813 research outputs found
CO Infrared Phonon Modes in Interstellar Ice Mixtures
CO ice is an important reservoir of carbon and oxygen in star and planet
forming regions. Together with water and CO, CO sets the physical and
chemical characteristics of interstellar icy grain mantles, including
desorption and diffusion energies for other ice constituents. A detailed
understanding of CO ice spectroscopy is a prerequisite to characterize
CO interactions with other volatiles both in interstellar ices and in
laboratory experiments of interstellar ice analogs. We report laboratory
spectra of the CO longitudinal optical (LO) phonon mode in pure CO ice
and in CO ice mixtures with HO, CO, O components. We show that the
LO phonon mode position is sensitive to the mixing ratio of various ice
components of astronomical interest. In the era of JWST, this characteristic
could be used to constrain interstellar ice compositions and morphologies. More
immediately, LO phonon mode spectroscopy provides a sensitive probe of ice
mixing in the laboratory and should thus enable diffusion measurements with
higher precision than has been previously possible
CO diffusion and desorption kinetics in CO ices
Diffusion of species in icy dust grain mantles is a fundamental process that
shapes the chemistry of interstellar regions; yet measurements of diffusion in
interstellar ice analogs are scarce. Here we present measurements of CO
diffusion into CO ice at low temperatures (T=11--23~K) using CO
longitudinal optical (LO) phonon modes to monitor the level of mixing of
initially layered ices. We model the diffusion kinetics using Fick's second law
and find the temperature dependent diffusion coefficients are well fit by an
Arrhenius equation giving a diffusion barrier of 300 40 K. The low
barrier along with the diffusion kinetics through isotopically labeled layers
suggest that CO diffuses through CO along pore surfaces rather than through
bulk diffusion. In complementary experiments, we measure the desorption energy
of CO from CO ices deposited at 11-50 K by temperature-programmed
desorption (TPD) and find that the desorption barrier ranges from 1240 90
K to 1410 70 K depending on the CO deposition temperature and
resultant ice porosity. The measured CO-CO desorption barriers demonstrate
that CO binds equally well to CO and HO ices when both are compact. The
CO-CO diffusion-desorption barrier ratio ranges from 0.21-0.24 dependent on
the binding environment during diffusion. The diffusion-desorption ratio is
consistent with the above hypothesis that the observed diffusion is a surface
process and adds to previous experimental evidence on diffusion in water ice
that suggests surface diffusion is important to the mobility of molecules
within interstellar ices
-Martin boundary of killed random walks in the quadrant
We compute the -Martin boundary of two-dimensional small steps random
walks killed at the boundary of the quarter plane. We further provide explicit
expressions for the (generating functions of the) discrete -harmonic
functions. Our approach is uniform in , and shows that there are three
regimes for the Martin boundary.Comment: 18 pages, 2 figures, to appear in S\'eminaire de Probabilit\'e
CO ice photodesorption: A wavelength-dependent study
UV-induced photodesorption of ice is a non-thermal evaporation process that
can explain the presence of cold molecular gas in a range of interstellar
regions. Information on the average UV photodesorption yield of astrophysically
important ices exists for broadband UV lamp experiments. UV fields around
low-mass pre-main sequence stars, around shocks and in many other astrophysical
environments are however often dominated by discrete atomic and molecular
emission lines. It is therefore crucial to consider the wavelength dependence
of photodesorption yields and mechanisms. In this work, for the first time, the
wavelength-dependent photodesorption of pure CO ice is explored between 90 and
170 nm. The experiments are performed under ultra high vacuum conditions using
tunable synchrotron radiation. Ice photodesorption is simultaneously probed by
infrared absorption spectroscopy in reflection mode of the ice and by
quadrupole mass spectrometry of the gas phase. The experimental results for CO
reveal a strong wavelength dependence directly linked to the vibronic
transition strengths of CO ice, implying that photodesorption is induced by
electronic transition (DIET). The observed dependence on the ice absorption
spectra implies relatively low photodesorption yields at 121.6 nm (Ly-alpha),
where CO barely absorbs, compared to the high yields found at wavelengths
coinciding with transitions into the first electronic state of CO (singulet Pi
at 150 nm); the CO photodesorption rates depend strongly on the UV profiles
encountered in different star formation environments.Comment: 5 pages, 2 figures, published in ApJ
Indirect ultraviolet photodesorption from CO:N2 binary ices - an efficient grain-gas process
UV ice photodesorption is an important non-thermal desorption pathway in many
