GPS radio occultation with CHAMP and SAC-C: global monitoring of thermal tropopause parameters

In this study the global lapse-rate tropopause (LRT) pressure, temperature, potential temperature, and sharpness are discussed based on Global Positioning System (GPS) radio occultations (RO) from the German CHAMP (CHAllenging Minisatellite Payload) and the U.S.-Argentinian SAC-C (Satelite de Aplicaciones Cientificas-C) satellite missions. Results with respect to seasonal variations are compared with operational radiosonde data and ECMWF (European Centre for Medium-Range Weather Forecast) operational analyses. Results on the tropical quasi-biennial oscillation (QBO) are updated from an earlier study. CHAMP RO data are available continuously since May 2001 with on average 150 high resolution temperature profiles per day. SAC-C data are available for several periods in 2001 and 2002. In this study temperature data from CHAMP for the period May 2001-December 2004 and SAC-C data from August 2001-October 2001 and March 2002-November 2002 were used, respectively. The bias between GPS RO temperature profiles and radiosonde data was found to be less than 1.5K between 300 and 10hPa with a standard deviation of 2-3K. Between 200-20hPa the bias is even less than 0.5K (2K standard deviation). The mean deviations based on 167699 comparisons between CHAMP/SAC-C and ECMWF LRT parameters are (-2.1±37.1)hPa for pressure and (0.1±4.2)K for temperature. Comparisons of LRT pressure and temperature between CHAMP and nearby radiosondes (13230) resulted in (5.8±19.8)hPa and (-0.1±3.3)K, respectively. The comparisons between CHAMP/SAC-C and ECMWF show on average the largest differences in the vicinity of the jet streams with up to 700m in LRT altitude and 3K in LRT temperature, respectively. The CHAMP mission generates the first long-term RO data set. Other satellite missions will follow (GRACE, COSMIC, MetOp, TerraSAR-X, EQUARS) generating together some thousand temperature profiles daily

GPS radio occultation with CHAMP: monitoring of climate change parameters

International audienceThe Global Positioning System (GPS) radio occultation (RO) technique offers a valuable new data source for global and continuous monitoring of the Earth's atmosphere. Refractivity, temperature and water vapor profiles with high accuracy and vertical resolution can be derived from this method. The GPS RO technique requires no calibration, is not affected by clouds, aerosols or precipitation, and the occultations are almost uniformly distributed over the globe. In this paper the potential of GPS RO for monitoring of the temperature is demonstrated exemplarily for the tropical upper troposphere and lower stratosphere (UTLS) region using GPS RO data from the German CHAMP (CHAllenging Minisatellite Payload) satellite mission. In addition, results of a 1DVAR retrieval scheme to derive tropospheric water vapor profiles using ECMWF data as background will be discussed. CHAMP RO data are available since 2001 with up to 200 high resolution temperature profiles per day. The temperature bias between CHAMP temperature profiles and radiosonde data as well as ECMWF analyses is less than 0.5 K between 300?30 hPa. The CHAMP RO experiment generates the first long-term RO data set. Other satellite missions will follow (GRACE, TerraSAR-X, COSMIC, METOP) generating some thousand profiles of atmospheric parameters daily

Temperature dependence of the primary electron transfer in photosynthetic reaction centers from Rhodobacter sphaeroides

The primary electron transfer (ET) in reaction centers (RC) of Rhodobacter sphaeroides is investigated as a function of temperature with femtosecond time resolution. For temperatures from 300 to 25 K the ET to the bacteriopheophytin is characterized by a biphasic time dependence. The two time constants of τ1=3.5±0.4 ps and τ2=1.2±0.3 ps at T=300 K decrease continously with temperature to values of τ1=1.4±0.3 ps and τ2=0.3±0.15 ps at 25 K. The experimental results indicate that the ET is not thermally activated and that the same ET mechanisms are active at room and low temperatures. All observations are readily rationalized by a two-step ET model with the monomeric bacteriochlorophyll as a real electron carrier

Dissolved noble gases and stable isotopes as tracers of preferential fluid flow along faults in the Lower Rhine Embayment, Germany

Groundwater in shallow unconsolidated sedimentary aquifers close to the Bornheim fault in the Lower Rhine Embayment (LRE), Germany, has relatively low δ2H and δ18O values in comparison to regional modern groundwater recharge, and 4He concentrations up to 1.7 × 10−4 cm3 (STP) g–1 ± 2.2 % which is approximately four orders of magnitude higher than expected due to solubility equilibrium with the atmosphere. Groundwater age dating based on estimated in situ production and terrigenic flux of helium provides a groundwater residence time of ∼107 years. Although fluid exchange between the deep basal aquifer system and the upper aquifer layers is generally impeded by confining clay layers and lignite, this study’s geochemical data suggest, for the first time, that deep circulating fluids penetrate shallow aquifers in the locality of fault zones, implying  that sub-vertical fluid flow occurs along faults in the LRE. However, large hydraulic-head gradients observed across many faults suggest that they act as barriers to lateral groundwater flow. Therefore, the geochemical data reported here also substantiate a conduit-barrier model of fault-zone hydrogeology in unconsolidated sedimentary deposits, as well as corroborating the concept that faults in unconsolidated aquifer systems can act as loci for hydraulic connectivity between deep and shallow aquifers. The implications of fluid flow along faults in sedimentary basins worldwide are far reaching and of particular concern for carbon capture and storage (CCS) programmes, impacts of deep shale gas recovery for shallow groundwater aquifers, and nuclear waste storage sites where fault zones could act as potential leakage pathways for hazardous fluids