Development of high thermal conductivity polymeric materials for spacecraft use Final report, 1 Jul. 1966 - 31 May 1969

High thermal conductivity polymeric materials for spacecraft applications using phenyl compound

Thermally conducting electron transfer polymers

New polymeric material exhibits excellent physical shock protection, high electrical resistance, and thermal conductivity. It is especially useful for electronic circuitry, such as subminiaturization of components and modular construction of circuits

Improved thermally conducting electron transfer polymers

Development of polymers with improved heat transfer coefficients for use in encapsulating electronic modules is discussed. Chemical reactions for synthesizing the polymers are described and thermodynamic and physical properties are analyzed

Suitability of commercially available laboratory cryogenic refrigerators to support shipboard electro-optical systems in the 10 - 77 Kelvin region

The primary development of cryogenically cooled infrared systems was accomplished by FLIR systems designed for airborne, passive night vision. Essential to the development of these FLIR systems was a family of closed cycle refrigerators which had to meet a limited envelope requirement, utilize a nonlubricated compressor module, and be light in weight. Closed cycle refrigerators accomplished the same cooling function, they use modified oil lubricated reciprocating compressors which are limited in their axis of orientation to an angle of approximately 15-20 degrees maximum from horizon

The extension of the thermal-vacuum test optimization program to multiple flights

The thermal vacuum test optimization model developed to provide an approach to the optimization of a test program based on prediction of flight performance with a single flight option in mind is extended to consider reflight as in space shuttle missions. The concept of 'utility', developed under the name of 'availability', is used to follow performance through the various options encountered when the capabilities of reflight and retrievability of space shuttle are available. Also, a 'lost value' model is modified to produce a measure of the probability of a mission's success, achieving a desired utility using a minimal cost test strategy. The resulting matrix of probabilities and their associated costs provides a means for project management to evaluate various test and reflight strategies

Synthesis and evaluation of polymers for use in early warning fire alarm devices

Conjugated polyacetylene polymers and one condensation polyene, all containing a high degree of conjugated unsaturation, were synthesized. These polymers were characterized by chemical analysis and by thermogravimetric analysis, as well as for their film-forming capability and gas/polymer interactions. It was found that those that had a high degree of conjugated unsaturation and had resonance - stabilizing groups were very thermally stable to 200 C, e.g., poly(dicyanoacetylene), poly(ethynylferrocene) and poly(phenylacetylene); while those with labile moieties, such as poly(p-formamidophenylacetylene), among others, suffered some degradation when heated in air. When subjected to gas/polymer interaction effects, the greatest change in electrical conductance was observed when ammonia was used as the gas and poly(p-nitrophenylacetylene) was the detector. Other polymers showed similar behavior. For example, poly(ethynylcarborane), considered to be an electron acceptor also showed a change in electrical conductance when exposed to ammonia, while poly(ethynylpyridine) and poly(ethylidenepyridazine) responded to carbon monoxide. However, for "fire gases" (gases from smoldering cotton), poly(ethynylferrocene) was the most responsive. Thus, the concept of polymers with different electronegativities forming charge-transfer complexes with different gases was found to be operable

Semiconducting polymers for gas detection

Conjugated polyenes, and polyesters containing phthalocyanine in their backbone, were synthesized. These polymers were characterized by chemical analysis, thermogravimetric analysis, spectral analysis, and X-ray diffraction studies for crystallinity, as well as for their film-forming capability and gas/polymer interactions. Most of the polymers were relatively insensitive to water vapor up to 50 percent relative humidity, but the polyester/phthalocyanine (iron) polymer was relatively insensitive up to 100 percent RH. On the other hand, poly(p-dimethylaminophenylacetylene) was too conductive at 100 percent RH. Of the gases tested, the only ones that gave any evidence of interacting with the polymers were SO2, NOx, HCN and NH3. Poly(imidazole)/thiophene responded to each of these gases at all relative humidities, while the other polymers gave varying response, depending upon the RH. Thus, since most of these gases were electron-accepting, the electron-donating character of poly(imidazole)/thiophene substantiates the concept of electronegativity being the operating principle for interaction effects. Of the six polymers prepared, poly(imidazole)/thiophene first showed a very good response to smoldering cotton, but it later became nonresponsive; presumably due to oxidation effects

