Phase diagram analysis and crystal growth of solid solutions Ca_{1-x}Sr_xF_2

The binary phase diagram CaF$_2$--SrF$_2$ was investigated by differential thermal analysis (DTA). Both substances exhibit unlimited mutual solubility with an azeotropic point showing a minimum melting temperature of T_\mathrm{min}=1373^{\circ}$C for the composition Ca$_{0.582}$Sr$_{0.418}$F$_2$. Close to this composition, homogeneous single crystals up to 30 mm diameter without remarkable segregation could be grown by the Czochralski method.Comment: accepted for publication in J. Crystal Growt

Evaluation of diffusive gradients in thin-films using a Diphonix® resin for monitoring dissolved uranium in natural waters

Commercially available Diphonix® resin (TrisKem International) was evaluated as a receiving phase for use with the diffusive gradients in thin-films (DGT) passive sampler for measuring uranium. This resin has a high partition coefficient for actinides and is used in the nuclear industry. Other resins used as receiving phases with DGT for measuring uranium have been prone to saturation and significant chemical interferences. The performance of the device was evaluated in the laboratory and in field trials. In laboratory experiments uptake of uranium (all 100% efficiency) by the resin was unaffected by varying pH (4–9), ionic strength (0.01–1.00 M, as NaNO3) and varying aqueous concentrations of Ca2+ (100–500 mg L−1) and HCO3− (100–500 mg L−1). Due to the high partition coefficient of Diphonex®, several elution techniques for uranium were evaluated. The optimal eluent mixture was 1 M NaOH/1 M H2O2, eluting 90% of the uranium from the resin. Uptake of uranium was linear (R2 = 0.99) over time (5 days) in laboratory experiments using artificial freshwater showing no saturation effects of the resin. In field deployments (River Lambourn, UK) the devices quantitatively accumulated uranium for up to 7 days. In both studies uptake of uranium matched that theoretically predicted for the DGT. Similar experiments in seawater did not follow the DGT theoretical uptake and the Diphonix® appeared to be capacity limited and also affected by matrix interferences. Isotopes of uranium (U235/U238) were measured in both environments with a precision and accuracy of 1.6–2.2% and 1.2–1.4%, respectively. This initial study shows the potential of using Diphonix®-DGT for monitoring of uranium in the aquatic environment

EBSD mapping of herringbone domain structures in tetragonal piezoelectrics

Herringbone domain structures have been mapped using electron backscatter diffraction (EBSD) in two tetragonal piezoelectrics, lead zirconate titanate, [Pb(Zr,Ti)O<sub>3</sub>] and bismuth ferrite – lead titanate, [(PbTi)<sub>0.5</sub>(BiFe)<sub>0.5</sub>O<sub>3</sub>]. Analysis of the domain misorientations across the band junctions shows that the structures correspond very well to crystallographic models. High resolution mapping with a 20 nm step size allowed the crystal rotation across one of these band junctions in lead zirconate titanate to be studied in detail and allowed an improved estimation of the peak strain at the junction, of 0.56 GPa. The significance of this for crack nucleation and propagation in such materials is discussed

The Knudsen temperature jump and the Navier-Stokes hydrodynamics of granular gases driven by thermal walls

Thermal wall is a convenient idealization of a rapidly vibrating plate used for vibrofluidization of granular materials. The objective of this work is to incorporate the Knudsen temperature jump at thermal wall in the Navier-Stokes hydrodynamic modeling of dilute granular gases of monodisperse particles that collide nearly elastically. The Knudsen temperature jump manifests itself as an additional term, proportional to the temperature gradient, in the boundary condition for the temperature. Up to a numerical pre-factor of order unity, this term is known from kinetic theory of elastic gases. We determine the previously unknown numerical pre-factor by measuring, in a series of molecular dynamics (MD) simulations, steady-state temperature profiles of a gas of elastically colliding hard disks, confined between two thermal walls kept at different temperatures, and comparing the results with the predictions of a hydrodynamic calculation employing the modified boundary condition. The modified boundary condition is then applied, without any adjustable parameters, to a hydrodynamic calculation of the temperature profile of a gas of inelastic hard disks driven by a thermal wall. We find the hydrodynamic prediction to be in very good agreement with MD simulations of the same system. The results of this work pave the way to a more accurate hydrodynamic modeling of driven granular gases.Comment: 7 pages, 3 figure

Development and Use of a Pneumoconiosis Database of Human Pulmonary Inorganic Particulate Burden in Over 400 Lungs

Over 400 cases with data from in situ electron microprobe quantitation of non-fibrous inorganic particles (e.g., silica, alumino-silicates, talc, metals) in pulmonary tissue sections, and data from quantitative digestion analyses for fiber content (e.g., asbestos, silica, alumino-silicates, man-made fibers, talc) comprise an extensive microcomputer data set of lung particle burden. When allied with demographic and histopathologic information the result is a comprehensive database of occupational pulmonary pathology. Examples of the kinds of information which can be extracted from the database include: 1) summary information on the types sizes and associations of particles in lungs with a variety of exposures, 2) concentrations of etiologic particle type in cases with recognized pneumoconioses, and 3) correlations between particle type, pathology, occupation and social history. The database provides a powerful tool for assessing such information on statistically meaningful sample sets

Just how long can you live in a black hole and what can be done about it?

