2,061 research outputs found

    Temperature dependence of the triplet diffusion and quenching rates in films of an Ir(ppy)(3)-cored dendrimer

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    We study photoluminescence and triplet-triplet exciton annihilation in a neat film of a fac-tris(2-phenylpyridyl)iridium(III) [Ir(ppy)(3)]-cored dendrimer and in its blend with a 4,4(')-bis(N-carbazolyl)biphenyl host for the temperature range of 77-300 K. The nearest neighbor hopping rate of triplet excitons is found to increase by a factor of 2 with temperature between 150 and 300 K and is temperature independent at lower temperature. The intermolecular quenching rate follows the Arrhenius law with an activation energy of 7 meV, which can be explained by stronger dipole-dipole interactions with the donor molecule in the higher triplet substate. The results indicate that energy disorder has no significant effect on triplet transport and quenching in these materials

    Self-Generated Magnetic Fields in Galactic Cooling Flows

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    Interstellar magnetic fields in elliptical galaxies are assumed to have their origin in stellar fields that accompany normal mass loss from an evolving population of old stars. The seed fields are amplified by interstellar turbulence driven by stellar mass loss and supernova events. These disordered fields are further amplified by time-dependent compression in the inward moving galactic cooling flow and are expected to dominate near the galactic core. Under favorable circumstances, fields similar in strength to those observed B110 (r/10 kpc)1.2μB \sim 1-10~(r/10~kpc)^{-1.2}\muG can be generated solely from these natural galactic processes. In general the interstellar field throughout elliptical galaxies is determined by the outermost regions in the interstellar gas where the turbulent dynamo process can occur. Because of the long hydrodynamic flow times in galactic cooling flows, currently observed magnetic fields may result from periods of intense turbulent field amplification that occurred in the outer galaxy in the distant past. Particularly strong fields in ellipticals may result from ancient galactic mergers or shear turbulence introduced at the boundary between the interstellar gas and ambient cluster gas.Comment: 21 pages in AASTEX LaTeX with 2 figures; accepted by Astrophysical Journa

    Evidence for Ordered Magnetic Fields in the Quasar Environment

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    At a distance of 20 pc from the purported supermassive black hole powering quasars, temperatures and densities are inferred from optical observations to be ~10**4 K and ~10**4 cm**-3. Here we present Very Long Baseline Interferometry radio observations revealing organized magnetic fields on the parsec scale in the hot plasma surrounding the quasar OQ172 (1442+101). These magnetic fields rotate the plane of polarization of the radio emission coming from the core and inner jet of the quasar. The derived rotation measure (RM) is 40,000 rad m**-2 in the rest frame of the quasar. Only 10 mas (a projected distance of 68 pc) from the nucleus the jet absolute values of RM fall to less than 100 rad m**-2.Comment: in press at ApJ Letters, 12 page LaTeX document includes 4 postscript figure

    In-plane superfluid density and microwave conductivity of the organic superconductor kappa-(BEDT-TTF)(2)Cu[N(CN)(2)]Br: evidence for d-wave pairing and resilient quasiparticles

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    We report the in-plane microwave surface impedance of a high-quality single crystal of kappa-(BEDT-TTF)(2)Cu[N(CN)(2)]Br. In the superconducting state, we find three independent signatures of d-wave pairing: (i) a strong, linear temperature dependence of superfluid density; (ii) deep in the superconducting state the quasiparticle scattering rate Gamma similar to T-3; and (iii) no BCS coherence peak is observed in the quasiparticle conductivity. Above T-c, the Kadowaki-Woods ratio and the temperature dependence of the in-plane conductivity show that the normal state is a Fermi liquid below similar or equal to 23 K, yet resilient quasiparticles dominate the transport up to similar or equal to 50 K

    Surface plasmon-polariton mediated emission from phosphorescent dendrimer light-emitting diodes

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    Copyright © 2006 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Applied Physics Letters 88 (2006) and may be found at http://link.aip.org/link/?APPLAB/88/161105/1We present experimental results showing electroluminescence from a dendrimer based organic light-emitting diode (OLED) mediated via surface plasmon polariton (SPP) modes. A combination of angle dependent electroluminescence, photoluminescence, and reflectance measurements is used to identify emission originating from the guided modes of the device. It is found that the SPP modes, which are usually nonradiative, are coupled to light by a wavelength scale periodic microstructure. It is demonstrated that the necessary microstructure can be readily fabricated by solvent-assisted micromoulding. Our results indicate that such an approach may offer a means to increase the efficiency of dendrimer based OLEDs

    An amphitropic cAMP-binding protein in yeast mitochondria

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    ABSTRACT: We describe the first example of a mitochondrial protein with a covalently attached phos-phatidylinositol moiety acting as a membrane anchor. The protein can be metabolically labeled with both stearic acid and inositol. The stearic acid label is removed by phospholipase D whereupon the protein with the retained inositol label is released from the membrane. This protein is a cAMP receptor of the yeast Saccharomyces cereuisiae and tightly associated with the inner mitochondrial membrane. However, it is converted into a soluble form during incubation of isolated mitochondria with Ca2+ and phospholipid (or lipid derivatives). This transition requires the action of a proteinaceous, N-ethylmaleimide-sensitive component of the intermembrane space and is accompanied by a decrease in the lipophilicity of the cAMP receptor. We propose that the component of the intermembrane space triggers the amphitropic behavior of the mitochondrial lipid-modified CAMP-binding protein through a phospholipase activity. Only in recent years specific fatty acids have been recog-nized to play important roles in the association of proteins with membranes. Both noncovalent and covalent interactions be-tween fatty acids and proteins have been reported. Among the latter are GTP-binding proteins (Molenaar et al., 1988)
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