and 75° with respect to the 3-momentum transfer →q. The new data agree well with previous data, which reached pr ∼ 500  MeV/c. At θnq = 35° and 45°, final state interactions, meson exchange currents, and isobar currents are suppressed and the plane wave impulse approximation provides the dominant cross section contribution. We compare the new data to recent theoretical calculations, where we observe a significant discrepancy for recoil momenta pr \u3e 700  MeV/c