Modélisation des effets hydrochimiques à long terme des dépôts acides et des reboisements dans les bassins versants du Mont-Lozère (Sud de la France)

L'évolution de la chimie des sols et des eaux dans trois petits bassins-versants subméditerranéens granitiques recevant d'importants apports atmosphériques de S04 et de poussières sahariennes a été simulée, de 1845 à 2125, en utilisant le modèle MAGIC. Ce modèle biogéochimique global comporte une série de relations d'équilibre entre les phases gazeuse, liquide et solide (adsorption de soufre, solubilité de l'aluminium, échanges cationiques, système C02/carbonates, dissociation des acides organiques) et une comptabilisation des flux d'éléments (entrées atmosphériques, sorties hydrologiques, immobilisation biologique, altération). Les bassins versants diffèrent par l'historique récente de leur utilisation par l'homme : la pelouse pâturée qui les recouvraient en 1845 n'a subsisté que dans un bassin : elle a été remplacée vers 1930 par une pessière dans l'un des bassins, et colonisée, après abandon, par une hêtraie dans l'autre. Les simulations montrent que le bassin couvert de pelouse a peu souffert de l'augmentation de l'acidité des pluies au cours du XXe siècle, et pourrait subir les apports actuels pendant plus de 100 ans sans dommage. Les deux bassins forestiers s'acidifient fortement depuis 1970 par les effets combinés de la pollution et des reboisements. Pour la pessière, seule une réduction d'au moins 60 % des apports soufrés permettrait d'inverser le processus. Le vieillissement naturel de la hêtraie produirait une amélioration même sans réduction des dépôts acides, en diminuant le taux d'assimilation de cations. Les deux facteurs acidifiants agissent donc en synergie, mais dans le cas de la pessière l'augmentation des apports acides due à l'effet filtrant des frondaisons est prépondérant, alors que dans la hêtraie, la forte immobilisation cationique dans la biomasse perenne jolie un plus grand rôle.Introduction. The combined acidifying effects of afforestation and acid deposition are well documented for sites in North-Western Europe and North America. In acid-sensitive mediterranean areas, acidification has been delayed by lower deposition rates and alkaline aeolian dust input to the ecosystems. Here, the evolution of stream water and soil chemistry, from 1845 to 2125, in three small submediterranean catchments of Southern France, is assessed using the MAGIC model.Sites and methods. Three granitic catchments have been monitored since 1981 in the South-Eastern Massif Central. The mean elevation is 1300 m above sea level and the soils are rankers and acid brown earth. The catchments are submitted to heavy atmospheric deposition of industrial acidic oxides (mainly sulphate : more than 20 kg.ha-1•year-1 of S-S04) and of alkaline saharan dust. The land use was similar in all the catchments up to 1930, and consisted mainly of extensive sheep grazing on semi natural grassland. Then one catchment (19.5 ha) was afforested with conifers (spruce), another catchment (54 ha) was abandoned and progressively settled by a beech coppice, while the other catchment (81 ha) remained covered with grassland. MAGIC is a lumped, process-oriented biogeochemical model, where the soil physical and chemical characteristics are described by a single set of mean variables. The processes in soils are modelled by a series of equilibrium equations : Aluminium solubility, cation exchange, sulphate adsorption, C02 and carbonates equllibria, organic acids dissociation. The changes in the stocks of elements are calculated from the main input, output and internal fluxes : atmospheric deposition, river load, biological uptake and weathering. The calibration aims to get the best fit between measured and simulated values to the « target variables », i.e., the present day exchangeable cations amounts in soils and river chemical composition. Hindcast and forecast runs need historical and prospective scenarios for atmospheric deposition, dry deposition factor, nutrient uptake and discharge. Here, the growth of the forest was modelled by increasing dry deposition factor and nutrient uptake and decreasing the discharge according to the field observations. The sequence of sulphate deposition was derived from S02 emission data. Three scenarios were tested in the forecasts : a constant deposition al the present level, a 30 % reduction and a 60 % reduction within 2010. In both cases, the nutrient uptake of the spruce stand and grassland was kept constant, white those of the beech coppice was progressively decreased to simulate a natural ageing of the forest.Results. The model successfully reproduced the chemistry of the catchments. The values of the optimised parameters suggest that :- the soils of the area have a very high sulphate adsorption capacity;- the weathering rates are similar in the three catchments except for the calcium (lower in the beech catchment) and the magnesium (much higher in the spruce catchment);- the initial conditions calculated by the model for 1845 are slightly different; the alkalinity and cations concentrations are lower, and the base saturation higher, in the beech catchment.The simulations show that for the grassland catchment, there has been little change due to increasing of S04 wet deposition over the last 100 years. The simulations for the other two catchments (beech and spruce stands) show that they have been acidifying since 1970 due to the combined effects of air pollution and afforestation. This trend could lead to a severe decline of soil base saturation and streamwater quality by 2050. Concerning the coniferous catchment, only a 60 % reduction of the sulphur input could allow a recovery. The natural ageing of the beech stand, resulting in a decrease of the biological uptake, would permit a recovery even under constant sulphur deposition.Conclusion. This exercise show that although the effects afforestation and acid deposition are synergetical and difficult to distinguish, their relative importance in acidification processes varies according to the vegetation. In the spruce catchment, the enhanced deposition due to the scavenging properties of the canopy is the determining factor. If no emission reduction occurs and no mitigating measures are taken, the decline of soil and water quality is a serious threat. In the beech catchment, the dynamics of biological uptake prevail, because the trees store a large amount of base cations. If the stand is allowed to age, a recovery can be observed even if no sulphur emission reduction occurs. This is also partly due, in this context, to the scavenging of the alkaline aeolian dust

