Control of Diseases in the Home Lawn.

4 p

Control Diseases in the Home Lawn.

4 p

Green synthesis and photocatalytic dye degradation activity of CuO Nanoparticles

This project was supported by Researchers Supporting Project Number (RSP-2023R7) King Saud University, Riyadh, Saudi Arabia. S.A.C.C. acknowledges support from FCT/MCTES (Fundação para a Ciência e Tecnologia and Ministério da Ciência, Tecnologia e Ensino Superior) through projects UIDB/50006/2020 and UIDP/50006/2020 and for the Scientific Employment Stimulus—Institutional Call (CEECINST/00102/2018). The authors thank The Islamia University of Bahawalpur for providing basic facilities.The degradation of dyes is a difficult task due to their persistent and stable nature; therefore, developing materials with desirable properties to degrade dyes is an important area of research. In the present study, we propose a simple, one-pot mechanochemical approach to synthesize CuO nanoparticles (NPs) using the leaf extract of Seriphidium oliverianum, as a reducing and stabilizing agent. The CuO NPs were characterized via X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence (PL) and Fourier-transform infrared spectroscopy (FTIR). The photocatalytic activity of CuO NPs was monitored using ultraviolet-visible (UV-Vis) spectroscopy. The CuO NPs exhibited high potential for the degradation of water-soluble industrial dyes. The degradation rates for methyl green (MG) and methyl orange (MO) were 65.231% ± 0.242 and 65.078% ± 0.392, respectively. Bio-mechanochemically synthesized CuO NPs proved to be good candidates for efficiently removing dyes from waterpublishersversionpublishe

Risk-shifting Through Issuer Liability and Corporate Monitoring

This article explores how issuer liability re-allocates fraud risk and how risk allocation may reduce the incidence of fraud. In the US, the apparent absence of individual liability of officeholders and insufficient monitoring by insurers under-mine the potential deterrent effect of securities litigation. The underlying reasons why both mechanisms remain ineffective are collective action problems under the prevailing dispersed ownership structure, which eliminates the incentives to moni-tor set by issuer liability. This article suggests that issuer liability could potentially have a stronger deterrent effect when it shifts risk to individuals or entities holding a larger financial stake. Thus, it would enlist large shareholders in monitoring in much of Europe. The same risk-shifting effect also has implications for the debate about the relationship between securities litigation and creditor interests. Credi-tors’ claims should not be given precedence over claims of defrauded investors (e.g., because of the capital maintenance principle), since bearing some of the fraud risk will more strongly incentivise large creditors, such as banks, to monitor the firm in jurisdictions where corporate debt is relatively concentrated

WISEA J083011.95+283716.0: A Missing Link Planetary-mass Object

We present the discovery of WISEA J083011.95+283716.0, the first Y-dwarf candidate identified through the "Backyard Worlds: Planet 9" citizen science project. We identified this object as a red, fast-moving source with a faint W2 detection in multiepoch AllWISE and unWISE images. We have characterized this object with Spitzer and Hubble Space Telescope's (HST) follow-up imaging. With mid-infrared detections in Spitzer's ch1 and ch2 bands and flux upper limits in HST F105W and F125W filters, we find that this object is both very faint and has extremely red colors (ch1 − ch2 = 3.25 ± 0.23 mag, F125W − ch2 ≥ 9.36 mag), consistent with a T_(eff) ~ 300 K source, as estimated from the known Y-dwarf population. A preliminary parallax provides a distance of 11.1_(-1.5)^(+2.0) pc, leading to a slightly warmer temperature of ~350 K. The extreme faintness and red HST and Spitzer colors of this object suggest that it may be a link between the broader Y-dwarf population and the coldest known brown dwarf WISE J0855−0714, and may highlight our limited knowledge of the true spread of Y-dwarf colors. We also present four additional "Backyard Worlds: Planet 9" late-T brown dwarf discoveries within 30 pc

WISEA J083011.95+283716.0: A Missing Link Planetary-Mass Object

We present the discovery of WISEA J083011.95+283716.0, the first Y dwarf candidate identified through the Backyard Worlds: Planet 9 citizen science project. We identified this object as a red, fast-moving source with a faint $W2$ detection in multi-epoch \textit{AllWISE} and unWISE images. We have characterized this object with Spitzer Space Telescope and \textit{Hubble Space Telescope} follow-up imaging. With mid-infrared detections in \textit{Spitzer}'s \emph{ch1} and \emph{ch2} bands and flux upper limits in Hubble Space Telescope $F105W$ and $F125W$ filters, we find that this object is both very faint and has extremely red colors ($ch1-ch2 = 3.25\pm0.23$ mag, $F125W-ch2 \geq 9.36$ mag), consistent with a T$_{eff}\sim300$ K source, as estimated from the known Y dwarf population. A preliminary parallax provides a distance of $11.1^{+2.0}_{-1.5}$ pc, leading to a slightly warmer temperature of $\sim350$ K. The extreme faintness and red Hubble Space Telescope and Spitzer Space Telescope colors of this object suggest it may be a link between the broader Y dwarf population and the coldest known brown dwarf WISE J0855$-$0714, and highlight our limited knowledge of the true spread of Y dwarf colors. We also present four additional Backyard Worlds: Planet 9 late-T brown dwarf discoveries within 30 pc.Comment: 13 pages, 6 figures, 5 table

Health Care for Mitochondrial Disorders in Canada: A Survey of Physicians

Background: An improved understanding of diagnostic and treatment practices for patients with rare primary mitochondrial disorders can support benchmarking against guidelines and establish priorities for evaluative research. We aimed to describe physician care for patients with mitochondrial diseases in Canada, including variation in care. Methods: We conducted a cross-sectional survey of Canadian physicians involved in the diagnosis and/or ongoing care of patients with mitochondrial diseases. We used snowball sampling to identify potentially eligible participants, who were contacted by mail up to five times and invited to complete a questionnaire by mail or internet. The questionnaire addressed: personal experience in providing care for mitochondrial disorders; diagnostic and treatment practices; challenges in accessing tests or treatments; and views regarding research priorities. Results: We received 58 survey responses (52% response rate). Most respondents (83%) reported spending 20% or less of their clinical practice time caring for patients with mitochondrial disorders. We identified important variation in diagnostic care, although assessments frequently reported as diagnostically helpful (e.g., brain magnetic resonance imaging, MRI/MR spectroscopy) were also recommended in published guidelines. Approximately half (49%) of participants would recommend mitochondrial cocktails for all or most patients, but we identified variation in responses regarding specific vitamins and cofactors. A majority of physicians recommended studies on the development of effective therapies as the top research priority. Conclusions: While Canadian physicians\u27 views about diagnostic care and disease management are aligned with published recommendations, important variations in care reflect persistent areas of uncertainty and a need for empirical evidence to support and update standard protocols