We study the problem of how long a journey within a black hole can last. Based on our observations, we make two conjectures. First, for observers that have entered a black hole from an asymptotic region, we conjecture that the length of their journey within is bounded by a multiple of the future asymptotic ``size'' of the black hole, provided the spacetime is globally hyperbolic and satisfies the dominant-energy and non-negative-pressures conditions. Second, for spacetimes with ${\Bbb R}^3$ Cauchy surfaces (or an appropriate generalization thereof) and satisfying the dominant energy and non-negative-pressures conditions, we conjecture that the length of a journey anywhere within a black hole is again bounded, although here the bound requires a knowledge of the initial data for the gravitational field on a Cauchy surface. We prove these conjectures in the spherically symmetric case. We also prove that there is an upper bound on the lifetimes of observers lying ``deep within'' a black hole, provided the spacetime satisfies the timelike-convergence condition and possesses a maximal Cauchy surface. Further, we investigate whether one can increase the lifetime of an observer that has entered a black hole, e.g., by throwing additional matter into the hole. Lastly, in an appendix, we prove that the surface area $A$ of the event horizon of a black hole in a spherically symmetric spacetime with ADM mass $M_{\text{ADM}}$ is always bounded by $A \le 16\pi M_{\text{ADM}}^2$, provided that future null infinity is complete and the spacetime is globally hyperbolic and satisfies the dominant-energy condition.Comment: 20 pages, REVTeX 3.0, 6 figures included, self-unpackin

Understanding the effects of peripheral vision and muscle memory on in-vehicle touchscreen interactions

It is important to gain a better understanding of how drivers interact with in-vehicle touchscreens to help design interfaces to minimise “eyes off road” time. The study aimed to investigate the relative effects of two interaction mechanisms (peripheral vision - PV and muscle memory - MM) shown to be relevant to visual behaviour when driving, on the time to press different sized buttons (small 6x6cm, medium 10x10cm, large 14x14cm) on an in-vehicle touchscreen. Twenty-five participants took part in a driving simulator study. They were presented with a single, white, square button on the touchscreen on 24 successive trials. For MM conditions, participants wore a pair of glasses that blocked their peripheral vision and for PV conditions they were asked to keep their focus on the vehicle in front throughout. Results showed that task time gradually decreased for the trials when participants could only use MM. However, overall task time for MM conditions were significantly higher than for those in which PV was utilised, and participants rated the use of MM to be more difficult than PV. In contrast, results suggest that for interfaces that utilise peripheral visual processing the learning effect is not evident and operation times are constant over time. These findings indicate that in-vehicle touch screens should be designed to utilise peripheral vision for making simple button selections with reduced visual demand

Understanding the effects of peripheral vision and muscle memory on in-vehicle touchscreen interactions

It is important to gain a better understanding of how drivers interact with in-vehicle touchscreens to help design interfaces to minimise “eyes off road” time. The study aimed to investigate the relative effects of two interaction mechanisms (peripheral vision - PV and muscle memory - MM) shown to be relevant to visual behaviour when driving, on the time to press different sized buttons (small 6x6cm, medium 10x10cm, large 14x14cm) on an in-vehicle touchscreen. Twenty-five participants took part in a driving simulator study. They were presented with a single, white, square button on the touchscreen on 24 successive trials. For MM conditions, participants wore a pair of glasses that blocked their peripheral vision and for PV conditions they were asked to keep their focus on the vehicle in front throughout. Results showed that task time gradually decreased for the trials when participants could only use MM. However, overall task time for MM conditions were significantly higher than for those in which PV was utilised, and participants rated the use of MM to be more difficult than PV. In contrast, results suggest that for interfaces that utilise peripheral visual processing the learning effect is not evident and operation times are constant over time. These findings indicate that in-vehicle touch screens should be designed to utilise peripheral vision for making simple button selections with reduced visual demand

In Search of the Solar Wind Nitrogen Isotope Composition: Analysis of a Gold Plate from the Genesis Spacecraft Concentrator

We report N isotope analysis of a gold plate from the Genesis spacecraft concentrator. We did not find evidence for a light N component in the solar wind