Anisotropic Local Stress and Particle Hopping in a Deeply Supercooled Liquid

The origin of the microscopic motions that lead to stress relaxation in deeply supercooled liquid remains unclear. We show that in such a liquid the stress relaxation is locally anisotropic which can serve as the driving force for the hopping of the system on its free energy surface. However, not all hopping are equally effective in relaxing the local stress, suggesting that diffusion can decouple from viscosity even at local level. On the other hand, orientational relaxation is found to be always coupled to stress relaxation.Comment: 4 pages, 3 figure

Failure of steel tanks during their construction: experiments and computational modeling

La construcción de tanques de acero destinados al almacenamiento de petróleo plantea un estado de solicitaciones frente a la acción de viento que no está contemplado en las normativas. En la Patagonia Argentina, como en otros lugares reportados en la bibliografía, se han registrado casos de colapso de este tipo de estructuras durante la etapa constructiva a moderadas velocidades de viento. Estudios numéricos anteriores condujeron a determinar como factor desencadenante del mecanismo de colapso, la falta de integridad estructural por las irregularidades en la continuidad del apoyo en el sentido circunferencial. Un mayor conocimiento del comportamiento fluido-dinámico del viento permite ajustar las acciones actuantes usadas en el abordaje del estudio numérico. Este trabajo completa el análisis de tanques no anclados que colapsaron por acción del viento durante su etapa constructiva evaluando el patrón del flujo interior en los tanques mediante ensayos en túnel de viento, incluyendo estos resultados en el estudio numérico. La estructura se modela por elementos finitos mediante un código de propósitos generales, evaluando la inestabilidad del equilibrio mediante un análisis de bifurcación lineal (LBA) y análisis no lineal geométrico con imperfecciones (GNIA). Los ensayos permitieron determinar la formación de un vórtice interior que produce una depresión mayor que el de la estela a sotavento del tanque.During the construction of steel storage oil tanks, a state of stresses under wind loads is induced which is not covered by the regulations. Cases of collapse of such structures during their construction occurred in Patagonia Argentina and elsewhere under moderate wind speeds, as reported in the literature. Previous numerical studies concentrated on the identification of the collapse mechanism, which was related to the loss of structural integrity due to discontinuity of the support in the circumferential direction. An increased knowledge of the fluid dynamic behavior under wind allows obtaining an improved input used in the subsequent numerical study. This paper provides new insight into the wind behavior of unanchored tanks that collapsed during their construction by wind tunnel tests to evaluate the flow pattern inside the tanks, which is an input for the subsequent numerical study. The structure is modeled using a general purpose finite element code, in which instability is evaluated by Linear Bifurcation Analysis (LBA) and by Geometrically Nonlinear Analysis with Imperfections (GNIA). Tests allowed identifying that an inner vortex is induced which produces a greater depression than the downwind wake in the leeward region of the tank.Fil: Jaca, Rossana Claudia. Universidad Nacional del Comahue; ArgentinaFil: Cicerone, Esteban. Universidad Nacional del Comahue; ArgentinaFil: Hernandez, Facundo C.. Universidad Nacional del Comahue; ArgentinaFil: Lassig, Jorge Luis. Universidad Nacional del Comahue; ArgentinaFil: Godoy, Luis Augusto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Estudios Avanzados En Ingeniería y Tecnología. Universidad Nacional de Córdoba. Facultad de Cs.exactas Físicas y Naturales. Instituto de Estudios Avanzados En Ingeniería y Tecnología; Argentin

Heterogeneous Diffusion in Highly Supercooled Liquids

The diffusivity of tagged particles is demonstrated to be very heterogeneous on time scales comparable to or shorter than the $\alpha$ relaxation time $\tau_{\alpha}$ ($\cong$ the stress relaxation time) in a highly supercooled liquid via 3D molecular dynamics simulation. The particle motions in the relatively active regions dominantly contribute to the mean square displacement, giving rise to a diffusion constant systematically larger than the Einstein-Stokes value. The van Hove self-correlation function $G_s(r,t)$ is shown to have a long distance tail which can be scaled in terms of $r/t^{1/2}$ for t \ls 3\tau_{\alpha}. Its presence indicates heterogeneous diffusion in the active regions. However, the diffusion process eventually becomes homogeneous on time scales longer than the life time of the heterogeneity structure ($\sim 3 \tau_{\alpha}$).Comment: 4 pages, 5 figure

