N 1,N 2-Bis[(2-chloro-6-methyl­quinolin-3-yl)methyl­idene]ethane-1,2-diamine

The title mol­ecule, C24H20Cl2N4, lies on an inversion center in an extended trans conformation. In the crystal, weak C—H⋯Cl inter­actions connect the mol­ecules into chains along [010]

Breaking of the overall permutation symmetry in nonlinear optical susceptibilities of one-dimensional periodic dimerized Huckel model

Based on infinite one-dimensional single-electron periodic models of trans-polyacetylene, we show analytically that the overall permutation symmetry of nonlinear optical susceptibilities is, albeit preserved in the molecular systems with only bound states, no longer generally held for the periodic systems. The overall permutation symmetry breakdown provides a fairly natural explanation to the widely observed large deviations of Kleinman symmetry for periodic systems in off-resonant regions. Physical conditions to experimentally test the overall permutation symmetry break are discussed.Comment: 7 pages, 1 figur

Hawking radiation from "phase horizons" in laser filaments?

Belgiorno et al have reported on experiments aiming at the detection of (the analogue of) Hawking radiation using laser filaments [F. Belgiorno et al, Phys. Rev. Lett. 105, 203901 (2010)]. They sent intense focused Bessel pulses into a non-linear dielectric medium in order to change its refractive index via the Kerr effect and saw creation of photons orthogonal to the direction of travel of the pluses. Since the refractive index change in the pulse generated a "phase horizon" (where the phase velocity of these photons equals the pulse speed), they concluded that they observed the analogue of Hawking radiation. We study this scenario in a model with a phase horizon and a phase velocity very similar to that of their experiment and find that the effective metric does not quite correspond to a black hole. The photons created in this model are not due to the analogue of black hole evaporation but have more similarities to cosmological particle creation. Nevertheless, even this effect cannot explain the observations -- unless the pulse has significant small scale structure in both the longitudinal and transverse dimensions.Comment: 13 pages RevTeX, 2 figure

Adolescents' reference groups in the school situation

Most researchers who have studied the relationship between the adolescent, his parents and his peers have cast parents and peers as mutually exclusive forces - to follow one is automatically to reject the other. These researchers have turned up inconsistent findings, some finding the adolescent's conformity to his peers so great that they write of a separate youth culture, while others have found that the adolescent is still very much under the thumb of his parents

Linear response functions for a vibrational configuration interaction state

Linear response functions are implemented for a vibrational configuration interaction state allowing accurate analytical calculations of pure vibrational contributions to dynamical polarizabilities. Sample calculations are presented for the pure vibrational contributions to the polarizabilities of water and formaldehyde. We discuss the convergence of the results with respect to various details of the vibrational wave function description as well as the potential and property surfaces. We also analyze the frequency dependence of the linear response function and the effect of accounting phenomenologically for the finite lifetime of the excited vibrational states. Finally, we compare the analytical response approach to a sum-over-states approac

1-Formyl-r-2,c-6-bis­(4-methoxy­phen­yl)-t-3-methyl­piperidin-4-one

The asymmetric unit of the title compound, C21H23NO4, contains two crystallographically independent mol­ecules A and B. In both mol­ecules, the piperidine-4-one rings adopt a distorted twist-boat conformation. The formyl group at position 1, the methoxy­phenyl ring at position 2 and the methyl group at position 3 are attached equatorially. The meth­oxy phenyl ring at position 6 has an axial orientation. The dihedral angle between the two benzene rings is 55.27 (8)° in mol­ecule A, and 55.29 (8)° in mol­ecule B. In the crystal, the mol­ecules are linked by weak C—H⋯O inter­molecular hydrogen-bond inter­actions. In addition, weak C—H⋯π inter­molecular inter­actions involving the benzene rings at positions 6 and 2 of mol­ecule B are also found in the crystal structure

Structure of multiphoton quantum optics. II. Bipartite systems, physical processes, and heterodyne squeezed states

Extending the scheme developed for a single mode of the electromagnetic field in the preceding paper ``Structure of multiphoton quantum optics. I. Canonical formalism and homodyne squeezed states'', we introduce two-mode nonlinear canonical transformations depending on two heterodyne mixing angles. They are defined in terms of hermitian nonlinear functions that realize heterodyne superpositions of conjugate quadratures of bipartite systems. The canonical transformations diagonalize a class of Hamiltonians describing non degenerate and degenerate multiphoton processes. We determine the coherent states associated to the canonical transformations, which generalize the non degenerate two--photon squeezed states. Such heterodyne multiphoton squeezed are defined as the simultaneous eigenstates of the transformed, coupled annihilation operators. They are generated by nonlinear unitary evolutions acting on two-mode squeezed states. They are non Gaussian, highly non classical, entangled states. For a quadratic nonlinearity the heterodyne multiphoton squeezed states define two--mode cubic phase states. The statistical properties of these states can be widely adjusted by tuning the heterodyne mixing angles, the phases of the nonlinear couplings, as well as the strength of the nonlinearity. For quadratic nonlinearity, we study the higher-order contributions to the susceptibility in nonlinear media and we suggest possible experimental realizations of multiphoton conversion processes generating the cubic-phase heterodyne squeezed states.Comment: 16 pages, 23 figure

On the Non-invasive Measurement of the Intrinsic Quantum Hall Effect

With a model calculation, we demonstrate that a non-invasive measurement of intrinsic quantum Hall effect defined by the local chemical potential in a ballistic quantum wire can be achieved with the aid of a pair of voltage leads which are separated by potential barriers from the wire. B\"uttiker's formula is used to determine the chemical potential being measured and is shown to reduce exactly to the local chemical potential in the limit of strong potential confinement in the voltage leads. Conditions for quantisation of Hall resistance and measuring local chemical potential are given.Comment: 16 pages LaTex, 2 post-script figures available on reques

The physical significance of the Babak-Grishchuk gravitational energy-momentum tensor

We examine the claim of Babak and Grishchuk [1] to have solved the problem of localising the energy and momentum of the gravitational field. After summarising Grishchuk's flat-space formulation of gravity, we demonstrate its equivalence to General Relativity at the level of the action. Two important transformations are described (diffeomorphisms applied to all fields, and diffeomorphisms applied to the flat-space metric alone) and we argue that both should be considered gauge transformations: they alter the mathematical representation of a physical system, but not the system itself. By examining the transformation properties of the Babak-Grishchuk gravitational energy-momentum tensor under these gauge transformations (infinitesimal and finite) we conclude that this object has no physical significance.Comment: 10 pages. Submitted to Phys. Rev. D; acknowledgements adjuste