1,578 research outputs found
From bare interactions, low--energy constants and unitary gas to nuclear density functionals without free parameters: application to neutron matter
We further progress along the line of Ref. [Phys. Rev. {\bf A 94}, 043614
(2016)] where a functional for Fermi systems with anomalously large -wave
scattering length was proposed that has no free parameters. The
functional is designed to correctly reproduce the unitary limit in Fermi gases
together with the leading-order contributions in the s- and p-wave channels at
low density. The functional is shown to be predictive up to densities
fm that is much higher densities compared to the Lee-Yang
functional, valid for fm. The form of the functional
retained in this work is further motivated. It is shown that the new functional
corresponds to an expansion of the energy in and to all
orders, where is the effective range and is the Fermi momentum. One
conclusion from the present work is that, except in the extremely low--density
regime, nuclear systems can be treated perturbatively in with
respect to the unitary limit. Starting from the functional, we introduce
density--dependent scales and show that scales associated to the bare
interaction are strongly renormalized by medium effects. As a consequence, some
of the scales at play around saturation are dominated by the unitary gas
properties and not directly to low-energy constants. For instance, we show that
the scale in the s-wave channel around saturation is proportional to the
so-called Bertsch parameter and becomes independent of . We also
point out that these scales are of the same order of magnitude than those
empirically obtained in the Skyrme energy density functional. We finally
propose a slight modification of the functional such that it becomes accurate
up to the saturation density fm
Magnetic and electrical properties of dhcp NpPd3 and U(1-x)Np(x)Pd3
We have made an extensive study of the magnetic and electrical properties of
double-hexagonal closepacked NpPd3 and a range of U(1-x)Np(x)Pd3 compounds with
x=0.01, 0.02, 0.05, and 0.50 using magnetization, magnetic susceptibility,
electrical resistivity, and heat capacity measurements on polycrystalline
samples, performed in the temperature range 2-300 K and in magnetic fields up
to 9 T. Two transitions are observed in NpPd3 at T=10 and 30 K. Dilute Np
samples (x<0.05) exhibit quadrupolar transitions, with the transition
temperatures reduced from those of pure UPd3.Comment: 10 pages, 18 figure
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Effects on Calculated Half-Widths and Shifts from the Line Coupling for Asymmetric-Top Molecules
The refinement of the Robert-Bonamy formalism by considering the line coupling for linear molecules developed in our previous studies [Q. Ma, C. Boulet, and R. H. Tipping, J. Chem. Phys. 139, 034305 (2013); 140, 104304 (2014)] have been extended to asymmetric-top molecules. For H2O immersed in N2 bath, the line coupling selection rules applicable for the pure rotational band to determine whether two specified lines are coupled or not are established. Meanwhile, because the coupling strengths are determined by relative importance of off-diagonal matrix elements versus diagonal elements of the operator -iS1 -S2, quantitative tools are developed with which one is able to remove weakly coupled lines from consideration. By applying these tools, we have found that within reasonable tolerances, most of the H2O lines in the pure rotational band are not coupled. This reflects the fact that differences of energy levels of the H2O states are pretty large. But, there are several dozen strongly coupled lines and they can be categorized into different groups such that the line couplings occur only within the same groups. In practice, to identify those strongly coupled lines and to confine them into sub-linespaces are crucial steps in considering the line coupling. We have calculated half-widths and shifts for some groups, including the line coupling. Based on these calculations, one can conclude that for most of the H2O lines, it is unnecessary to consider the line coupling. However, for several dozens of lines, effects on the calculated half-widths from the line coupling are small, but remain noticeable and reductions of calculated half-widths due to including the line coupling could reach to 5%. Meanwhile, effects on the calculated shifts are very significant and variations of calculated shifts could be as large as 25%
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Relaxation Matrix for Symmetric Tops with Inversion Symmetry: Line Coupling and Line Mixing Effects on NH3 Lines in the nu4 Band
Line shape parameters including the half-widths and the off-diagonal elements of the relaxation matrix have been calculated for self-broadened NH3 lines in the perpendicular nu4 band. As in the pure rotational and the parallel nu1 bands, the small inversion splitting in this band causes a complete failure of the isolated line approximation. As a result, one has to use formalisms not relying on this approximation. However, due to differences between parallel and perpendicular bands of NH3, the applicability of the formalism used in our previous studies of the nu1 band and other parallel bands must be carefully verified. We have found that, as long as potential models only contain components with K1 = K2 = 0, whose matrix elements require the selection rule ∆k = 0, the formalism is applicable for the nu4 band with some minor adjustments. Based on both theoretical considerations and results from numerical calculations, the non-diagonality of the relaxation matrices in all the PP, RP, PQ, RQ, PR, and RR branches is discussed. Theoretically calculated self-broadened half-widths are compared with measurements and the values listed in HITRAN 2012. With respect to line coupling effects, we have compared our calculated intra-doublet off-diagonal elements of the relaxation matrix with reliable measurements carried out in the PP branch where the spectral environment is favorable. The agreement is rather good since our results do well reproduce the observed k and j dependences of these elements, thus validating our formalism
Theoretical Studies of Spectroscopic Line Mixing in Remote Sensing Applications