Etude expérimentale du ruissellement sur des sols à végétation contrastée du Mont Lozère

Les conditions d'apparition du ruissellement de surface, et les valeurs limites que peut atteindre l'infiltration sont étudiés expérimentalement par simulation de pluie sur des sols à végétation contrastée du Mont Lozère (Sud du Massif Central, France), développés sur arène granitique peu profonde. Les résultats mettent en évidence la forte capacité d'infiltration du milieu naturel, mais aussi la grande variabilité spatiale de cette capacité d'infiltration, pour aboutir à un schéma de fonctionnement dans lequel, si la circulation hypodermique, à la limite de la roche saine, demeure le processus essentiel de transfert de l'eau entre son point de chute et le cours d'eau, le ruissellement sur les versants n'est pas exclu et peut jouer un rôle important dans la formation des crues. Par ailleurs il semblerait qu'une pelouse en bon état, couvrant parfaitement le sol, présente une aussi bonne protection contre le ruissellement et l'érosion que les litières forestières testées. (Résumé d'auteur

Effects of nanoparticles on murine macrophages

Metallic nanoparticles are more and more widely used in an increasing number of applications. Consequently, they are more and more present in the environment, and the risk that they may represent for human health must be evaluated. This requires to increase our knowledge of the cellular responses to nanoparticles. In this context, macrophages appear as an attractive system. They play a major role in eliminating foreign matter, e.g. pathogens or infectious agents, by phagocytosis and inflammatory responses, and are thus highly likely to react to nanoparticles. We have decided to study their responses to nanoparticles by a combination of classical and wide-scope approaches such as proteomics. The long term goal of this study is the better understanding of the responses of macrophages to nanoparticles, and thus to help to assess their possible impact on human health. We chose as a model system bone marrow-derived macrophages and studied the effect of commonly used nanoparticles such as TiO2 and Cu. Classical responses of macrophage were characterized and proteomic approaches based on 2D gels of whole cell extracts were used. Preliminary proteomic data resulting from whole cell extracts showed different effects for TiO2-NPs and Cu-NPs. Modifications of the expression of several proteins involved in different pathways such as, for example, signal transduction, endosome-lysosome pathway, Krebs cycle, oxidative stress response have been underscored. These first results validate our proteomics approach and open a new wide field of investigation for NPs impact on macrophagesComment: Nanosafe2010: International Conference on Safe Production and Use of Nanomaterials 16-18 November 2010, Grenoble, France, Grenoble : France (2010

Multi-Armed Bandits for Correlated Markovian Environments with Smoothed Reward Feedback

We study a multi-armed bandit problem in a dynamic environment where arm rewards evolve in a correlated fashion according to a Markov chain. Different than much of the work on related problems, in our formulation a learning algorithm does not have access to either a priori information or observations of the state of the Markov chain and only observes smoothed reward feedback following time intervals we refer to as epochs. We demonstrate that existing methods such as UCB and $\varepsilon$-greedy can suffer linear regret in such an environment. Employing mixing-time bounds on Markov chains, we develop algorithms called EpochUCB and EpochGreedy that draw inspiration from the aforementioned methods, yet which admit sublinear regret guarantees for the problem formulation. Our proposed algorithms proceed in epochs in which an arm is played repeatedly for a number of iterations that grows linearly as a function of the number of times an arm has been played in the past. We analyze these algorithms under two types of smoothed reward feedback at the end of each epoch: a reward that is the discount-average of the discounted rewards within an epoch, and a reward that is the time-average of the rewards within an epoch.Comment: Significant revision of prior version including deeper discussion of related work, gap-independent regret bounds, and regret bounds for discounted reward

