16 research outputs found
Polyoxometalate/polymer composites for the photodegradation of organic dyes
International audienc
Valuation of biomass residues by oxidative depolymerization using ionic liquids based on polyoxometalate anions
International audienc
Valuation of biomass residues by oxidative depolymerization using ionic liquids based on polyoxometalate anions
International audienc
IR Spectroscopic Investigation of Heteropolymolybdate Catalysts: Acidic Properties and Reactivity towards Propene
Selective conversion of {Mo-132} Keplerate ion into 4-electron reduced crown-capped Keggin derivative Te5Mo15O57 (8-). A key intermediate to single-phase M1 multielement MoVTeO light-alkanes oxidation catalyst
22 Canioni, Romain Marchal-Roch, Catherine Leclerc-Laronze, Nathalie Haouas, Mohamed Taulelle, Francis Marrot, Jerome Paul, Sebastien Lamonier, Carole Paul, Jean-Francois Loridant, Stephane Millet, Jean-Marc M. Cadot, Emmanuel{Mo-132} Keplerate anion reacts with tellurites to give a soluble precursor to produce in hydrothermal conditions single-phase M1 MoVTeO light-alkanes oxidation catalyst. Characterization of this Te-containing intermediate by single-crystal X-ray diffraction, Te-125 NMR, UV-visible and redox titration reveals a molybdotellurite anion as a crown-capped Keggin derivative