Negative capacitance in organic semiconductor devices: bipolar injection and charge recombination mechanism

We report negative capacitance at low frequencies in organic semiconductor based diodes and show that it appears only under bipolar injection conditions. We account quantitatively for this phenomenon by the recombination current due to electron-hole annihilation. Simple addition of the recombination current to the well established model of space charge limited current in the presence of traps, yields excellent fits to the experimentally measured admittance data. The dependence of the extracted characteristic recombination time on the bias voltage is indicative of a recombination process which is mediated by localized traps.Comment: 3 pages, 3 figures, accepted for publication in Applied Physics Letter

Characterisation of an n-type segmented BEGe detector

A four-fold segmented n-type point-contact "Broad Energy" high-purity germanium detector, SegBEGe, has been characterised at the Max-Planck-Institut f\"ur Physik in Munich. The main characteristics of the detector are described and first measurements concerning the detector properties are presented. The possibility to use mirror pulses to determine source positions is discussed as well as charge losses observed close to the core contact

Self-consistent model of unipolar transport in organic semiconductor diodes: accounting for a realistic density-of-states distribution

A self-consistent, mean-field model of charge-carrier injection and unipolar transport in an organic semiconductor diode is developed utilizing the effective transport energy concept and taking into account a realistic density-of-states distribution as well as the presence of trap states in an organic material. The consequences resulting from the model are discussed exemplarily on the basis of an indium tin oxide/organic semiconductor/metallic conductor structure. A comparison of the theory to experimental data of a unipolar indium tin oxide/poly-3-hexyl-thiophene/Al device is presented.Comment: 6 pages, 2 figures; to be published in Journal of Applied Physic

Carbon footprint in different beef production systems on a southern Brazilian farm: a case study.

The carbon footprint (CF) of beef production is one of the most widely discussed environmental issues within the current agricultural community due to its association with climate change. Because of these relevant and serious concerns, the beef cattle industry is under increasing pressure to reduce production or implement technological changes with significant consequences in terms of beef marketing. The goals of this study were to evaluate the CF per 1 kg of live weight gain (LWG) at the farm gate for different beef production systems in the southern part of Brazil. Aberdeen Angus beef-bred cattle were assigned to one of seven categories: natural grass; improved natural grass; natural grass plus ryegrass; improved natural grass plus sorghum; cultivated ryegrass and sorghum; natural grass supplemented with protein mineralised salt; and natural grass supplemented with protein-energetic mineralised salt. Monte Carlo analysis was employed to analyse the effect of variations of dry matter intake digestibility (DMID), total digestible nutrients (TDN) and crude protein (CP) parameters in methane (CH4) enteric, CH4 manure, nitrous oxide (N2O) manure and N2O N-fertiliser. The method used was a comparative life cycle assessment (LCA) centred on the CF. The CF varied from 18.3 kg CO2 equivalent/kg LWG for the ryegrass and sorghum pasture system to 42.6 kg CO2 equivalent/kg LWG for the natural grass system, including the contributions of cows, calves and steers. Among all grassland-based cattle farms, production systems with DMID from 52 to 59% achieved the lowest CO2 emissions and the highest feed conversion rate, thereby generating lower CH4 and N2O emissions per production system. Because the feed intake and feed conversion rate are one of the most important production parameters in beef cattle production with an obvious risk of data uncertainty, accurate feed data, which include quantity and quality, are important in estimates of CF for LWG. The choice of adequate feeding strategies to mitigate greenhouse gas (GHG) emissions may result in better environmental advantages

Study of molecular spin-crossover complex Fe(phen)2(NCS)2 thin films

We report on the growth by evaporation under high vacuum of high-quality thin films of Fe(phen)2(NCS)2 (phen=1,10-phenanthroline) that maintain the expected electronic structure down to a thickness of 10 nm and that exhibit a temperature-driven spin transition. We have investigated the current-voltage characteristics of a device based on such films. From the space charge-limited current regime, we deduce a mobility of 6.5x10-6 cm2/V?s that is similar to the low-range mobility measured on the widely studied tris(8-hydroxyquinoline)aluminium organic semiconductor. This work paves the way for multifunctional molecular devices based on spin-crossover complexes

Charge carrier injection into insulating media: single-particle versus mean-field approach

Self-consistent, mean-field description of charge injection into a dielectric medium is modified to account for discreteness of charge carriers. The improved scheme includes both the Schottky barrier lowering due to the individual image charge and the barrier change due to the field penetration into the injecting electrode that ensures validity of the model at both high and low injection rates including the barrier dominated and the space-charge dominated regimes. Comparison of the theory with experiment on an unipolar ITO/PPV/Au-device is presented.Comment: 32 pages, 9 figures; revised version accepted to PR

Near-field spectroscopy of a gated electron gas: a direct evidence for electrons localization

The near-field photoluminescence of a gated two-dimensional electron gas is measured. We use the negatively charged exciton, formed by binding of an electron to a photo-excited electron-hole pair, as an indicator for the local presence of charge. Large spatial fluctuations in the luminescence intensity of the negatively charged exciton are observed. These fluctuations are shown to be due to electrons localized in the random potential of the remote ionized donors. We use these fluctuations to image the electrons and donors distribution in the plane.Comment: 10 pages, 5 figures, to be published in PR