63 research outputs found
Ionization energy of Li 6,7 determined by triple-resonance laser spectroscopy
Rydberg level energies for Li7 were measured using triple-resonance laser excitation, followed by drifted field ionization. In addition to the principal n P2 series, weak Stark mixing from residual electric fields allowed observation of n S2 and hydrogenic Stark manifold series at higher n. Limit analyses for the series yield the spectroscopic ionization energy EI (Li7) =43 487.159 40 (18) cm-1. The Li 6,7 isotope shift (IS) was measured in selected n P2 Rydberg levels and extrapolation to the series limit yields IS (EI) 7,6 =18 067.54 (21) MHz. Results are compared with recent theoretical calculations: EI values from experiment and theory agree to within 0.0011 cm-1, with the remaining discrepancy comparable to uncertainty in QED corrections of order α4 Ry. The difference between experiment and calculated mass-based IS (EI) yields a change in nuclear charge radii between the two isotopes δ r2 7,6 =-0.60 (10) fm2. © 2007 The American Physical Society
Isotope Shift Measurements of Stable and Short-Lived Lithium Isotopes for Nuclear Charge Radii Determination
Changes in the mean-square nuclear charge radii along the lithium isotopic
chain were determined using a combination of precise isotope shift measurements
and theoretical atomic structure calculations. Nuclear charge radii of light
elements are of high interest due to the appearance of the nuclear halo
phenomenon in this region of the nuclear chart. During the past years we have
developed a new laser spectroscopic approach to determine the charge radii of
lithium isotopes which combines high sensitivity, speed, and accuracy to
measure the extremely small field shift of an 8 ms lifetime isotope with
production rates on the order of only 10,000 atoms/s. The method was applied to
all bound isotopes of lithium including the two-neutron halo isotope Li-11 at
the on-line isotope separators at GSI, Darmstadt, Germany and at TRIUMF,
Vancouver, Canada. We describe the laser spectroscopic method in detail,
present updated and improved values from theory and experiment, and discuss the
results.Comment: 34 pages, 24 figures, 14 table
Nuclear Charge Radius of Li-9, Li-11: Halo Neutron: the influence of Halo Neutrons
The nuclear charge radius of Li-11 has been determined for the first time by
high precision laser spectroscopy. On-line measurements at TRIUMF-ISAC yielded
a Li-7 - Li-11 isotope shift (IS) of 25101.23(13) MHz for the Doppler-free 2s -
3s transition. IS precision for all other bound Li isotopes was also improved.
Differences from calculated mass-based IS yield values for change in charge
radius along the isotope chain. The charge radius decreases monotonically from
Li-6 to Li-9, and then increases from 2.217(35) fm to 2.467(37) fm for Li-11.
This is compared to various models, and it is found that a combination of halo
neutron correlation and intrinsic core excitation best reproduces the
experimental results.Comment: 5 pages, 2 figure
The processing and impact of dissolved riverine nitrogen in the Arctic Ocean
© The Author(s), 2011. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Estuaries and Coasts 35 (2012): 401-415, doi:10.1007/s12237-011-9417-3.Although the Arctic Ocean is the most riverine-influenced of all of the world’s oceans, the importance of terrigenous nutrients in this environment is poorly understood. This study couples estimates of circumpolar riverine nutrient fluxes from the PARTNERS (Pan-Arctic River Transport of Nutrients, Organic Matter, and Suspended Sediments) Project with a regionally configured version of the MIT general circulation model to develop estimates of the distribution and availability of dissolved riverine N in the Arctic Ocean, assess its importance for primary production, and compare these estimates to potential bacterial production fueled by riverine C. Because riverine dissolved organic nitrogen is remineralized slowly, riverine N is available for uptake well into the open ocean. Despite this, we estimate that even when recycling is considered, riverine N may support 0.5–1.5 Tmol C year−1 of primary production, a small proportion of total Arctic Ocean photosynthesis. Rapid uptake of dissolved inorganic nitrogen coupled with relatively high rates of dissolved organic nitrogen regeneration in N-limited nearshore regions, however, leads to potential localized rates of riverine-supported photosynthesis that represent a substantial proportion of nearshore production.Funding for this work was provided through NSFOPP-
0229302 and NSF-OPP-0732985.Support to SET was additionally
provided by an NSERC Postdoctoral Fellowship
Recommended from our members
Laser ablation/ionization characterization of solids: Second interim progress report of the strategic environmental research development program
The Department of Energy is undertaking the enormous task of remediating defense wastes and environmental insults which have occurred over 50 years of nuclear weapons production. It is abundantly clear that significant technology advances are needed to characterize, process, and store highly radioactive waste and to remediate contaminated zones. In addition to the processing and waste form issues, analytical technologies needed for the characterization of solids, and for monitoring storage tanks and contaminated sites do not exist or are currently expensive labor-intensive tasks. This report describes progress in developing sensitive, rapid, and widely applicable laser-based mass spectrometry techniques for analysis of mixed chemical wastes and contaminated soils
- …