Charge Carrier Concentration and Temperature Dependent Recombination in Polymer Fullerene Solar Cells

We performed temperature dependent transient photovoltage and photocurrent measurements on poly(3-hexylthiophene):[6,6]-phenyl-C61 butyric acid methylester bulk heterojuction solar cells. We found a strongly charge carrier concentration and temperature dependent Langevin recombination prefactor. The observed recombination mechanism is discussed in terms of bimolecular recombination. The experimental results were compared with charge carrier extraction by linearly increasing voltage (photo-CELIV) measurements done on the same blend system. We explain the charge carrier dynamics, following an apparent order larger than two, by dynamic trapping of charges in the tail states of the gaussian density of states.Comment: 4 pages, 3 figures, 1 tabl

The Superhorizon Test of Future B-mode Experiments

Inflation predicts B-mode polarization with correlations that span superhorizon scales at recombination. In contrast, the correlations set up by causal sources, such as phase transitions or defects, necessarily vanish on superhorizon scales. Motivated by BICEP2's B-mode detection, we consider the prospects for measuring the inflationary superhorizon signature in future observations. We explain that the finite resolution of an experiment and the filtering of the raw data induces a transfer of spurious subhorizon power to superhorizon scales, and describe ways to correct for it. We also provide a detailed treatment of possible sources of noise in the measurement. Finally, we present forecasts for the detectability of the signal with future CMB polarization experiments.Comment: 16 pages, 9 figures, 2 table

On the predictive power of Local Scale Invariance

Local Scale Invariance (LSI) is a theory for anisotropic critical phenomena designed in the spirit of conformal invariance. For a given representation of its generators it makes non-trivial predictions about the form of universal scaling functions. In the past decade several representations have been identified and the corresponding predictions were confirmed for various anisotropic critical systems. Such tests are usually based on a comparison of two-point quantities such as autocorrelation and response functions. The present work highlights a potential problem of the theory in the sense that it may predict any type of two-point function. More specifically, it is argued that for a given two-point correlator it is possible to construct a representation of the generators which exactly reproduces this particular correlator. This observation calls for a critical examination of the predictive content of the theory.Comment: 17 pages, 2 eps figure

Ageing in disordered magnets and local scale-invariance

The ageing of the bond-disordered two-dimensional Ising model quenched to below its critical point is studied through the two-time autocorrelator and thermoremanent magnetization (TRM). The corresponding ageing exponents are determined. The form of the scaling function of the TRM is well described by the theory of local scale-invariance.Comment: Latex2e, with epl macros, 7 pages, final for

Ageing without detailed balance: local scale invariance applied to two exactly solvable models

I consider ageing behaviour in two exactly solvable reaction-diffusion systems. Ageing exponents and scaling functions are determined. I discuss in particular a case in which the equality of two critical exponents, known from systems with detailed balance, does not hold any more. Secondly it is shown that the form of the scaling functions can be understood by symmetry considerations.Comment: 6 pages, contribution to the summer school "Ageing and the Glass Transition" held in Luxemburg in September 05. Published versio

Learning from the world - Adding a strategic dimension to lesson-drawing from successful sustainable transport policies

This paper investigates how planning practitioners can increase the effectiveness of lesson-drawing from exemplary case studies in sustainable urban transport development. There are a number of cities worldwide that have successfully managed a transition in their transport systems towards providing attractive and efficient structures for public transport, walking, and cycling in liveable communities. Several studies have analysed these successful examples of sustainable transport development, and a related body of literature investigates their transferability to other cities. Based on a review of the existing literature on lesson-drawing and policy transfer, this paper finds that current practice mainly focuses on the content of what has been implemented in exemplary case studies. We suggest that there are additional lessons that practitioners can learn from investigating how a successful program has been implemented, and how practitioners have contributed to this success by advocating their subjects in the political arena. These strategic lessons are especially valuable with regards to interventions that promote sustainability, as these are often discussed in a climate of polarised or adversarial ideas and interests in civil society. The paper concludes with suggesting three areas for strategic lesson-drawing: suitable policy windows, the role of key individuals, and the quality of stakeholder debate

Persistent photovoltage in methylammonium lead iodide perovskite solar cells

Open circuit voltage decay measurements are performed on methylammonium lead iodide (CH3NH3PbI3) perovskite solar cells to investigate the charge carrier recombination dynamics. The measurements are compared to the two reference polymer-fullerene bulk heterojunction solar cells based on P3HT:PC60BM and PTB7:PC70BM blends. In the perovskite devices, two very different time domains of the voltage decay are found, with a first drop on a short time scale that is similar to the organic solar cells. However, two major differences are also observed. 65-70% of the maximum photovoltage persists on much longer timescales, and the recombination dynamics are dependent on the illumination intensity.Comment: 5 pages, 3 figure

Structures for small scientific satellites

Structures and design for scientific satellite

A Field Range Bound for General Single-Field Inflation

We explore the consequences of a detection of primordial tensor fluctuations for general single-field models of inflation. Using the effective theory of inflation, we propose a generalization of the Lyth bound. Our bound applies to all single-field models with two-derivative kinetic terms for the scalar fluctuations and is always stronger than the corresponding bound for slow-roll models. This shows that non-trivial dynamics can't evade the Lyth bound. We also present a weaker, but completely universal bound that holds whenever the Null Energy Condition (NEC) is satisfied at horizon crossing.Comment: 16 page