27 research outputs found
Submicrometric Films of Surface-Attached Polymer Network with Temperature-Responsive Properties
Temperature-responsive properties of surface-attached
poly(N-isopropylacrylamide) (PNIPAM) network films with well-controlled
chemistry are investigated. The synthesis consists of cross-linking and
grafting preformed ene-reactive polymer chains through thiol--ene click
chemistry. The formation of surface-attached and cross-linked polymer films has
the advantage of being wellcontrolled without any caution of no-oxygen
atmosphere or addition of initiators. PNIPAM hydrogel films with same
cross-link density are synthesized on a wide range of thickness, from
nanometers to micrometers. The swelling-collapse transition with temperature is
studied by using ellipsometry, neutron reflectivity, and atomic force
microscopy as complementary surface-probing techniques. Sharp and high
amplitude temperature-induced phase transition is observed for all
submicrometric PNIPAM hydrogel films. For temperature above LCST,
surface-attached PNIPAM hydrogels collapse similarly but without complete
expulsion of water. For temperature below LCST, the swelling of PNIPAM
hydrogels depends on the film thickness. It is shown that the swelling is
strongly affected by the surface attachment for ultrathin films below 150
nm. For thicker films above 150 nm (to micrometers), surface-attached polymer
networks with the same cross-link density swell equally. The density profile of
the hydrogel films in the direction normal to the substrate is confronted with
in-plane topography of the free surface. It results that the free interface
width is much larger than the roughness of the hydrogel film, suggesting
pendant chains at the free surface.Comment: in Langmuir, American Chemical Society, 2015, LANGMUIR, 31 (42),
pp.11516-1152
Experimental evidence of non-Amontons behaviour at a multicontact interface
We report on normal stress field measurements at the multicontact interface
between a rough elastomeric film and a smooth glass sphere under normal load,
using an original MEMS-based stress sensing device. These measurements are
compared to Finite Elements Method calculations with boundary conditions
obeying locally Amontons' rigid-plastic-like friction law with a uniform
friction coefficient. In dry contact conditions, significant deviations are
observed which decrease with increasing load. In lubricated conditions, the
measured profile recovers almost perfectly the predicted profile. These results
are interpreted as a consequence of the finite compliance of the multicontact
interface, a mechanism which is not taken into account in Amontons' law
Semi-industrial development of nutritious and healthy seafood dishes from sustainable species
This study aimed to devise innovative, tailor-made, appealing, tasty and semi-industrialized dishes, using sustainable and under-utilized seafood species (bib, common dab, common carp, blue mussel and blue whiting), that can meet the specific nutritional and functional needs of children (8-10-years), pregnant women (20-40-years) and seniors (≥60-years). Hence, contests were organised among cooking schools from 6 European countries and the best recipes/dishes were reformulated, semi-industrially produced and chemically and microbiologically evaluated. The dishes intended for: (i) children and pregnant women had EPA + DHA and I levels that reached the target quantities, supporting the claim as “high in I”; and (ii) seniors were “high in protein” (24.8%-Soup_S and 34.0%-Balls_S of the energy was provided by proteins), “high in vitamin B12”, and had Na contents (≤0.4%) below the defined limit. All dishes reached the vitamin D target value. Sausages_C, Roulade_P, Fillet_P and Balls_S had a well-balanced protein/fat ratio. Roulade_P presented the highest n-3 PUFA/n-6 PUFA ratio (3.3), while Sausages_C the lowest SFA/UNS ratio (0.2). Dishes were considered safe based on different parameters (e.g. Hg-T, PBDEs, Escherichia coli). All represent dietary sources contributing to meet the reference intakes of target nutrients (33->100%), providing valuable options to overcome nutritional and functional imbalances of the three groups.This project has received funding from the European Union's Horizon 2020 research and innovation programme under Grant Agreement no. 773400 (SEAFOODTOMORROW). This work was also supported by the Spanish Ministry of Science and Innovation (Project CEX 2018-000794-S), the Generalitat de Catalunya (Consolidated Research Group Water and Soil Quality Unit 2017 SGR 1404) and Fundação para a Ciência e a Tecnologia (FCT)/Ministério da Ciência, Tecnologia e Ensino Superior (MCTES) through national funds (UID/QUI/50006/2019, UIDB/50006/2020, UIDP/50006/2020, UIDB/04423/2020 and UIDP/04423/2020). The authors also thank FCT and the European Union's H2020 Research and Innovation Programme for funding through the project Systemic - An integrated approach to the challenge of sustainable food systems: adaptive and mitigatory strategies to address climate change and malnutrition. Sara Cunha also acknowledges FCT for the IF/01616/2015 contract. Biotage is acknowledged for providing SPE cartridges and Bekolut for the QuEChERS kits. This output reflects the views only of the author(s), and the European Union cannot be held responsible for any use that may be made of the information contained therein
Lateral heat diffusion in layered structures: Theory and photothermal experiments
It is very important to understand how the heat
diffuses in the case of nano objects and of layered structures. We will
demonstrate that the lateral diffusion could be very different in the case
of a good conductor layer deposited on a bad one and for the reverse (bad
one on good substrate). Moreover, we will show how a thermoreflectance
experiment can reveal both the thermal conductivity and the thermal
diffusivity of thin layers deposited on substrates
Viscoelastic dewetting of a polymer film on a liquid substrate
The Dewetting of thin polymer films (60–300 nm) on a
non-wettable liquid substrate has been studied in the vicinity of
their glass transition temperature. In our experiment, we observe a global
contraction of the film while its thickness remains uniform. We
show that, in this case, the strain corresponds to simple extension, and we verify that it is linear with the stress applied by
the surface tension. This allows direct measurement of the
stress/strain response as a function of time, and thus permits the
measurement of an effective compliance of the thin films. It is,
however, difficult to obtain a complete viscoelastic
characterization, as the short time response is highly dependant on
the physical age of the sample. Experimental results underline the
effects of residual stress and friction when dewetting is analyzed
on rigid substrates
Local friction at a sliding interface between an elastomer and a rigid spherical probe
This paper reports on spatially resolved measurements of the shear stress distribution at a frictional interface between a flat rubber substrate and a glass lens. Silicone rubber specimens marked close to their surface by a colored pattern have been prepared in order to measure the surface displacement field induced by the steady-state friction of the spherical probe. The deconvolution of this displacement field then provides the actual shear stress distribution at the contact interface. When a smooth glass lens is used, a nearly constant shear stress is achieved within the contact. On the other hand, a bell-shaped shear stress distribution is obtained with rough lenses. These first results suggest that simple notions of real contact area and constant interface shear stress cannot account for the observed changes in local friction when roughness is varied
Particle structuring under the effect of an uniaxial deformation in soft/hard nanocomposites
A model nanocomposite sample, made of rigid monodisperse spherical inclusions in a deformable matrix, was uniaxially stretched. The displacement field of the particles at the sample surface is analyzed using atomic force microscopy. It is shown that its 2D structure factor presents most of the characteristic features previously described from scattering experiments on similar materials. At the scale of the particles, distortions from affinity are observed. They can be explained by the radial interactions between neighboring inclusions, related to the mechanical confinement of the matrix between particles. At larger scales, remarkable alignments of particles are observed along a direction which is roughly perpendicular to the stretching direction. We show that this effect is found in other soft/hard nanocomposites. It may contribute to the mechanical properties of this class of heterogeneous materials