A Multi-Wavelength Study of Sgr A*: The Role of Near-IR Flares in Production of X-ray, Soft γ\gamma-ray and Sub-millimeter Emission

(abridged) We describe highlights of the results of two observing campaigns in 2004 to investigate the correlation of flare activity in Sgr A* in different wavelength regimes, using a total of nine ground and space-based telescopes. We report the detection of several new near-IR flares during the campaign based on {\it HST} observations. The level of near-IR flare activity can be as low as $\sim0.15$ mJy at 1.6 $\mu$m and continuous up to about 40% of the total observing time. Using the NICMOS instrument on the {\it HST}, the {\it XMM-Newton} and CSO observatories, we also detect simultaneous bright X-ray and near-IR flare in which we observe for the first time correlated substructures as well as simultaneous submillimeter and near-IR flaring. X-ray emission is arising from the population of near-IR-synchrotron-emitting relativistic particles which scatter submillimeter seed photons within the inner 10 Schwarzschild radii of Sgr A* up to X-ray energies. In addition, using the inverse Compton scattering picture, we explain the high energy 20-120 keV emission from the direction toward Sgr A*, and the lack of one-to-one X-ray counterparts to near-IR flares, by the variation of the magnetic field and the spectral index distributions of this population of nonthermal particles. In this picture, the evidence for the variability of submillimeter emission during a near-IR flare is produced by the low-energy component of the population of particles emitting synchrotron near-IR emission. Based on the measurements of the duration of flares in near-IR and submillimeter wavelengths, we argue that the cooling could be due to adiabatic expansion with the implication that flare activity may drive an outflow.Comment: 48 pages, 12 figures, ApJ (in press

Ab initio analysis of the x-ray absorption spectrum of the myoglobin-carbon monoxide complex: Structure and vibrations

We present a comparison between Fe K-edge x-ray absorption spectra of carbonmonoxy-myoglobin and its simulation based on density-functional theory determination of the structure and vibrations and spectral simulation with multiple-scattering theory. An excellent comparison is obtained for the main part of the molecular structure without any structural fitting parameters. The geometry of the CO ligand is reliably determined using a synergic approach to data analysis. The methodology underlying this approach is expected to be especially useful in similar situations in which high-resolution data for structure and vibrations are available.Comment: 13 pages, 3 figure

On the Effects of Dissipative Turbulence on the Narrow Emission-Line Ratios in Seyfert Galaxies

We present a photoionization model study of the effects of micro-turbulence and dissipative heating on emission lines for number and column densities, elemental abundances, and ionizations typical for the narrow emission line regions (NLRs) of Seyfert galaxies. Earlier studies of NLR spectra generally found good agreement between the observations and the model predictions for most strong emission lines, such as [O III] $\lambda$5007, [O II] $\lambda$3727, [N II] $\lambda$6583, [Ne III] $\lambda$3869, and the H and He recombination lines. Nevertheless, the strengths of lines from species with ionization potentials greater than that of He$^{+}$(54.4 eV), e.g. N$^{+4}$ and Ne$^{+4}$, were often under-predicted. Among the explanations suggested for these discrepancies were (selectively) enhanced elemental abundances and contributions from shock heated gas. Interestingly, the NLR lines have widths of several 100 km s$^{-1}$, well in excess of the thermal broadening. If this is due to micro-turbulence, and the turbulence dissipates within the emission-line gas, the gas can be heated in excess of that due to photoionization. We show that the combined effects of turbulence and dissipative heating can strongly enhance N V $\lambda$1240 (relative to He II $\lambda$1640), while the heating alone can boost the strength of [Ne V] $\lambda$3426. We suggest that this effect is present in the NLR, particularly within $\sim$ 100 pc of the central engine. Finally, since micro-turbulence would make clouds robust against instabilities generated during acceleration, it is not likely to be a coincidence that the radially outflowing emission-line gas is turbulent.Comment: 29 oages, including 10 figures. Accepted for publication in the Astrophysical Journa

Structural and functional stabilization of protein entities

XI Reunião Regional Nordeste da SBBq | 4th International Symposium in Biochemistry of Macromolecules and BiotechnologyStabilization of protein and protein-like molecules translates into preservation of both structure and functionality during storage and/or targeting, and such stabilization is mostly attained through establishment of a thermodynamic equilibrium with the (micro)environment. The basic thermodynamic principles that govern protein structural transitions and the interactions of the protein and/or peptide molecule with its (micro)environment will, therefore, be tackled. Protein stabilization is based upon dampening the molecular motions and, therefore, eliminating conformational transitions while the molecule is still in the native 3D (folded) state. The 3D structure of a protein molecule depends mostly on two types of interactions: intramolecular interactions between aminoacid moieties and intermolecular interactions with solute and/or solvent molecules present in its microenvironment. Stabilizing a biomolecule (aiming at preserving its function) involves dampening its molecular motions, and this can be achieved by reducing the chemical activity of the water present in its microenvironment, thus stabilizing both its structure and functionality. Recently, the simultaneous entrapment-stabilization of proteins and enzymes based on nanoencapsulation in a nanoemulsion (W/O/W) matrix with an hydrophilic core has started to gain momentum. Similarly to the stabilization mechanism of osmolytes, in nanoencapsulation the water activity is altered thus affecting the molecular motions of the proteins. Highlights will also be given to structural and functional stabilization of protein entities (viz. enzymes, (macro)peptides, (recombinant) proteins, and bacteriophages) by chemical methodologies. Modification of the biomolecules microenvironment via multipoint covalent attachment onto a solid surface followed by hydrophylic polymer coimmobilization, are some of the (latest) strategies that will be discussed.info:eu-repo/semantics/publishedVersio

