Radiation/convection coupling in rocket motor and plume analysis

A method for describing radiation/convection coupling to a flow field analysis was developed for rocket motors and plumes. The three commonly used propellant systems (H2/O2, RP-1/O2, and solid propellants) radiate primarily as: molecular emitters, non-scattering small particles (soot), and scattering larger particles (Al2O3), respectively. For the required solution, the divergence of the radiation heat flux was included in the energy equation, and the local, volume averaged intensity was determined by a solution to the radiative transfer equation. A rigorous solution to this problem is intractable, therefore, solution methods which use the ordinary and improved differential approximation were developed. This radiation model was being incorporated into the FDNS code, a Navier-Stokes flowfield solver for multiphase, turbulent combusting flows

External tank aerothermal design criteria verification

If a Space Shuttle Main Engine (SSME) fails during the initial 160 seconds of the Shuttle flight, a return-to-launch-site maneuver will be implemented. The period of concern for this task is the pitch-around maneuver when the vehicle is flying backward. The intent of this report is to identify and define the flowfield at the most critical locations from an environment perspective. The solution procedure used to predict the plume heating rates involves both computational analysis and engineering modeling

Slowly, slowly in the wind: 3D hydrodynamical simulations of wind mass transfer and angular-momentum loss in AGB binary systems

Wind mass transfer in binary systems with AGB donor stars plays a fundamental role in the formation of a variety of objects, including barium stars and CEMP stars. We carry out a comprehensive set of SPH simulations of wind-losing AGB stars in binaries, for a variety of binary mass ratios, orbital separations, initial wind velocities and rotation rates of the donor star. The initial parameters of the simulated systems are chosen to match the expected progenitors of CEMP stars. We find that the strength of interaction between the wind and the stars depends on both the wind-velocity-to-orbital-velocity ratio ($v_\infty/v_\mathrm{orb}$) and the binary mass ratio. Strong interaction occurs for close systems and comparable mass ratios, and gives rise to a complex morphology of the outflow and substantial angular-momentum loss, which leads to a shrinking of the orbit. As the orbital separation increases and the mass of the companion star decreases, the morphology of the outflow, as well as the angular-momentum loss, become more similar to the spherically symmetric wind case. We also explore the effects of tidal interaction and find that for orbital separations up to 7-10 AU, depending on mass ratio, spin-orbit coupling of the donor star occurs at some point during the AGB phase. If the initial wind velocity is relatively low, we find that corotation of the donor star results in a modified outflow morphology that resembles wind Roche-lobe overflow. In this case the mass-accretion efficiency and angular-momentum loss differ from those found for a non-rotating donor. Finally, we provide a relation for both the mass-accretion efficiency and angular-momentum loss as a function of $v_\infty/v_\mathrm{orb}$ and the binary mass ratio that can be easily implemented in a population synthesis code to study populations of barium stars, CEMP stars and other products of interaction in AGB binaries.Comment: Accepted for publication in A&A, 20 pages, 12 figures, 4 tables. Abstract abridged due to arXiv requirement

Radiation/convection coupling in rocket motors and plumes

The three commonly used propellant systems - H2/O2, RP-1/O2, and solid propellants - primarily radiate as molecular emitters, non-scattering small particles, and scattering larger particles, respectively. Present technology has accepted the uncoupling of the radiation analysis from that of the flowfield. This approximation becomes increasingly inaccurate as one considers plumes, interior rocket chambers, and nuclear rocket propulsion devices. This study will develop a hierarchy of methods which will address radiation/convection coupling in all of the aforementioned propulsion systems. The nature of the radiation/convection coupled problem is that the divergence of the radiative heat flux must be included in the energy equation and that the local, volume-averaged intensity of the radiation must be determined by a solution of the radiative transfer equation (RTE). The intensity is approximated by solving the RTE along several lines of sight (LOS) for each point in the flowfield. Such a procedure is extremely costly; therefore, further approximations are needed. Modified differential approximations are being developed for this purpose. It is not obvious which order of approximations are required for a given rocket motor analysis. Therefore, LOS calculations have been made for typical rocket motor operating conditions in order to select the type approximations required. The results of these radiation calculations, and the interpretation of these intensity predictions are presented herein

Tannin Structural Elucidation and Quantitative P-31 NMR Analysis. 1. Model Compounds

