Manipulation of the graphene surface potential by ion irradiation

We show that the work function of exfoliated single layer graphene can be modified by irradiation with swift (E_{kin}=92 MeV) heavy ions under glancing angles of incidence. Upon ion impact individual surface tracks are created in graphene on SiC. Due to the very localized energy deposition characteristic for ions in this energy range, the surface area which is structurally altered is limited to ~ 0.01 mum^2 per track. Kelvin probe force microscopy reveals that those surface tracks consist of electronically modified material and that a few tracks suffice to shift the surface potential of the whole single layer flake by ~ 400 meV. Thus, the irradiation turns the initially n-doped graphene into p-doped graphene with a hole density of 8.5 x 10^{12} holes/cm^2. This doping effect persists even after heating the irradiated samples to 500{\deg}C. Therefore, this charge transfer is not due to adsorbates but must instead be attributed to implanted atoms. The method presented here opens up a new way to efficiently manipulate the charge carrier concentration of graphene.Comment: 6 pages, 4 figure

Intrinsic and structural isotope effects in Fe-based superconductors

The currently available results of the isotope effect on the superconducting transition temperature T_c in Fe-based high-temperature superconductors (HTS) are highly controversial. The values of the Fe isotope effect (Fe-IE) exponent \alpha_Fe for various families of Fe-based HTS were found to be as well positive, as negative, or even be exceedingly larger than the BCS value \alpha_BCS=0.5. Here we demonstrate that the Fe isotope substitution causes small structural modifications which, in turn, affect T_c. Upon correcting the isotope effect exponent for these structural effects, an almost unique value of \alpha~0.35-0.4 is observed for at least three different families of Fe-based HTS.Comment: 4 pages, 2 figure

Evidence for strong lattice effects as revealed from huge unconventional oxygen isotope effects on the pseudogap temperature in La2−x_{2-x}Srx_{x}CuO4_{4}

The oxygen isotope ($^{16}$O/$^{18}$O) effect (OIE) on the pseudogap (charge-stripe ordering) temperature $T^{\ast}$ is investigated for the cuprate superconductor La$_{2-x}$Sr$_{x}$CuO$_{4}$ as a function of doping $x$ by means of x-ray absorption near edge structure (XANES) studies. A strong $x$ dependent and sign reversed OIE on $T^{\ast}$ is observed. The OIE exponent $\alpha_{T^{\ast}}$ systematically decreases from $\alpha_{T^{\ast}} = - 0.6(1.3)$ for $x = 0.15$ to $\alpha_{T^{\ast}} = - 4.4(1.1)$ for $x = 0.06$, corresponding to increasing $T^{\ast}$ and decreasing superconducting transition temperature $T_{c}$. Both $T^{\ast}(^{16}{\rm O})$ and $T^{\ast}(^{18}{\rm O})$ exhibit a linear doping dependence with different slopes and critical end points (where $T^{\ast}(^{16}{\rm O})$ and $T^{\ast}(^{18}{\rm O})$ fall to zero) at $x_{c}(^{16}{\rm O}) = 0.201(4)$ and $x_{c}(^{18}{\rm O}) = 0.182(3)$, indicating a large positive OIE of $x_{c}$ with an exponent of $\alpha_{x_{c}} = 0.84(22)$. The remarkably large and strongly doping dependent OIE on $T^{\ast}$ signals a substantial involvement of the lattice in the formation of the pseudogap, consistent with a polaronic approach to cuprate superconductivity and the vibronic character of its ground state

Correlation between oxygen isotope effects on the transition temperature and the magnetic penetration depth in high-temperature superconductors close to optimal doping

The oxygen-isotope (^{16}O/^{18}O) effect (OIE) on the in-plane magnetic penetration depth \lambda_{ab}(0) in optimally-doped YBa_2Cu_3O_{7-\delta} and La_{1.85}Sr_{0.15}CuO_4, and in slightly underdoped YBa_2Cu_4O_8 and Y_{0.8}Pr_{0.2}Ba_2Cu_3O_{7-\delta} was studied by means of muon-spin rotation. A substantial OIE on \lambda_{ab}(0) with an OIE exponent \beta_O=-d\ln\lambda_{ab}(0)/d\ln M_O\approx - 0.2 (M_O is the mass of the oxygen isotope), and a small OIE on the transition temperature T_c with an OIE exponent \alpha_O=-d\ln T_{c}/d \ln M_O\simeq0.02 to 0.1 were observed. The observation of a substantial isotope effect on \lambda_{ab}(0), even in cuprates where the OIE on T_c is small, indicates that lattice effects play an important role in cuprate HTS.Comment: 6 pages, 4 figure

