Change of Compressiblity at the Glass Transition and Prigogine-Defay Ratio in ZrTiCuNiBe Alloys

The change of the compressibility at the glass transition Tg is evaluated from pressure experiments in the liquid and the glassy state of the ZrTiCuNiBe bulk metallic glass forming system. Via the enthalpy recovery method, we derive an increase of Tg with pressure of 3.6 K/GPa. Comparing the changes of the compressibility, the specific heat capacity, and the thermal expansion coefficient at Tg, we estimate for the first time a Prigogine-Defay ratio in metallic systems. This ratio is about 2.4 for the present alloy and compares well with known nonmetallic glass forming systems

Experimental determination of a time–temperature-transformation diagram of the undercooled Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 alloy using the containerless electrostatic levitation processing technique

High temperature high vacuum electrostatic levitation was used to determine the complete time–temperature–transformation (TTT) diagram of the Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 bulk metallic glass forming alloy in the undercooled liquid state. This is the first report of experimental data on the crystallization kinetics of a metallic system covering the entire temperature range of the undercooled melt down to the glass transition temperature. The measured TTT diagram exhibits the expected "C" shape. Existing models that assume polymorphic crystallization cannot satisfactorily explain the experimentally obtained TTT diagram. This originates from the complex crystallization mechanisms that occur in this bulk glass-forming system, involving large composition fluctuations prior to crystallization as well as phase separation in the undercooled liquid state below 800 K

Metallic glass formation in highly undercooled Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 during containerless electrostatic levitation processing

Various sample sizes of Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 with masses up to 80 mg were undercooled below Tg (the glass transition temperature) while electrostatically levitated. The final solidification product of the sample was determined by x-ray diffraction to have an amorphous phase. Differential scanning calorimetry was used to confirm the absence of crystallinity in the processes sample. The amorphous phase could be formed only after heating the samples above the melting temperature for extended periods of time in order to break down and dissolve oxides or other contaminants which would otherwise initiate heterogeneous nucleation of crystals. Noncontact pyrometry was used to monitor the sample temperature throughout processing. The critical cooling rate required to avoid crystallization during solidification of the Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 alloy fell between 0.9 and 1.2 K/s

Hemispherical total emissivity and specific heat capacity of deeply undercooled Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 melts

High-temperature high-vacuum electrostatic levitation (HTHVESL) and differential scanning calorimetry (DSC) were combined to determine the hemispherical total emissivity epsilon T, and the specific heat capacity cp, of the undercooled liquid and throughout the glass transition of the Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 bulk metallic glass forming alloy. The ratio of cp/epsilon T as a function of undercooling was determining from radiative cooling curves measured in the HTHVESL. Using specific heat capacity data obtained by DSC investigations close to the glass transition and above the melting point, epsilon T and cp were separated and the specific heat capacity of the whole undercooled liquid region was determined. Furthermore, the hemispherical total emissivity of the liquid was found to be about 0.22 at 980 K. On undercooling the liquid, the emissivity decreases to approximately 0.18 at about 670 K, where the undercooled liquid starts to freeze to a glass. No significant changes of the emissivity are observed as the alloy undergoes the glass transition

Spontaneous Emission in ultra-cold spin-polarised anisotropic Fermi Seas

We examine and explain the spatial emission patterns of ultracold excited fermions in anisotropic trapping potentials in the presence of a spin polarised Fermi sea of ground state atoms. Due to the Pauli principle, the Fermi sea modifies the available phase space for the recoiling atom and thereby modifies its decay rate and the probability of the emitted photon's direction. We show that the spatial anisotropies are due to an intricate interplay between Fermi energies and degeneracy values of specific energy levels and identify a regime in which the emission will become completely directional. Our results are relevant for recent advances in trapping and manipulating cold fermionic samples experimentally and give an example of a conceptually new idea for a directional photon source.Comment: 7 pages, 7 figure

Observing the Profile of an Atom Laser Beam

We report on an investigation of the beam profile of an atom laser extracted from a magnetically trapped $^{87}$Rb Bose-Einstein condensate. The transverse momentum distribution is magnified by a curved mirror for matter waves and a momentum resolution of 1/60 of a photon recoil is obtained. We find the transverse momentum distribution to be determined by the mean-field potential of the residing condensate, which leads to a non-smooth transverse density distribution. Our experimental data are compared with a full 3D simulation of the output coupling process and we find good agreement.Comment: 4 pages, 4 figure

Strongly Incompatible Quantum Devices

The fact that there are quantum observables without a simultaneous measurement is one of the fundamental characteristics of quantum mechanics. In this work we expand the concept of joint measurability to all kinds of possible measurement devices, and we call this relation compatibility. Two devices are incompatible if they cannot be implemented as parts of a single measurement setup. We introduce also a more stringent notion of incompatibility, strong incompatibility. Both incompatibility and strong incompatibility are rigorously characterized and their difference is demonstrated by examples.Comment: 27 pages (AMSart), 6 figure

Detection of quantum light in the presence of noise

Detection of quantum light in the presence of dark counts and background radiation noise is considered. The corresponding positive operator-valued measure is obtained and photocounts statistics of quantum light in the presence of noise is studied.Comment: 4 pages, 1 figure; misprints correcte

Small Numbers of Vortices in Anisotropic Traps

We investigate the appearance of vortices and vortex lattices in two-dimensional, anisotropic and rotating Bose-Einstein condensates. Once the anisotropy reaches a critical value, the positions of the vortex cores in the ground state are no longer given by an Abrikosov lattice geometry, but by a linear arrangement. Using a variational approach, we determine the critical stirring frequency for a single vortex as well as the equilibrium positions of a small number of vortices.Comment: 7 pages, 7 figure

Thermodynamics of Cu47Ti34Zr11Ni8, Zr52.5Cu17.9Ni14.6Al10Ti5 and Zr57Cu15.4Ni12.6Al10Nb5 bulk metallic glass forming alloys

The differences in the thermodynamic functions between the liquid and the crystalline states of three bulk metallic glass forming alloys, Cu47Ti34Zr11Ni8, Zr52.5Cu17.9Ni14.6Al10Ti5, and Zr57Cu15.4Ni12.6Al10Nb5, were calculated. The heat capacity was measured in the crystalline solid, the amorphous solid, the supercooled liquid, and the equilibrium liquid. Using these heat capacity data and the heats of fusion of the alloys, the differences in the thermodynamic functions between the liquid and the crystalline states were determined. The Gibbs free energy difference between the liquid and the crystalline states gives a qualitative measure of the glass forming ability of these alloys. Using the derived entropy difference, the Kauzmann temperatures for these alloys were determined