Tannins and flavonoids are secondary metabolites of plants that display a wide array of biological activities. This peculiarity is related to the inhibition of extracellular enzymes that occurs through the complexation of peptides by tannins. Not only the nature of these interactions, but more fundamentally also the structure of these heterogeneous polyphenolic molecules are not completely clear. This first paper describes the development of a new analytical method for the structural characterization of tannins on the basis of tannin model compounds employing an in situ labeling of all labile H groups (aliphatic OH, phenolic OH, and carboxylic acids) with a phosphorus reagent. The P-31 NMR analysis of P-31 labeled samples allowed the unprecedented quantitative and qualitative structural characterization of hydrolyzable tannins, proanthocyanidins, and catechin tannin model compounds, forming the foundations for the quantitative structural elucidation of a variety of actual tannin samples described in part 2 of this series

An efficient and stereoselective dearylation of asarinin and sesamin tetrahydrofurofuran lignans to acuminatolide by methyltrioxorhenium/H2O2 and UHP systems

The synthesis of stereoisomers of acuminatolide is rare and requires complex and time-consuming multistep procedures. Asarinin (1) and sesamin (2), two diasteromeric tetrahydrofurofuran lignans, are efficiently mono-dearylated by methyltrioxorhenium (MTO, I) and hydrogen peroxide (H2O2) or urea hydrogen peroxide adduct (UHP) as primary oxidant to give (-)-(7R,8'R,8R)-acuminatolide (3A) and (+)-(7S,8R,8'R)-acuminatolide (3B), respectively, in high yield and diastereoselectivity (de > 98%). The oxidation of 1 was also performed with novel heterogeneous catalysts based on the heterogenation of MTO on poly(4-vinylpyridine) and polystyrene resins. In these latter cases 3A was obtained with a different yield and selectivity depending on the physical-chemical properties of the support. Cytotoxic effects of 3A and 3B in mammalian cell lines in vitro are also reported

Durum wheat growth analysis in a semiarid environment in relation to crop rotation and nitrogen rate

SUMMARY – A research on durum wheat growth analysis was carried out at Sparacia farm (37°37’N-13°42’E) during the 2000-2001 and 2001-2002 seasons in a typical semi-arid environment. The objective of this research was to determine the effects of crop rotation (continuous wheat and wheat-pea rotation) and N fertilizer rates (0, 60 and 120 Kg ha-1) on growth of four durum wheat varieties, characterized by different productive ability and adaptation. A split- split-plot design with three replications was used. The study highlighted the role of the CGR index in order to enable a better knowledge of the relationship among crop techniques and wheat yield respons

Multimetallic Oxynitrides Nanoparticles for a New Generation of Photocatalysts

A versatile synthetic strategy for the preparation of multimetallic oxynitrides has been designed and here exemplarily discussed considering the preparation of nanoscaled zinc\u2013gallium oxynitrides and zinc\u2013gallium\u2013indium oxynitrides, two important photocatalysts of new generation, which proved to be active in key energy related processes from pollutant decomposition to overall water splitting. The synthesis presented here allows the preparation of small nanoparticles (less than 20 nm in average diameter), well-defined in size and shape, yet highly crystalline and with the highest surface area reported so far (up to 80 m2 g 121). X-ray diffraction studies show that the final material is not a mixture of single oxides but a distinctive compound. The photocatalytic properties of the oxynitrides have been tested towards the decomposition of an organic dye (as a model reaction for the decomposition of air pollutants), showing better photocatalytic performances than the corresponding pure phases (reaction constant 0.22 h 121), whereas almost no reaction was observed in absence of catalyst or in the dark. The photocatalysts have been also tested for H2 evolution (semi-reaction of the water splitting process) with results comparable to the best literature values but leaving room for further improvement

Formamide as the main building block in the origin of nucleic acids

The simplest molecules grouping the four most common elements of the universe H,C,O and N (with the exception of the biologically inert He) are isocyanate HNCO and formamide H2NCOH. Reasons for the availability of formamide on prebiotic Earth are presented. We review evidence showing that formamide in the presence of largely available catalysts and by moderate heating yields the complete set of nucleic bases necessary for the formation of nucleic acids. Formamide also favours the formation of acyclonucleosides and the phosphorylation and trans-phosphorylation of nucleosides, thus providing a plausible chemical frame for the passage from a simple one-carbon compound to nucleic polymers. Physico-chemical conditions exist in which formamide favours the stability of the phosphoester bonds in nucleic polymers relative to that of the same bonds in monomers. Starting from a formamide-laden environment subject only to the laws of chemistry, a hypothesis is outlined sketching the passage towards an aqueous world in which Darwinian rules apply