Iron isotope effect on the superconducting transition temperature and the crystal structure of FeSe_1-x

The Fe isotope effect (Fe-IE) on the transition temperature T_c and the crystal structure was studied in the Fe chalcogenide superconductor FeSe_1-x by means of magnetization and neutron powder diffraction (NPD). The substitution of natural Fe (containing \simeq 92% of ^{56}Fe) by its lighter ^{54}Fe isotope leads to a shift of T_c of 0.22(5)K corresponding to an Fe-IE exponent of \alpha_Fe=0.81(15). Simultaneously, a small structural change with isotope substitution is observed by NDP which may contribute to the total Fe isotope shift of T_c.Comment: 4 pages, 3 figure

The polarizability model for ferroelectricity in perovskite oxides

This article reviews the polarizability model and its applications to ferroelectric perovskite oxides. The motivation for the introduction of the model is discussed and nonlinear oxygen ion polarizability effects and their lattice dynamical implementation outlined. While a large part of this work is dedicated to results obtained within the self-consistent-phonon approximation (SPA), also nonlinear solutions of the model are handled which are of interest to the physics of relaxor ferroelectrics, domain wall motions, incommensurate phase transitions. The main emphasis is to compare the results of the model with experimental data and to predict novel phenomena.Comment: 55 pages, 35 figure

Charge-density-wave instability in the Holstein model with quartic anharmonic phonons

The molecular-crystal model, that describes a one-dimensional electron gas interacting with quartic anharmonic lattice vibrations, offers great potentials in the mapping of a relatively wide range of low-dimensional fermion systems coupled to optical phonons onto quantum liquids with retarded interactions. Following a non-perturbative approach involving non-Gaussian partial functional integrations of lattice degrees of freedom, the exact expression of the phonon-mediated two-electron action for this model is derived. With the help of Hubbard-Stratonovich transformation the charge-density-wave instability is examined in the sequel, with particular emphasis on the effect of the quartic anharmonic phonons on the charge-density-wave transition temperature.Comment: 12 pages, 3 figure

The Star Formation Histories of z ~ 2 Dust-obscured Galaxies and Submillimeter-selected Galaxies

The Spitzer Space Telescope has identified a population of ultraluminous infrared galaxies (ULIRGs) at z ~ 2 that may play an important role in the evolution of massive galaxies. We measure the stellar masses (M_*) of two populations of Spitzer-selected ULIRGs that have extremely red R – [24] colors (dust-obscured galaxies, or DOGs) and compare our results with submillimeter-selected galaxies (SMGs). One set of 39 DOGs has a local maximum in their mid-infrared (mid-IR) spectral energy distribution (SED) at rest frame 1.6 μm associated with stellar emission ("bump DOGs"), while the other set of 51 DOGs have power-law mid-IR SEDs that are typical of obscured active galactic nuclei ("power-law DOGs"). We measure M_* by applying Charlot & Bruzual stellar population synthesis models to broadband photometry in the rest-frame ultraviolet, optical, and near-infrared of each of these populations. Assuming a simple stellar population and a Chabrier initial mass function, we find that power-law DOGs and bump DOGs are on average a factor of 2 and 1.5 more massive than SMGs, respectively (median and inter-quartile M_* values for SMGs, bump DOGs, and power-law DOGs are log(M_*/M_☉) = 10.42^(+0.42)_(–0.36), 10.62^(+0.36)_(–0.32), and 10.71^(+0.40)_(–0.34), respectively). More realistic star formation histories drawn from two competing theories for the nature of ULIRGs at z ~ 2 (major merger versus smooth accretion) can increase these mass estimates by up to 0.5 dex. A comparison of our stellar masses with the instantaneous star formation rate (SFR) in these z ~ 2 ULIRGs provides a preliminary indication supporting high SFRs for a given M_*, a situation that arises more naturally in major mergers than in smooth accretion-powered systems