90 research outputs found

    k-Dirac operator and parabolic geometries

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    The principal group of a Klein geometry has canonical left action on the homogeneous space of the geometry and this action induces action on the spaces of sections of vector bundles over the homogeneous space. This paper is about construction of differential operators invariant with respect to the induced action of the principal group of a particular type of parabolic geometry. These operators form sequences which are related to the minimal resolutions of the k-Dirac operators studied in Clifford analysis

    Nonlinear optical materials formed by push-pull (bi)thiophene derivatives functionalized with di(tri)cyanovinyl acceptor groups

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    Studies of the second-order nonlinear optical susceptibilities of six NLOphores bearing di(tri)cyanovinyl acceptor groups linked to (bi)thiophene heterocyclic donor systems were performed for the first time in polymethyl methacrylate (PMMA) matrices with a 1064 nm laser working in the 20 ns time pulse regime. Absorption spectra and DFT calculations were also performed. This multidisciplinary study showed that modulation of the optical (linear and nonlinear) properties can be achieved by increasing the length of the -conjugated heterocyclic system (thiophene vs. bithiophene), the strength of the electron donor groups (HMeO/EtOEt2N) as well as the strength of the electron acceptor moieties (DCV vs. TCV, two vs. three electron withdrawing cyano groups). Due to the relatively high second-order susceptibilities (0.08 to 6.45 pm/V), the studied push-pull chromophores can be denote as very potent NLOphores.Fundação para a Ciência e a Tecnologia (FCT

    Preclinical electrogastrography in experimental pigs

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    Surface electrogastrography (EGG) is a non-invasive means of recording gastric myoelectric activity or slow waves from cutaneous leads placed over the stomach. This paper provides a comprehensive review of preclinical EGG. Our group recently set up and worked out the methods for EGG in experimental pigs. We gained our initial experience in the use of EGG in assessment of porcine gastric myoelectric activity after volume challenge and after intragastric administration of itopride and erythromycin. The mean dominant frequency in pigs is comparable with that found in humans. EGG in experimental pigs is feasible. Experimental EGG is an important basis for further preclinical projects in pharmacology and toxicology

    Introductory clifford analysis

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    In this chapter an introduction is given to Clifford analysis and the underlying Clifford algebras. The functions under consideration are defined on Euclidean space and take values in the universal real or complex Clifford algebra, the structure and properties of which are also recalled in detail. The function theory is centered around the notion of a monogenic function, which is a null solution of a generalized Cauchy–Riemann operator, which is rotation invariant and factorizes the Laplace operator. In this way, Clifford analysis may be considered as both a generalization to higher dimension of the theory of holomorphic functions in the complex plane and a refinement of classical harmonic analysis. A notion of monogenicity may also be associated with the vectorial part of the Cauchy–Riemann operator, which is called the Dirac operator; some attention is paid to the intimate relation between both notions. Since a product of monogenic functions is, in general, no longer monogenic, it is crucial to possess some tools for generating monogenic functions: such tools are provided by Fueter’s theorem on one hand and the Cauchy–Kovalevskaya extension theorem on the other hand. A corner stone in this function theory is the Cauchy integral formula for representation of a monogenic function in the interior of its domain of monogenicity. Starting from this representation formula and related integral formulae, it is possible to consider integral transforms such as Cauchy, Hilbert, and Radon transforms, which are important both within the theoretical framework and in view of possible applications

    Body indices and basic vital signs in Helicobacter pylori positive and negative persons

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    It has been hypothesized that Helicobacter pylori (Hp) infection may contribute to reduced stature, risk of hypertension or obesity. The aim was to evaluate body indices in Hp positive and negative persons. A total of 2436 subjects (4–100 years old) were tested for Hp status by 13Curea breath test. Data on height and weight were collected for 84%, and blood pressure for 80% of the study subjects. The prevalence of Hp infection was 41.6%. The odds ratio for a 10-year increase in age was 1.21 (95% CI 1.17–1.25, p-value <0.001). Statistically significant negative association of Hp positivity with body height was most pronounced in the younger age groups, while a positive association of Hp positivity with body mass index was only seen in those aged 15+ years. There was a negative effect of Hp positivity on systolic and diastolic blood pressure in subjects below 25 and a relatively strong positive effect on blood pressure in subjects over 65 years. Residual confounding by social characteristics as a possible explanation for the associations of Hp positivity with height and blood pressure cannot be excluded. Unmeasured factors related to social and family environment may cause the apparent association between Hp positivity and children’s growth and blood pressure

    Excitační/detekční energií kontrolovaná anizotropní dynamika u kyan-substituovaných tripodálních molekul.