Structural Relaxation, Self Diffusion and Kinetic Heterogeneity in the Two Dimensional Lattice Coulomb Gas

We present Monte Carlo simulation results on the equilibrium relaxation dynamics in the two dimensional lattice Coulomb gas, where finite fraction $f$ of the lattice sites are occupied by positive charges. In the case of high order rational values of $f$ close to the irrational number $1-g$ ($g\equiv(\sqrt{5} -1)/2$ is the golden mean), we find that the system exhibits, for wide range of temperatures above the first-order transition, a glassy behavior resembling the primary relaxation of supercooled liquids. Single particle diffusion and structural relaxation show that there exists a breakdown of proportionality between the time scale of diffusion and that of structural relaxation analogous to the violation of the Stokes-Einstein relation in supercooled liquids. Suitably defined dynamic cooperativity is calculated to exhibit the characteristic nature of dynamic heterogeneity present in the system.Comment: 12 pages, 20 figure

Dynamical heterogeneities in a supercooled Lennard-Jones liquid

We present the results of a large scale molecular dynamics computer simulation study in which we investigate whether a supercooled Lennard-Jones liquid exhibits dynamical heterogeneities. We evaluate the non-Gaussian parameter for the self part of the van Hove correlation function and use it to identify ``mobile'' particles. We find that these particles form clusters whose size grows with decreasing temperature. We also find that the relaxation time of the mobile particles is significantly shorter than that of the bulk, and that this difference increases with decreasing temperature.Comment: 8 pages of RevTex, 4 ps figure

Photoelectron Flux Build-Up in the Plasmasphere

Processes which confine photoelectrons to the plasmasphere (e.g., collisional backscattering from the thermosphere and magnetic trapping due to pitch angle redistribution through Coulomb collisions in the plasmasphere) tend to increase the steady state photoelectron flux in the plasmasphere above the amplitude level that would otherwise have been attained. Theoretical calculations are presented of steady state photoelectron fluxes in the plasmasphere, for specified atmospheric and ionospheric conditions. (Observational plasma line intensity data for these conditions exist and will be compared elsewhere.) General features of the angular distribution are presented and compared with observations. The transparency of the plasmasphere and the backscattering properties of the thermosphere are investigated. The buildup effect due to collisional backscatter alone is calculated, and the combined buildup effect of pitch angle diffusion and backscatter is estimated. It is found that the inclusion of these effects increases the steady state photoelectron flux amplitude in the plasmasphere by about 50% over the value obtained when the buildup effects are neglected. The calculated steady state photoelectron fluxes in the plasmasphere are in good agreement with the available observations

Virilizing Leydig-Sertoli cell ovarian tumor associated with endometrioid carcinoma of the endometrium in a postmenopausal patient: Case report and general considerations

Sertoli-Leydig cell tumors (SLCTs) are rare tumors mostly occurring in young women. Here we report an unusual case of a SLCT with simultaneous occurrence of endometrioid adenocarcinoma of the endometrium in a woman in menopause

Growing spatial correlations of particle displacements in a simulated liquid on cooling toward the glass transition

We define a correlation function that quantifies the spatial correlation of single-particle displacements in liquids and amorphous materials. We show for an equilibrium liquid that this function is related to fluctuations in a bulk dynamical variable. We evaluate this function using computer simulations of an equilibrium glass-forming liquid, and show that long range spatial correlations of displacements emerge and grow on cooling toward the mode coupling critical temperature

String-like Clusters and Cooperative Motion in a Model Glass-Forming Liquid

A large-scale molecular dynamics simulation is performed on a glass-forming Lennard-Jones mixture to determine the nature of dynamical heterogeneities which arise in this model fragile liquid. We observe that the most mobile particles exhibit a cooperative motion in the form of string-like paths (``strings'') whose mean length and radius of gyration increase as the liquid is cooled. The length distribution of the strings is found to be similar to that expected for the equilibrium polymerization of linear polymer chains.Comment: 6 pages of RevTex, 6 postscript figures, uses epsf.st