Laboratory von H\'amos X-ray Spectroscopy for Routine Sample Characterization

High energy resolution, hard X-ray spectroscopies are powerful element selective probes of the electronic and local structure of matter, with diverse applications in chemistry, physics, biology and materials science. The routine application of these techniques is hindered by the complicated and slow access to synchrotron radiation facilities. Here we propose a new, economic, easily operated laboratory high resolution von H\'amos type X-ray spectrometer, which offers rapid transmission experiments for X-ray absorption, and is also capable of recording X-ray emission spectra. The use of a cylindrical analyzer crystal and a position sensitive detector enabled us to build a maintenance free, flexible setup with low operational costs, while delivering synchrotron grade signal to noise measurements in reasonable acquisition times. We demonstrate the proof of principle and give examples for both measurement types. Finally, tracking of a several day long chemical transformation, a case better suited for laboratory than synchrotron investigation, is also presented

A star-forming galaxy at z= 5.78 in the Chandra Deep Field South

We report the discovery of a luminous z = 5.78 star-forming galaxy in the Chandra Deep Field South. This galaxy was selected as an ‘i-drop’ from the GOODS public survey imaging with the Hubble Space Telescope/Advanced Camera for Surveys (object 3 in the work of Stanway, Bunker & McMahon 2003). The large colour of (i′−z′)AB = 1.6 indicated a spectral break consistent with the Lyman α forest absorption shortward of Lyman α at z≈ 6. The galaxy is very compact (marginally resolved with ACS with a half-light radius of 0.08 arcsec, so rhl 5. Our spectroscopic redshift for this object confirms the validity of the i′-drop technique of Stanway et al. to select star-forming galaxies atz≈ 6

Construction and measurements of a vacuum-swing-adsorption radon-mitigation system

Long-lived alpha and beta emitters in the $^{222}$Rn decay chain on (and near) detector surfaces may be the limiting background in many experiments attempting to detect dark matter or neutrinoless double-beta decay, and in screening detectors. In order to reduce backgrounds from radon-daughter plate-out onto the wires of the BetaCage during its assembly, an ultra-low-radon cleanroom is being commissioned at Syracuse University using a vacuum-swing-adsorption radon-mitigation system. The radon filter shows ~20$\times$ reduction at its output, from 7.47$\pm$0.56 to 0.37$\pm$0.12 Bq/m$^3$, and the cleanroom radon activity meets project requirements, with a lowest achieved value consistent with that of the filter, and levels consistently < 2 Bq/m$^3$.Comment: 5 pages, 3 figures, Proceedings of Low Radioactivity Techniques (LRT) 2013, Gran Sasso, Italy, April 10-12, 201

XAFS Debye-Waller factors for deformed hemes and metal substituted hemes

We present an efficient and accurate method for calculating XAFS Debye-Waller factors for deformed active sites of hemoproteins and metal substituted hemes. Based on the Normal Coordinate Structural Decomposition scheme, the deformation of the porphyrin macrocycle is expressed as a linear combination of the normal modes of the planar species. In our approach, we identify the modes that contribute most to the deformation. Small metal-porphyrin structures which match the macrocycle structural deformation of the deformed hemoprotein site are used to calculate the Debye-Waller parameters at sample\u27s temperature. The Debye-Waller factors are directly obtained by calculating the normal mode spectrum of the corresponding metal-porphyrin structure using Density Functional Theory. Our method is tested on Ni-tetraadamantyl porphyrin and cytochrome c structures with more than 500 available scattering paths. © 2009 IOP Publishing Ltd

Longitudinal magnetic excitations in classical spin systems

Using spin dynamics simulations we predict the splitting of the longitudinal spin wave peak in all antiferromagnets with single site anisotropy into two peaks separated by twice the energy gap at the Brillouin zone center. This phenomenon has yet to be observed experimentally but can be easily investigated through neutron scattering experiments on MnF$_2$ and FeF$_2$. We have also determined that for all classical Heisenberg models the longitudinal propagative excitations are entirely multiple spin-wave in nature.Comment: four pages three figures, the last two postscript files are two parts of the third figur

Notations and conventions in molecular spectroscopy: part 1. General spectroscopic notation

The field of Molecular Spectroscopy was surveyed in order to determine a set of conventions and symbols which are in common use in the spectroscopic literature. This document, which is Part I in a series, establishes the notations and conventions used for general spectroscopic notations and deals with quantum mechanics, quantum numbers (vibrational states, angular momentum and energy levels), spectroscopic transitions, and miscellaneous notations (e.g. spectroscopic terms). Further parts will follow, dealing inter alia with symmetry notation, permutation and permutation-inversion symmetry notation, vibration-rotation spectroscopy and electronic spectroscopy

Hydrogeology and stratigraphy of the Dakota formation in Northwest Iowa

https://ir.uiowa.edu/igs_wsb/1012/thumbnail.jp

Cold guided beams of water isotopologs

Electrostatic velocity filtering and guiding is an established technique to produce high fluxes of cold polar molecules. In this paper we clarify different aspects of this technique by comparing experiments to detailed calculations. In the experiment, we produce cold guided beams of the three water isotopologs H2O, D2O and HDO. Their different rotational constants and orientations of electric dipole moments lead to remarkably different Stark shift properties, despite the molecules being very similar in a chemical sense. Therefore, the signals of the guided water isotopologs differ on an absolute scale and also exhibit characteristic electrode voltage dependencies. We find excellent agreement between the relative guided fractions and voltage dependencies of the investigated isotopologs and predictions made by our theoretical model of electrostatic velocity filtering.Comment: 14 pages, 13 figures; small changes to the text, updated reference