130 research outputs found
Exploring Biorthonormal Transformations of Pair-Correlation Functions in Atomic Structure Variational Calculations
Multiconfiguration expansions frequently target valence correlation and
correlation between valence electrons and the outermost core electrons.
Correlation within the core is often neglected. A large orbital basis is needed
to saturate both the valence and core-valence correlation effects. This in turn
leads to huge numbers of CSFs, many of which are unimportant. To avoid the
problems inherent to the use of a single common orthonormal orbital basis for
all correlation effects in the MCHF method, we propose to optimize independent
MCHF pair-correlation functions (PCFs), bringing their own orthonormal
one-electron basis. Each PCF is generated by allowing single- and double-
excitations from a multireference (MR) function. This computational scheme has
the advantage of using targeted and optimally localized orbital sets for each
PCF. These pair-correlation functions are coupled together and with each
component of the MR space through a low dimension generalized eigenvalue
problem. Nonorthogonal orbital sets being involved, the interaction and overlap
matrices are built using biorthonormal transformation of the coupled basis sets
followed by a counter-transformation of the PCF expansions.
Applied to the ground state of beryllium, the new method gives total energies
that are lower than the ones from traditional CAS-MCHF calculations using large
orbital active sets. It is fair to say that we now have the possibility to
account for, in a balanced way, correlation deep down in the atomic core in
variational calculations
On the rise of proton-proton cross-sections at high energies
The rise of the total, elastic and inelastic hadronic cross sections at high
energies is investigated by means of an analytical parametrization, with the
exponent of the leading logarithm contribution as a free fit parameter. Using
derivative dispersion relations with one subtraction, two different fits to
proton-proton and antiproton-proton total cross section and rho parameter data
are developed, reproducing well the experimental information in the energy
region 5 GeV - 7 TeV. The parametrization for the total cross sections is then
extended to fit the elastic (integrated) cross section data in the same energy
region, with satisfactory results. From these empirical results we extract the
energy dependence of several physical quantities: inelastic cross section,
ratios elastic/total, inelastic/total cross sections, ratio
total-cross-section/elastic-slope, elastic slope and optical point. All data,
fitted and predicted, are quite well described. We find a statistically
consistent solution indicating: (1) an increase of the hadronic cross sections
with the energy faster than the log-squared bound by Froissart and Martin; (2)
asymptotic limits 1/3 and 2/3 for the ratios elastic/total and inelastic/total
cross sections, respectively, a result in agreement with unitarity. These
indications corroborate recent theoretical arguments by Ya. I. Azimov on the
rise of the total cross section.Comment: 35 pages, 12 figures, discussions improved with further
clarifications, references added and updated, one note added, results and
conclusions unchanged. Version to be published in J. Phys. G: Nucl. Part.
Phy
Experimental study of spin-exchange effects in elastic and ionizing collisions of polarized electrons with polarized hydrogen atoms
Cutaneous lesions of the nose
Skin diseases on the nose are seen in a variety of medical disciplines. Dermatologists, otorhinolaryngologists, general practitioners and general plastic and dermatologic surgeons are regularly consulted regarding cutaneous lesions on the nose. This article is the second part of a review series dealing with cutaneous lesions on the head and face, which are frequently seen in daily practice by a dermatologic surgeon. In this review, we focus on those skin diseases on the nose where surgery or laser therapy is considered a possible treatment option or that can be surgically evaluated
An assessment of American Indian women's mammography experiences
<p>Abstract</p> <p>Background</p> <p>Mortality from breast cancer has increased among American Indian/Alaskan Native (AI/AN) women. Despite this alarming reality, AI/AN women have some of the lowest breast cancer screening rates. Only 37% of eligible AI/AN women report a mammogram within the last year and 52% report a mammogram within the last two years compared to 57% and 72% for White women. The experiences and satisfaction surrounding mammography for AI/AN women likely are different from that of women of other racial/ethnic groups, due to cultural differences and limited access to Indian Health Service sponsored mammography units. The overall goals of this study are to identify and understand the mammography experiences and experiential elements that relate to satisfaction or dissatisfaction with mammography services in an AI/AN population and to develop a culturally-tailored AI/AN mammography satisfaction survey.</p> <p>Methods and Design</p> <p>The three project aims that will be used to guide this work are: 1) To compare the mammography experiences and satisfaction with mammography services of Native American/Alaska Native women with that of Non-Hispanic White, Hispanic, and Black women, 2) To develop and validate the psychometric properties of an American Indian Mammography Survey, and 3) To assess variation among AI/AN women's assessments of their mammography experiences and mammography service satisfaction. Evaluations of racial/ethnic differences in mammography patient satisfaction have received little study, particularly among AI/AN women. As such, qualitative study is uniquely suited for an initial examination of their experiences because it will allow for a rich and in-depth identification and exploration of satisfaction elements.</p> <p>Discussion</p> <p>This formative research is an essential step in the development of a validated and culturally tailored AI/AN mammography satisfaction assessment. Results from this project will provide a springboard from which a maximally effective breast cancer screening program to benefit AI/AN population will be developed and tested in an effort to alter the current breast cancer-related morbidity and mortality trajectory among AI/AN women.</p
Dissolution and biodurability: Important parameters needed for risk assessment of nanomaterials
L’impact sur les intentions de fécondité de la perception subjective de contrôle sur le travail, du stress lié au travail et du conflit travail-famille: une comparaison européenne
Potential flows of dilute polymer solutions by Kramers' method
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