Initial Data for General Relativity with Toroidal Conformal Symmetry

A new class of time-symmetric solutions to the initial value constraints of vacuum General Relativity is introduced. These data are globally regular, asymptotically flat (with possibly several asymptotic ends) and in general have no isometries, but a $U(1)\times U(1)$ group of conformal isometries. After decomposing the Lichnerowicz conformal factor in a double Fourier series on the group orbits, the solutions are given in terms of a countable family of uncoupled ODEs on the orbit space.Comment: REVTEX, 9 pages, ESI Preprint 12

Polya's inequalities, global uniform integrability and the size of plurisubharmonic lemniscates

First we prove a new inequality comparing uniformly the relative volume of a Borel subset with respect to any given complex euclidean ball \B \sub \C^n with its relative logarithmic capacity in \C^n with respect to the same ball \B. An analoguous comparison inequality for Borel subsets of euclidean balls of any generic real subspace of \C^n is also proved. Then we give several interesting applications of these inequalities. First we obtain sharp uniform estimates on the relative size of \psh lemniscates associated to the Lelong class of \psh functions of logarithmic singularities at infinity on \C^n as well as the Cegrell class of \psh functions of bounded Monge-Amp\`ere mass on a hyperconvex domain \W \Sub \C^n. Then we also deduce new results on the global behaviour of both the Lelong class and the Cegrell class of \psh functions.Comment: 25 page

Discrete complex analysis on planar quad-graphs

We develop a linear theory of discrete complex analysis on general quad-graphs, continuing and extending previous work of Duffin, Mercat, Kenyon, Chelkak and Smirnov on discrete complex analysis on rhombic quad-graphs. Our approach based on the medial graph yields more instructive proofs of discrete analogs of several classical theorems and even new results. We provide discrete counterparts of fundamental concepts in complex analysis such as holomorphic functions, derivatives, the Laplacian, and exterior calculus. Also, we discuss discrete versions of important basic theorems such as Green's identities and Cauchy's integral formulae. For the first time, we discretize Green's first identity and Cauchy's integral formula for the derivative of a holomorphic function. In this paper, we focus on planar quad-graphs, but we would like to mention that many notions and theorems can be adapted to discrete Riemann surfaces in a straightforward way. In the case of planar parallelogram-graphs with bounded interior angles and bounded ratio of side lengths, we construct a discrete Green's function and discrete Cauchy's kernels with asymptotics comparable to the smooth case. Further restricting to the integer lattice of a two-dimensional skew coordinate system yields appropriate discrete Cauchy's integral formulae for higher order derivatives.Comment: 49 pages, 8 figure

Forced Stratified Turbulence: Successive Transitions with Reynolds Number

Numerical simulations are made for forced turbulence at a sequence of increasing values of Reynolds number, R, keeping fixed a strongly stable, volume-mean density stratification. At smaller values of R, the turbulent velocity is mainly horizontal, and the momentum balance is approximately cyclostrophic and hydrostatic. This is a regime dominated by so-called pancake vortices, with only a weak excitation of internal gravity waves and large values of the local Richardson number, Ri, everywhere. At higher values of R there are successive transitions to (a) overturning motions with local reversals in the density stratification and small or negative values of Ri; (b) growth of a horizontally uniform vertical shear flow component; and (c) growth of a large-scale vertical flow component. Throughout these transitions, pancake vortices continue to dominate the large-scale part of the turbulence, and the gravity wave component remains weak except at small scales.Comment: 8 pages, 5 figures (submitted to Phys. Rev. E

Now the wars are over: The past, present and future of Scottish battlefields

Battlefield archaeology has provided a new way of appreciating historic battlefields. This paper provides a summary of the long history of warfare and conflict in Scotland which has given rise to a large number of battlefield sites. Recent moves to highlight the archaeological importance of these sites, in the form of Historic Scotland’s Battlefields Inventory are discussed, along with some of the problems associated with the preservation and management of these important cultural sites