Modulating spin transfer torque switching dynamics with two orthogonal spin-polarizers by varying the cell aspect ratio

We study in-plane magnetic tunnel junctions with additional perpendicular polarizer for subnanosecond-current-induced switching memories. The spin-transfer-torque switching dynamics was studied as a function of the cell aspect ratio both experimentally and by numerical simulations using the macrospin model. We show that the anisotropy field plays a significant role in the dynamics, along with the relative amplitude of the two spin-torque contributions. This was confirmed by micromagnetic simulations. Real-time measurements of the reversal were performed with samples of low and high aspect ratio. For low aspect ratios, a precessional motion of the magnetization was observed and the effect of temperature on the precession coherence was studied. For high aspect ratios, we observed magnetization reversals in less than 1 ns for high enough current densities, the final state being controlled by the current direction in the magnetic tunnel junction cell.Comment: 6 pages, 7 figure

Dense Molecular Gas Associated with the Circumnuclear Star Forming Ring in the Barred Spiral Galaxy NGC 6951

We present high resolution (3" - 5") observations of CO(1-0) and HCN(1-0) emission from the circumnuclear star forming ring in the barred spiral galaxy NGC 6951, a host of a type-2 Seyfert, using the Nobeyama Millimeter Array and 45 m telescope. We find that most of the HCN emission is associated with the circumnuclear ring, where vigorous star formation occurs. The HCN to CO integrated intensity ratio is also enhanced in the star forming ring; the peak value of HCN/CO ratio is 0.18, which is comparable to the ratio in the starbursts NGC 253 and M82. The formation mechanism of dense molecular gas has been investigated. We find that the shocks along the orbit crowding do not promote the formation of the dense molecular gas effectively but enhance the presence of low density GMCs. Instead, gravitational instabilities of the gas can account for the dense molecular gas formation. The HCN/CO ratio toward the Seyfert nucleus of NGC 6951 is a rather normal value (0.086), in contrast with other Seyferts NGC 1068 and M51 where extremely high HCN/CO value of ~ 0.5 have been reported.Comment: 33 pages, 17 figures, to appear in the Astrophysical Journa

A 4-D dataset for validation of crystal growth in a complex three-phase material, ice cream

Four dimensional (4D, or 3D plus time) X-ray tomographic imaging of phase changes in materials is quickly becoming an accepted tool for quantifying the development of microstructures to both inform and validate models. However, most of the systems studied have been relatively simple binary compositions with only two phases. In this study we present a quantitative dataset of the phase evolution in a complex three-phase material, ice cream. The microstructure of ice cream is an important parameter in terms of sensorial perception, and therefore quantification and modelling of the evolution of the microstructure with time and temperature is key to understanding its fabrication and storage. The microstructure consists of three phases, air cells, ice crystals, and unfrozen matrix. We perform in situ synchrotron X-ray imaging of ice cream samples using in-line phase contrast tomography, housed within a purpose built cold-stage (-40 to +20oC) with finely controlled variation in specimen temperature. The size and distribution of ice crystals and air cells during programmed temperature cycling are determined using 3D quantification. The microstructural evolution of three-phase materials has many other important applications ranging from biological to structural and functional material, hence this dataset can act as a validation case for numerical investigations on faceted and non-faceted crystal growth in a range of materials

The local electronic structure of alpha-Li3N

New theoretical and experimental investigation of the occupied and unoccupied local electronic density of states (DOS) are reported for alpha-Li3N. Band structure and density functional theory calculations confirm the absence of covalent bonding character. However, real-space full-multiple-scattering (RSFMS) calculations of the occupied local DOS finds less extreme nominal valences than have previously been proposed. Nonresonant inelastic x-ray scattering (NRIXS), RSFMS calculations, and calculations based on the Bethe-Salpeter equation are used to characterize the unoccupied electronic final states local to both the Li and N sites. There is good agreement between experiment and theory. Throughout the Li 1s near-edge region, both experiment and theory find strong similarities in the s- and p-type components of the unoccupied local final density of states projected onto an orbital angular momentum basis (l-DOS). An unexpected, significant correspondence exists between the near-edge spectra for the Li 1s and N 1s initial states. We argue that both spectra are sampling essentially the same final density of states due to the combination of long core-hole lifetimes, long photoelectron lifetimes, and the fact that orbital angular momentum is the same for all relevant initial states. Such considerations may be generically applicable for low atomic number compounds.Comment: 34 pages, 7 figures, 1 tabl

Accelerating the adoption of Industry 4.0 supporting technologies in manufacturing engineering courses

[EN] Universities are one of the fundamental actors to guarantee the dissemination of knowledge and the development of competences related to the Industry of the Future (IoF) or Industry 4.0. Computer Aided (CAX) and Product Lifecycle Management (PLM) technologies are key part in the IoF. With this aim, it was launch a project focused on Manufacturing and partially funded by La Fondation Dassault Systèmes. This communication presents a review on CAX-PLM training, four initiatives already in place in universities participating in the project, the project scope, the approach to integrate with the industrial context, the working method to consider different competence profiles and the development framework.The authors express their gratitude to the other project colleagues and to La Fondation Dassault Systèmes for its funding support.Ríos, J.; Mas, F.; Marcos, M.; Vila, C.; Ugarte, D.; Chevrot, T. (2017). Accelerating the adoption of Industry 4.0 supporting technologies in manufacturing engineering courses. MATERIALS SCIENCE FORUM. 903:100-111. https://doi.org/10.4028/www.scientific.net/MSF.903.100S10011190