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    In the present work, the photophysical properties of two series of asymmetrical tri-podal molecules are studied, in order to determine the dependence of energy localization/delocalization phenomena on excitation and detection wavelength, by means of steady state, femtosecond time-resolved fluorescence and anisotropy spectroscopy. The molecules bear triphenylamine as an electron donating core and an acetylenic or olefinic pi-conjugated bridge. At the periphery, they are substituted by no, one, two or three -CN groups used as electron acceptors. Thus, the compounds with only one or two -CN groups are asymmetrically substituted. As a comparison, the photophysics of their dipolar and quadrupolar analogues is also presented. The steady state absorption spectra of the asymmetrical tri-podal compounds exhibit a broadening and a low energy shoulder due to the splitting of the excited states. The fluorescence spectra are more red-shifted in the tri-podal molecules with a single -CN group, providing the first evidence of its mostly dipolar nature. Time-resolved anisotropy measurements by using different excitation and detection wavelengths provide clear evidence that the asymmetrical tri-podal molecules with one or two -CN groups behave like octupolar molecules upon high-energy excitation (the initial anisotropy is found 0.1-0.15), while upon low-energy excitation they reveal a behavior expected for linear dipolar or V-shaped quadrupolar molecules (the initial anisotropy is very close to 0.4 and 0.17, respectively). The symmetrical tri-podal compounds with no or three cyano groups, exhibit an anisotropy depolarization time of 2.5 ps attributed to energy hopping. The amplitude of this energy hopping component is wavelength dependent and increases as the excitation is shifted towards the long wavelength edge.V této práci jsou studovány fotofyzikální vlastnosti dvou sérií asymetrických tripodálních molekul za účelem stanovení závislosti lokalizační/delokalizační energie na excitační a detekční vlnové délce pomocí fluorescenčních technik a femtosekundové anizotropní spektroskopie

    Imaging of Magnetic Domains and Domain Walls in Spherical Fe-Si Powder Using Magnetic Force Microscopy

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    The commercial Fe-Si powder, produced by Högänes Corporation, represents promising soft magnetic material for technological applications. The powder consists of spherical particles with diameter up to 150 μm. Internal microstructure of the powder is formed by grains of diameter of about 30 μm. Each separate grain has a random orientation of the easy magnetization axis and is sufficiently large to split into several magnetic domains. A comparative study of the atomic force microscopy (AFM) topography and the corresponding magnetic force microscopy (MFM) images was employed in order to examine the correlation between the grain size, boundaries of grains and characterization of the magnetic domains, which gives us an important knowledge about possible behavior of particles under the influence of the external magnetic field and further utilization of the spherical Fe-Si particles in electrotechnical industry. The grain size and the crystallographic orientation of grains were analyzed by the electron backscattering diffraction (EBSD) technique

    Ecological and evolutionary significance of genomic GC content diversity in monocots.

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    Genomic DNA base composition (GC content) is predicted to significantly affect genome functioning and species ecology. Although several hypotheses have been put forward to address the biological impact of GC content variation in microbial and vertebrate organisms, the biological significance of GC content diversity in plants remains unclear because of a lack of sufficiently robust genomic data. Using flow cytometry, we report genomic GC contents for 239 species representing 70 of 78 monocot families and compare them with genomic characters, a suite of life history traits and climatic niche data using phylogeny-based statistics. GC content of monocots varied between 33.6% and 48.9%, with several groups exceeding the GC content known for any other vascular plant group, highlighting their unusual genome architecture and organization. GC content showed a quadratic relationship with genome size, with the decreases in GC content in larger genomes possibly being a consequence of the higher biochemical costs of GC base synthesis. Dramatic decreases in GC content were observed in species with holocentric chromosomes, whereas increased GC content was documented in species able to grow in seasonally cold and/or dry climates, possibly indicating an advantage of GC-rich DNA during cell freezing and desiccation. We also show that genomic adaptations associated with changing GC content might have played a significant role in the evolution of the Earth’s contemporary biota, such as the rise of grass-dominated biomes during the mid-Tertiary. One of the major selective advantages of GC-rich DNA is hypothesized to be facilitating more complex gene regulation
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