Two-dimensional impurity imaging in deep Antarctic ice cores: snapshots of three climatic periods and implications for high-resolution signal interpretation

Due to its micrometer-scale resolution and inherently micro-destructive nature, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is particularly suited to exploring the thin and closely spaced layers in the oldest sections of polar ice cores. Recent adaptions to the LA-ICP-MS instrumentation mean we have faster washout times allowing state-of-the-art 2-D imaging of an ice core. This new method has great potential especially when applied to the localization of impurities on the ice sample, something that is crucial, to avoiding misinterpretation of the ultra-fine-resolution signals. Here we present the first results of the application of LA-ICP-MS elemental imaging to the analysis of selected glacial and interglacial samples from the Talos Dome and EPICA Dome C ice cores from central Antarctica. The localization of impurities from both marine and terrestrial sources is discussed, with special emphasis on observing a connection with the network of grain boundaries and differences between different climatic periods. Scale-dependent i mage analysis shows that the spatial significance of a single line profile along the main core axis increases systematically as the imprint of the grain boundaries weakens. It is demon-strated how instrumental settings can be adapted to suit the purpose of the analysis, i.e., by either employing LA-ICP-MS to study the interplay between impurities and the ice microstructure or to investigate the extremely thin climate proxy signals in deep polar ice

Fire and climate: Biomass burning recorded in ice and lake cores

Human activities including fossil fuel burning are currently altering the global climate system at rates faster than ever recorded in geologic time. Biomass burning causes carbon dioxide emissions equal to 50% of those from fossil-fuel combustion and so are highly likely to influence future climate change. However, aerosols continue to be one of the least understood aspects of the modern climate system and even less is known about their past influence. Ice and lake core proxy records provide quantifiable data on past fire regimes across most spatial and temporal scales. Some monosaccharide anhydrides such as levoglucosan, mannosan and galactosan are used as specific molecular markers for biomass burning as they can only be produced by combustion processes at temperatures greater than 300 °C and are present in both ice and lake cores. Other paleofire tracers such as microcharcoal, polycyclic aromatic hydrocarbons, and pollen records augment the fire history derived at single sites or across regions. As both pyrochemical and climate parameters are determined from the same depth and time within the ice or sediment matrix, the multi-proxy nature of ice and lake cores presents an ideal material to investigate the links between fires and climate change

A year-round measurement of water-soluble trace and rare earth elements in arctic aerosol: Possible inorganic tracers of specific events

This study presents the year-round variability of the water-soluble fraction of trace elements (wsTE) and rare earth elements (wsREE) among size segregated airborne particulate matter samples collected at Ny-Å lesund in the Svalbard Archipelago from 26 February 2018 to 26 February 2019. Six different aerosol dimensional fractions were collected using a multi-stage Andersen impactor to better understand local and global circulation with the aim of disentangling the source of inorganic tracers from specific natural or anthropogenic sources. The wsTE and wsREE content, especially in the finest fractions in remote areas, is primarily related to long-range transport and it gives valuable information on (1) the global circulation, (2) the natural sources and (3) the contribution of human activities to aerosol composition. A Factor Analysis was applied to the dataset, including levoglucosan and methanesulfonic acid (MSA), to assess the possibility of using certain inorganic tracers as indicators of specific transport events or circulation regimes. We also investigate back-trajectories to determine potential source areas

Fire, vegetation, and Holocene climate in a southeastern Tibetan lake: A multi-biomarker reconstruction from Paru Co

The fire history of the Tibetan Plateau over centennial to millennial timescales is not well known. Recent ice core studies reconstruct fire history over the past few decades but do not extend through the Holocene. Lacustrine sedimentary cores, however, can provide continuous records of local environmental change on millennial scales during the Holocene through the accumulation and preservation of specific organic molecular biomarkers. To reconstruct Holocene fire events and vegetation changes occurring on the southeastern Tibetan Plateau and the surrounding areas, we used a multi-proxy approach, investigating multiple biomarkers preserved in core sediment samples retrieved from Paru Co, a small lake located in the Nyainqentanglha Mountains (29°47045.600N, 92°21007.200 E; 4845ma.s.l.). Biomarkers include n-alkanes as indicators of vegetation, polycyclic aromatic hydrocarbons (PAHs) as combustion proxies, fecal sterols and stanols (FeSts) as indicators of the presence of humans or grazing animals, and finally monosaccharide anhydrides (MAs) as specific markers of vegetation burning processes. Insolation changes and the associated influence on the Indian summer monsoon (ISM) affect the vegetation distribution and fire types recorded in Paru Co throughout the Holocene. The early Holocene (10.7- 7.5 cal kyr BP) n-alkane ratios demonstrate oscillations between grass and conifer communities, resulting in respective smouldering fires represented by levoglucosan peaks, and high-temperature fires represented by high-molecular-weight PAHs. Forest cover increases with a strengthened ISM, where coincident high levoglucosan to mannosan (L = M) ratios are consistent with conifer burning. The decrease in the ISM at 4.2 cal kyr BP corresponds with the expansion of regional civilizations, although the lack of human FeSts above the method detection limits excludes local anthropogenic influence on fire and vegetation changes. The late Holocene is characterized by a relatively shallow lake surrounded by grassland, where all biomarkers other than PAHs display only minor variations. The sum of PAHs steadily increases throughout the late Holocene, suggesting a net increase in local to regional combustion that is separate from vegetation and climate change