interstellar environments that has been invoked to explain observations of cold
molecules in disks, clouds and cloud cores. Systematic laboratory studies of
the photodesorption rates, between 7 and 14 eV, from CO:N2 binary ices, have
been performed at the DESIRS vacuum UV beamline of the synchrotron facility
SOLEIL. The photodesorption spectral analysis demonstrates that the
photodesorption process is indirect, i.e. the desorption is induced by a photon
absorption in sub-surface molecular layers, while only surface molecules are
actually desorbing. The photodesorption spectra of CO and N2 in binary ices
therefore depend on the absorption spectra of the dominant species in the
subsurface ice layer, which implies that the photodesorption efficiency and
energy dependence are dramatically different for mixed and layered ices
compared to pure ices. In particular, a thin (1-2 ML) N2 ice layer on top of CO
will effectively quench CO photodesorption, while enhancing N2 photodesorption
by a factors of a few (compared to the pure ices) when the ice is exposed to a
typical dark cloud UV field, which may help to explain the different
distributions of CO and N2H+ in molecular cloud cores. This indirect
photodesorption mechanism may also explain observations of small amounts of
complex organics in cold interstellar environments.Comment: 21 pages 5 figure
On the dynamical behavior of the ABC model
We consider the ABC dynamics, with equal density of the three species, on the
discrete ring with sites. In this case, the process is reversible with
respect to a Gibbs measure with a mean field interaction that undergoes a
second order phase transition. We analyze the relaxation time of the dynamics
and show that at high temperature it grows at most as while it grows at
least as at low temperature
The Role of Oxidation Compounds in Biofilm Growth on Polyethylene Geomembrane Barriers Used in Landfill
In a model study, polyethylene was preoxidized and incubated for a period of 7 months at 40°C in two different municipal solid waste leachates. During the postexperimental analyses, specific attention was paid to the carbonyl species and carboxylic acid depletion during the environmental exposure because it is well known that carboxylic acids are believed to be a potential substrate for the development of microorganisms. The results showed that the carbonyl as well as the carboxylic acid depletion observed follows first-order kinetics. The biofilm formation was characterized using a suite of analytical techniques, and its formation was compared with the carboxylic acid and carbonyl depletion profil
Entrepreneurial intention studies: A hybrid bibliometric method to identify new directions for theory and research
Fragmentation is the main obstacle to scientific progress on entrepreneurial intention. To address this issue, we systematise the current literature with a hybrid bibliometric method that combines co-citation and bibliographic coupling analysis for the first time in entrepreneurial intention studies to show the field's knowledge base and research fronts and to examine how divergent perspectives have challenged the core knowledge of the field. We highlight three recurring dimensions of entrepreneurial intention studies: (1) personal factors, (2) social factors and (3) investigational settings. In addition to introducing new constructs, divergent perspectives have emphasised the interplay between these components and challenged the mechanisms connecting them. Based on these findings, we extend previous classifications in the literature by providing a framework that integrates divergent perspectives with the field's knowledge base, helping establish future research avenues and improving the theorising process of entrepreneurial intention
Three osculating walkers
We consider three directed walkers on the square lattice, which move
simultaneously at each tick of a clock and never cross. Their trajectories form
a non-crossing configuration of walks. This configuration is said to be
osculating if the walkers never share an edge, and vicious (or:
non-intersecting) if they never meet. We give a closed form expression for the
generating function of osculating configurations starting from prescribed
points. This generating function turns out to be algebraic. We also relate the
enumeration of osculating configurations with prescribed starting and ending
points to the (better understood) enumeration of non-intersecting
configurations. Our method is based on a step by step decomposition of
osculating configurations, and on the solution of the functional equation
provided by this decomposition
Long range correlations and phase transition in non-equilibrium diffusive systems
We obtain explicit expressions for the long range correlations in the ABC
model and in diffusive models conditioned to produce an atypical current of
particles.In both cases, the two-point correlation functions allow to detect
the occurrence of a phase transition as they become singular when the system
approaches the transition
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