Changing the Fourth Channels : Taiwan Tunes in to a New Cable Television Law

Threatened with potentially massive trade sanctions by the United States, Taiwan enacted the Cable Television Law in 1993 to regulate the so-called Fourth Channels, hundreds of private cable operations that transmitted programming pirated from the United States and other sources. This Comment identifies the roots of the Fourth Channels and examines the U.S. and Taiwanese forces that gave rise to the cable law. The Comment analyzes major provisions of the law and explores the law\u27s effects on both U.S. and Taiwanese interests

Functional Ontologies and Their Application to Hydrologic Modeling: Development of an Integrated Semantic and Procedural Knowledge Model and Reasoning Engine

This dissertation represents the research and development of new concepts and techniques for modeling the knowledge about the many concepts we as hydrologists must understand such that we can execute models that operate in terms of conceptual abstractions and have those abstractions translate to the data, tools, and models we use every day. This hydrologic knowledge includes conceptual (i.e. semantic) knowledge, such as the hydrologic cycle concepts and relationships, as well as functional (i.e. procedural) knowledge, such as how to compute the area of a watershed polygon, average basin slope or topographic wetness index. This dissertation is presented as three papers and a reference manual for the software created. Because hydrologic knowledge includes both semantic aspects as well as procedural aspects, we have developed, in the first paper, a new form of reasoning engine and knowledge base that extends the general-purpose analysis and problem-solving capability of reasoning engines by incorporating procedural knowledge, represented as computer source code, into the knowledge base. The reasoning engine is able to compile the code and then, if need be, execute the procedural code as part of a query. The potential advantage to this approach is that it simplifies the description of procedural knowledge in a form that can be readily utilized by the reasoning engine to answer a query. Further, since the form of representation of the procedural knowledge is source code, the procedural knowledge has the full capabilities of the underlying language. We use the term functional ontology to refer to the new semantic and procedural knowledge models. The first paper applies the new knowledge model to describing and analyzing polygons. The second and third papers address the application of the new functional ontology reasoning engine and knowledge model to hydrologic applications. The second paper models concepts and procedures, including running external software, related to watershed delineation. The third paper models a project scenario that includes integrating several models. A key advance demonstrated in this paper is the use of functional ontologies to apply metamodeling concepts in a manner that both abstracts and fully utilizes computational models and data sets as part of the project modeling process

A Bridge Over Troubled Water: Induction Teachers\u27 Perspectives Regarding Their Efficacy Towards Meeting the Needs of Diverse Populations of Students

The purpose of this qualitative multi-case study was to explore the perceptions of 13 first-year teachers as it relates to their readiness to meet the academic needs of their minority students. The findings provided information on their readiness, teacher preparation programs, and support needed from school leaders during their Induction year of teaching. The study was designed to explore the academic needs of the diverse population of students in a rural county school district in the Upstate of South Carolina. A triangulated study was conducted to include face-to-face interviews and an analysis of the transcripts to explore and examine the participants\u27 readiness. The findings revealed 12 themes aligned to three research questions. The themes based on their readiness were classroom management, culture shock, expectations, preconceptions and biases, preparedness, and relationships. The themes associated with their preparation were instructional knowledge, diversity, and communication. The themes associated with the support needed from the school leaders were professional development, ongoing support, and collaboration. The findings suggest the first-year teachers in this study do not understand and accept the cultural differences that exist between themselves and their students. Participants found it difficult to believe their values differed from their students, and this culture shock made it difficult to build relationships with students. The participants were prepared with content knowledge, but were not equipped with the skills needed to impart this knowledge to students. The findings were interpreted and situated in the context of the existing literature including the conceptual framework of culturally relevant pedagogy. The implications of the study are discussed and recommendations for future study were also provided