Continuous flow analysis method for determination of soluble iron and aluminium in ice cores

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Permafrost dynamics and the risk of anthrax transmission: a modelling study

A recent outbreak of anthrax disease, severely affecting reindeer herds in Siberia, has been reportedly associated to the presence of infected carcasses or spores released from the active layer over permafrost, which is thawing and thickening at increasing rates, thus underlying the re-emerging nature of this pathogen in the Arctic region because of warming temperatures. Anthrax is a global zoonotic and epizootic disease, with a high case-fatality ratio in infected animals. Its transmission is mediated by environmental contamination through highly resistant spores which can persist in the soil for several decades. Here we develop and analyze a new epidemiological model for anthrax transmission that is specifically tailored to the Arctic environmental conditions. The model describes transmission dynamics including also herding practices (e.g. seasonal grazing) and the role of the active layer over permafrost acting as a long-term storage of spores that could be viable for disease transmission during thawing periods. Model dynamics are investigated through linear stability analysis, Floquet theory for periodically forced systems, and a series of simulations with realistic forcings. Results show how the temporal variability of grazing and active layer thawing may influence the dynamics of anthrax disease and, specifically, favor sustained pathogen transmission. Particularly warm years, favoring deep active layers, are shown to be associated with an increase risk of anthrax outbreaks, and may also foster infections in the following years. Our results enable preliminary insights into measures (e.g. changes in herding practice) that may be adopted to decrease the risk of infection and lay the basis to possibly establish optimal procedures for preventing transmission; furthermore, they elicit the need of further investigations and observation campaigns focused on anthrax dynamics in the Arctic environment

Ice Core Science Meets Computer Vision: Challenges and Perspectives

Polar ice cores play a central role in studies of the earth's climate system through natural archives. A pressing issue is the analysis of the oldest, highly thinned ice core sections, where the identification of paleoclimate signals is particularly challenging. For this, state-of-the-art imaging by laser-ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) has the potential to be revolutionary due to its combination of micron-scale 2D chemical information with visual features. However, the quantitative study of record preservation in chemical images raises new questions that call for the expertise of the computer vision community. To illustrate this new inter-disciplinary frontier, we describe a selected set of key questions. One critical task is to assess the paleoclimate significance of single line profiles along the main core axis, which we show is a scale-dependent problem for which advanced image analysis methods are critical. Another important issue is the evaluation of post-depositional layer changes, for which the chemical images provide rich information. Accordingly, the time is ripe to begin an intensified exchange among the two scientific communities of computer vision and ice core science. The collaborative building of a new framework for investigating high-resolution chemical images with automated image analysis techniques will also benefit the already wide-spread application of LA-ICP-MS chemical imaging in the geosciences.Comment: 9 pages, 2 figures, submitted to Frontiers in Computer Science, section Computer Visio

Iron speciation in aerosol dust influences iron bioavailability over glacial-interglacial timescales

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Trace and rare earth elements determination in milk whey from the Veneto region, Italy

Multi-element analyses determine the content of 17 trace elements (Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Sr, Cd, Cs, Ba, Pb, U) and 14 rare earth elements (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, Lu, Y) in whey samples from cow and goat milk by inductively coupled plasma mass spectrometry and inductively coupled plasma-sector field mass spectrometry. A total of 261 milk whey samples were collected from four locations in the Veneto region of northeastern (NE) Italy. These samples contain a wide range concentration of 17 trace elements (0.06–1530 μg kg−1) and 14 rare earth elements (0.16–28.2 ng kg−1) in whey samples, but do not reach toxic concentrations. Elemental fingerprinting of trace and rare earth elements in cow and goat milk whey provide information on the dairy quality and, as they reflect the local environmental conditions, result in an excellent indicator of their geographical origin

Endovascular Treatment of Aorto-iliac Aneurysms: Four-year Results of Iliac Branch Endograft

Introduction: The aim of this report was to analyse early and mid-term outcomes of endovascular treatment (endovascular aneurysm repair, EVAR) for aorto-iliac aneurysms with the use of an iliac branch device (IBD). Report: A total of 85 EVAR procedures with IBD were electively carried out in 81 patients between September 2007 and August 2012. Technical success was obtained in 98.7% of the cases. The mean follow-up duration was 20.4 months (SD ± 15.4). There was one IBD occlusion (1.2%). Estimated 48 months' survival, freedom from re-intervention and branch occlusion were 76.7%, 88.3% and 98%, respectively. Conclusions: EVAR for aorto-iliac aneurysms using IBD is an effective procedure with low complication and re-intervention rates at mid-term follow-up