The phenomenon of collisional transfer of intensity due to line mixing has an increasing importance for atmospheric monitoring. From a theoretical point of view, all relevant information about the collisional processes is contained in the relaxation matrix where the diagonal elements give half-widths and shifts, and the off-diagonal elements correspond to line interferences. For simple systems such as those consisting of diatom-atom or diatom-diatom, accurate fully quantum calculations based on interaction potentials are feasible. However, fully quantum calculations become unrealistic for more complex systems. On the other hand, the semi-classical Robert-Bonamy (RB) formalism, which has been widely used to calculate half-widths and shifts for decades, fails in calculating the off-diagonal matrix elements. As a result, in order to simulate atmospheric spectra where the effects from line mixing are important, semi-empirical fitting or scaling laws such as the ECS (Energy-Corrected Sudden) and IOS (Infinite-Order Sudden) models are commonly used. Recently, while scrutinizing the development of the RB formalism, we have found that these authors applied the isolated line approximation in their evaluating matrix elements of the Liouville scattering operator given in exponential form. Since the criterion of this assumption is so stringent, it is not valid for many systems of interest in atmospheric applications. Furthermore, it is this assumption that blocks the possibility to calculate the whole relaxation matrix at all. By eliminating this unjustified application, and accurately evaluating matrix elements of the exponential operators, we have developed a more capable formalism. With this new formalism, we are now able not only to reduce uncertainties for calculated half-widths and shifts, but also to remove a once insurmountable obstacle to calculate the whole relaxation matrix. This implies that we can address the line mixing with the semi-classical theory based on interaction potentials between molecular absorber and molecular perturber. We have applied this formalism to address the line mixing for Raman and infrared spectra of molecules such as N2, C2H2, CO2, NH3, and H2O. By carrying out rigorous calculations, our calculated relaxation matrices are in good agreement with both experimental data and results derived from the ECS model
A comparison of physician emigration from Africa to the United States of America between 2005 and 2015
BACKGROUND: Migration of health professionals has been a cause for global concern, in particular migration from African countries with a high disease burden and already fragile health systems. An estimated one fifth of African-born physicians are working in high-income countries. Lack of good data makes it difficult to determine what constitutes "African" physicians, as most studies do not distinguish between their country of citizenship and country of training. Thus, the real extent of migration from African countries to the United States (US) remains unclear. This paper quantifies where African migrant physicians come from, where they were educated, and how these trends have changed over time. METHODS: We combined data from the Educational Commission for Foreign Medical Graduates with the 2005 and 2015 American Medical Association Physician Masterfiles. Using a repeated cross-sectional study design, we reviewed the available data, including medical school attended, country of medical school, and citizenship when entering medical school. RESULTS: The outflow of African-educated physicians to the US has increased over the past 10 years, from 10 684 in 2005 to 13 584 in 2015 (27.1% increase). This represents 5.9% of all international medical graduates in the US workforce in 2015. The number of African-educated physicians who graduated from medical schools in sub-Saharan countries was 2014 in 2005 and 8150 in 2015 (304.6% increase). We found four distinct categorizations of African-trained physicians migrating to the US: (1) citizens from an African country who attended medical school in their own country (86.2%, n = 11,697); (2) citizens from an African country who attended medical school in another African country (2.3%, n = 317); (3) US citizens who attended medical school in an African country (4.0%, n = 537); (4) citizens from a country outside Africa, and other than the United States, who attended medical school in an African country (7.5%, n = 1013). Overall, six schools in Africa provided half of all African-educated physicians. CONCLUSIONS: The number of African-educated physicians in the US has increased over the past 10 years. We have distinguished four migration patterns, based on citizenship and country of medical school. The majority of African graduates come to the US from relatively few countries, and from a limited number of medical schools. A proportion are not citizens of the country where they attended medical school, highlighting the internationalization of medical education
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The j and k dependencies of the line coupling and line mixing effects: Theoretical studies of the relaxation matrices of N₂-broadened CH₃D
Line coupling and line mixing effects in parallel and perpendicular bands of CH₃D perturbed by N₂ have been studied. The work focuses on exhibiting the j and k dependencies of these two processes. The calculations were based on a previously reported anisotropic intermolecular potential including both the long-range multipole, induction, and dispersion forces and a short-range atom-atom model. It is shown that components with L₁ = 3 of the atom-atom model are dominant contributions to the diffusion operator. As a consequence, in comparison with other molecular systems such as the CH₃Cl-N₂ and CH₃ I-N₂ , theoretically predicted line coupling and line mixing effects exhibit completely new j and k dependencies. In general, the theoretically calculated halfwidths and intra-doublets’ off-diagonal elements of the relaxation matrix are in reasonable agreement with measurements
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The influence of line mixing on the j and k dependencies of halfwidths and temperature exponents in N2-broadening coefficients of CH3F spectral lines
The N2-broadening halfwidths of CH3F in the n5 and n6 perpendicular bands have been calculated, along with their temperature exponents. These calculations utilize a modified and refined version of the Robert-Bonamy formalism, developed by the current authors within a semi-classical line shape framework. Extensive comparisons between the predicted halfwidths from the model and experimental measurements at 296 K and 183 K are presented. Our latest model accurately predicts the dependencies of the halfwidths on both the j and k quantum numbers. Furthermore, by extending our calculations to two additional temperatures, namely 240 K and 350 K, the temperature exponent N is determined for various sub-branches. The dependencies of N on j and k are analyzed, and theoretical explanations are provided to elucidate the predicted behaviors of N.
Keywords: Methyl fluoride, N2 broadened halfwidths of CH3F, line coupling and line mixing, temperature exponents, semi-classical line shape theor
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