Superconductivity suppression and peak resistivity enhancement for thin crystals of kappa-(BEDT-TTF)(2)Cu(SCN)(2)

Thick (100-130 mu m) crystals of kappa-(BEDT-TTF)2Cu(SCN)2 show maximum of p(T) dependence at 100K (2.52.8 times larger than their resistivity at 298K) and reproducible Tc (onset) at 10.4K. Thin (25 mu m) crystals attached to a SiO2 wafer demonstrated profound enhancement of peak resistivity near 100K (up to 3000 times greater than their room temperature resistivity). Further, superconductivity is absent in the thin films. We argue that these effects are due to negative pressure (about -2.5kbar at 100?K) caused by the large difference in the thermal expansion coefficients of SiO2 and kappa-(BEDT-TTF)2Cu(SCN)2. Thin single crystal on Au patterned Si/SiO2 wafer

Structure and properties of the stable two-dimensional conducting polymer Mg5C60

We present a study on the structural, spectroscopic, conducting, and magnetic properties of Mg5C60, which is a two-dimensional (2D) fulleride polymer. The polymer phase is stable up to the exceptionally high temperature of 823 K. The infrared and Raman studies suggest the formation of single bonds between the fulleride ions and possibly Mg-C-60 covalent bonds. Mg5C60 is a metal at ambient temperature, as shown by electron spin resonance and microwave conductivity measurements. The smooth transition from a metallic to a paramagnetic insulator state below 200 K is attributed to Anderson localization driven by structural disorder

Microwave dielectric study of spin-Peierls and charge ordering transitions in (TMTTF)2_2PF6_6 salts

We report a study of the 16.5 GHz dielectric function of hydrogenated and deuterated organic salts (TMTTF)$_2$PF$_6$. The temperature behavior of the dielectric function is consistent with short-range polar order whose relaxation time decreases rapidly below the charge ordering temperature. If this transition has more a relaxor character in the hydrogenated salt, charge ordering is strengthened in the deuterated one where the transition temperature has increased by more than thirty percent. Anomalies in the dielectric function are also observed in the spin-Peierls ground state revealing some intricate lattice effects in a temperature range where both phases coexist. The variation of the spin-Peierls ordering temperature under magnetic field appears to follow a mean-field prediction despite the presence of spin-Peierls fluctuations over a very wide temperature range in the charge ordered state of these salts.Comment: 7 pages, 6 figure

Transport properties and the anisotropy of Ba_{1-x}K_xFe_2As_2 single crystals in normal and superconducting states

The transport and superconducting properties of Ba_{1-x}K_xFe_2As_2 single crystals with T_c = 31 K were studied. Both in-plane and out-of plane resistivity was measured by modified Montgomery method. The in-plane resistivity for all studied samples, obtained in the course of the same synthesis, is almost the same, unlike to the out-of plane resistivity, which differ considerably. We have found that the resistivity anisotropy \gamma=\rho_c /\rho_{ab} is almost temperature independent and lies in the range 10-30 for different samples. This, probably, indicates on the extrinsic nature of high out-of-plane resistivity, which may appear due to the presence of the flat defects along Fe-As layers in the samples. This statement is supported by comparatively small effective mass anisotropy, obtained from the upper critical field measurements, and from the observation of the so-called "Friedel transition", which indicates on the existence of some disorder in the samples in c-direction.Comment: 5 pages, 5 figure

Indications of coherence-incoherence crossover in layered transport

For many layered metals the temperature dependence of the interlayer resistance has a different behavior than the intralayer resistance. In order to better understand interlayer transport we consider a concrete model which exhibits this behavior. A small polaron model is used to illustrate how the interlayer transport is related to the coherence of quasi-particles within the layers. Explicit results are given for the electron spectral function, interlayer optical conductivity and the interlayer magnetoresistance. All these quantities have two contributions: one coherent (dominant at low temperatures) and one incoherent (dominant at high temperatures).Comment: 6 pages, 4 figures, REVTEX

Magnetothemopower study of quasi two-dimensional organic conductor α\alpha-(BEDT-TTF)2_2KHg(SCN)4_4

We have used a low-frequency magneto-thermopower (MTEP) method to probe the high magnetic field ground state behavior of $\alpha$-(BEDT-TTF)$_2$KHg(SCN)$_4$ along all three principal crystallographic axes at low temperatures. The thermopower tensor coefficients ($S_{xx}, S_{yx}$ and $S_{zz}$) have been measured to 30 T, beyond the anomalous low temperature, field-induced transition at 22.5 T. We find a significant anisotropy in the MTEP signal, and also observe large quantum oscillations associated with the de Haas - van Alphen effect. The anisotropy indicates that the ground state properties are clearly driven by mechanisms that occur along specific directions for the in-plane electronic structure. Both transverse and longitudinal magnetothermopower show asymptotic behavior in field, which can be explained in terms of magnetic breakdown of compensated closed orbits.Comment: 9 pages, 10 figure

Anomalous behaviour of the in-plane electrical conductivity of the layered superconductor κ\kappa-(BEDT-TTF)2_2Cu(NCS)2_2

The quasiparticle scattering rates in high-quality crystals of the quasi-two-dimensional superconductor $\kappa$-(BEDT-TTF)$_2$Cu(NCS)$_2$ ~are studied using the Shubnikov-de Haas effect and MHz penetration-depth experiments. There is strong evidence that the broadening of the Landau-levels is primarily caused by spatial inhomogeneities, indicating a quasiparticle lifetime for the Landau states $\gg 3$ ps. In contrast to the predictions of Fermi-liquid theory, the scattering time derived from the intralayer conductivity is found to be much shorter ($0.14-0.56$ ps)