Reduction behavior of potassium-promoted iron oxide under mixed steam/hydrogen atmospheres

Potassium-promoted iron oxide catalysts are used in large volume for the commercial ethylbenzene dehydrogenation to styrene process. Short-term deactivation of these catalysts, which is addressed by operating in excess steam, is thought to be caused due to reactive site loss through coking and/or reduction. However, the relative importance of the two mechanisms is not known. Presented are results concerning the reduction behavior of potassium-promoted iron oxide materials in the absence of carbon. Thermogravimetric experiments and X-ray diffraction analysis were used to examine the reduction behavior of potassium-promoted iron oxide materials. The reduction behavior was then compared with results from isothermal ethylbenzene dehydrogenation reactor studies under low steam-to-ethylbenzene operation. Potassium incorporation was found to stabilize the iron oxide against reduction apparently through the formation of KFeO 2. Chromium addition improved the reduction resistance, which gave good qualitative agreement with the dehydrogenation reaction studies. In contrast, vanadium incorporation led to more significant reduction as well as poor stability in the dehydrogenation reaction

Interacting Boson Theory of the Magnetization Process of the Spin-1/2 Ferromagnetic-Antiferromagnetic Alternating Heisenberg Chain

The low temperature magnetization process of the ferromagnetic-antiferromagnetic Heisenberg chain is studied using the interacting boson approximation. In the low field regime and near the saturation field, the spin wave excitations are approximated by the $\delta$ function boson gas for which the Bethe ansatz solution is available. The finite temperature properties are calculated by solving the integral equation numerically. The comparison is made with Monte Carlo calculation and the limit of the applicability of the present approximation is discussed.Comment: 4 pages, 7 figure

Quasar Clustering and the Lifetime of Quasars

Although the population of luminous quasars rises and falls over a period of 10^9 years, the typical lifetime of individual quasars is uncertain by several orders of magnitude. We show that quasar clustering measurements can substantially narrow the range of possible lifetimes with the assumption that luminous quasars reside in the most massive host halos. If quasars are long-lived, then they are rare phenomena that are highly biased with respect to the underlying dark matter, while if they are short-lived they reside in more typical halos that are less strongly clustered. For a given quasar lifetime, we calculate the minimum host halo mass by matching the observed space density of quasars, using the Press-Schechter approximation. We use the results of Mo & White to calculate the clustering of these halos, and hence of the quasars they contain, as a function of quasar lifetime. A lifetime of t_Q = 4 x 10^7 years, the e-folding timescale of an Eddington luminosity black hole with accretion efficiency eps=0.1, corresponds to a quasar correlation length r_0 ~ 10 Mpc/h in low-density cosmological models at z=2-3; this value is consistent with current clustering measurements, but these have large uncertainties. High-precision clustering measurements from the 2dF and Sloan quasar surveys will test our key assumption of a tight correlation between quasar luminosity and host halo mass, and if this assumption holds then they should determine t_Q to a factor of three or better. An accurate determination of the quasar lifetime will show whether supermassive black holes acquire most of their mass during high-luminosity accretion, and it will show whether the black holes in the nuclei of typical nearby galaxies were once the central engines of high-luminosity quasars.Comment: ApJ Accepted (Feb 2001). 30 pages, 8 embedded ps figures, AASTEX5. Added discussion of quasar luminosity evolution. Also available at http://www.ociw.edu/~martini/pubs

Effects of semidiurnal tidal circulation on the distribution of holo- and meroplankton in a subtropical estuary

We examined how tidal changes and which physical factors affected holo- and meroplankton assemblages in a subtropical estuary in Taiwan in February 1999. A factor analysis showed that during tidal flooding, the water mass properties changed from low salinity (5–16) and high particulate organic carbon (POC, 2.6–4.5 mg L−1) content to increasing salinity and high total suspended matter content (29.0–104.5 mg L−1). With a receding tide, the water became more saline again, and its velocity increased (from non-detectable to 0.67 m s−1). One-way ANOVA showed that the distributions of four dominant taxa were affected by the ebb tide and exhibited two distinct groups. The first group consisted of non-motile invertebrate eggs and weakly swimming polychaete sabellid embryos and larvae (at densities of 1.25–1.40 ind. L−1), while the second consisted of better-swimming copepods and polychaete spionid larvae (at densities of 0.70–1.65 ind. L−1). A canonical correlation analysis demonstrated that the former group occurred at sites with greater freshwater input, higher POC content and greater depth, whereas the latter group was significantly associated with sites subject to seawater and faster flows. We propose that a two-layered circulation process and tidally induced oscillations in water movements might account for the distributional differences between these two groups

Pepper-pot emittance measurement of laser-plasma wakefield accelerated electrons

The transverse emittance is an important parameter governing the brightness of an electron beam. Here we present the first pepper-pot measurement of the transverse emittance for a mono-energetic electron beam from a laser-plasma wakefield accelerator, carried out on the Advanced Laser-Plasma High Energy Accelerators towards X-Rays (ALPHA-X) beam line. Mono-energetic electrons are passed through an array of 52 mu m diameter holes in a tungsten mask. The pepper-pot results set an upper limit for the normalised emittance at 5.5 +/- 1 pi mm mrad for an 82 MeV beam

Requirement for expert histopathological assessment of ovarian cancer and borderline tumours

The distinction between borderline ovarian tumours (BOT) and ovarian carcinoma is made by histopathological assessment. Of 64 patients managed according to institutional BOT protocols, 27 (42%) had been referred with a diagnosis of ovarian carcinoma that was subsequently changed to BOT following histopathological review. The 70% 6-year event-free survival of the patients with a revised diagnosis was not significantly different from those who were referred with a diagnosis of BOT. This change in diagnosis is important as it avoids the need for chemotherapy for most patients and results in patients receiving appropriate information concerning prognosis. Interestingly, 24 patients (38.1%) reported a family history of epithelial cancer, a finding that has not been reported previously.© 2000 Cancer Research Campaig