Exploring factors associated with commute mode choice: An application of city-level general social survey data

Developing sustainable transportation systems in a city can be substantially assisted by promoting environmentally friendly transportation modes such as walking, cycling, and public transit rather than private cars. Strategies for promoting these desirable transportation modes can be effectively identified based on a sound understanding of how citizens choose a travel mode. In this study, we sought to enhance this understanding by exploring factors associated with commute mode choice utilizing data from a general social survey in Seoul, South Korea. Based on the data, parametric and non-parametric statistical models based on classification tree and multilevel logistic regression approaches, respectively, were developed as a way to capture influential factors associated with the mode choice decision. The models illustrate that commuters\u27 socio-demographic characteristics such as income, occupation, gender, and residence duration tend to significantly influence mode choice. In addition, they showed that respondents\u27 attitudes and behaviors, including the amount of time spent on the internet and self-assessed social status, can be strongly associated with mode choice. This study is also meaningful in that it demonstrates the potential applicability of general social survey data for investigating travel behavior considering various factors that are rarely included in general transportation surveys

Highly Efficient Catalytic Cyclic Carbonate Formation by Pyridyl Salicylimines

Cyclic carbonates as industrial commodities offer a viable nonredox carbon dioxide fixation, and suitable heterogeneous catalysts are vital for their widespread implementation. Here, we report a highly efficient heterogeneous catalyst for CO₂ addition to epoxides based on a newly identified active catalytic pocket consisting of pyridine, imine, and phenol moieties. The polymeric, metal-free catalyst derived from this active site converts less-reactive styrene oxide under atmospheric pressure in quantitative yield and selectivity to the corresponding carbonate. The catalyst does not need additives, solvents, metals, or co-catalysts, can be reused at least 10 cycles without the loss of activity, and scaled up easily to a kilogram scale. Density functional theory calculations reveal that the nucleophilicity of pyridine base gets stronger due to the conjugated imines and H-bonding from phenol accelerates the reaction forward by stabilizing the intermediate