618 research outputs found
Double exchange magnets: Spin-dynamics in the paramagnetic phase
The electronic structure of perovskite manganese oxides is investigated in
terms of a Kondo lattice model with ferromagnetic Hund coupling and
antiferromagnetic exchange between -spins using a finite temperature
diagonalization technique. Results for the dynamic structure factor are
consistent with recent neutron scattering experiments for the bilayer manganite
LaSrMnO . The susceptibility shows Curie-Weiss
behaviour and is used to derive a phase diagram. In the paramagnetic phase
carriers are characterized as ferromagnetic polarons in an antiferromagnetic
spin liquid.Comment: Revtex, 4 pages with 5 postscript figures include
Determination of the crystal structure of CuSnTi by full profile Rietveld analysis
The crystal structure of the new ternary phase CuSnTi is determined by full profile Rietveld analysis of the powder diffractogram. 104 reflections were refined to a final RBragg value of 5.60%. CuSnTi crystallizes with the spacegroup P63/mmc and is isostructural to InNi2. The lattice parameters are a=0.439 555(5) nm and c=0.601 505(9) n
Inelastic neutron scattering studies of the quantum frustrated magnet clinoatacamite, -Cu2(OD)3Cl, a proposed valence bond solid (VBS)
The frustrated magnet clinoatacamite, -Cu(OH)Cl, is
attracting a lot of interest after suggestions that at low temperature it forms
an exotic quantum state termed a Valence Bond Solid (VBS) made from dimerised
Cu () spins.\cite{Lee_clinoatacamite} Key to the arguments
surrounding this proposal were suggestions that the kagom\'e planes in the
magnetic pyrochlore lattice of clinoatacamite are only weakly coupled, causing
the system to behave as a quasi-2-dimensional magnet. This was reasoned from
the near 95 angles made at the bridging oxygens that mediate exchange
between the Cu ions that link the kagom\'e planes.
Recent work pointed out that this exchange model is inappropriate for
-Cu(OH)Cl, where the oxygen is present as a
-OH.\cite{Wills_JPC} Further, it used symmetry calculations and neutron
powder diffraction to show that the low temperature magnetic structure (
K) was canted and involved significant spin ordering on all the Cu
spins, which is incompatible with the interpretation of simultaneous VBS and
N\'eel ordering. Correspondingly, clinoatacamite is best considered a distorted
pyrochlore magnet. In this report we show detailed inelastic neutron scattering
spectra and revisit the responses of this frustrated quantum magnet.Comment: Proceedings of The International Conference on Highly Frustrated
Magnetism 2008 (HFM2008
Global and regional effects of the photochemistry of CH_3O_2NO_2: evidence from ARCTAS
Using measurements from the NASA Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) experiment, we show that methyl peroxy nitrate (CH_3O_2NO_2) is present in concentrations of ~5ā15 pptv in the springtime arctic upper troposphere. We investigate the regional and global effects of CH_3O_2NO_2 by including its chemistry in the GEOS-Chem 3-D global chemical transport model. We find that at temperatures below 240 K inclusion of CH_3O_2NO_2 chemistry results in decreases of up to ~20 % in NO_x, ~20 % in N_2O_5, ~5 % in HNO3, ~2 % in ozone, and increases in methyl hydrogen peroxide of up to ~14 %. Larger changes are observed in biomass burning plumes lofted to high altitude. Additionally, by sequestering NO_x at low temperatures, CH_3O_2NO_2 decreases the cycling of HO_2 to OH, resulting in a larger upper tropospheric HO_2 to OH ratio. These results may impact some estimates of lightning NO_x sources as well as help explain differences between models and measurements of upper tropospheric composition
Spin pseudogap in Ni-doped SrCuO2
The S=1/2 spin chain material SrCuO2 doped with 1% S=1 Ni-impurities is
studied by inelastic neutron scattering. At low temperatures, the spectrum
shows a pseudogap \Delta ~ 8 meV, absent in the parent compound, and not
related to any structural phase transition. The pseudogap is shown to be a
generic feature of quantum spin chains with dilute defects. A simple model
based on this idea quantitatively accounts for the exprimental data measured in
the temperature range 2-300 K, and allows to represent the momentum-integrated
dynamic structure factor in a universal scaling form.Comment: 5 pages, 3 figure
The production and persistence of Ī£RONO2 in the Mexico City plume
Alkyl and multifunctional nitrates (RONO2, Ī£ANs) have been observed to be a significant fraction of NOy in a number of different chemical regimes. Their formation is an important free radical chain termination step ending production of ozone and possibly affecting formation of secondary organic aerosol. Ī£ANs also represent a potentially large, unmeasured contribution to OH reactivity and are a major pathway for the removal of nitrogen oxides from the atmosphere. Numerous studies have investigated the role of nitrate formation from biogenic compounds and in the remote atmosphere. Less attention has been paid to the role Ī£ANs may play in the complex mixtures of hydrocarbons typical of urban settings. Measurements of total alkyl and multifunctional nitrates, NO2, total peroxy nitrates (Ī£PNs), HNO3 and a representative suite of hydrocarbons were obtained from the NASA DC-8 aircraft during spring of 2006 in and around Mexico City and the Gulf of Mexico. Ī£ANs were observed to be 10ā20% of NOy in the Mexico City plume and to increase in importance with increased photochemical age. We describe three conclusions: (1) Correlations of Ī£ANs with odd-oxygen (Ox) indicate a stronger role for Ī£ANs in the photochemistry of Mexico City than is expected based on currently accepted photochemical mechanisms, (2) Ī£AN formation suppresses peak ozone production rates by as much as 40% in the near-field of Mexico City and (3) Ī£ANs play a significant role in the export of NOy from Mexico City to the Gulf Region
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