Effect of sintering temperature and heat treatment on electrical properties of indium oxide based ceramics

Indium oxide based ceramics with bismuth oxide addition were sintered in air in the temperature range 800-1300 ºC. Current-voltage characteristics of In2O3-Bi2O3 ceramics sintered at different temperatures are weakly nonlinear. After an additional heat treatment in air at about 200 ºC samples sintered at a temperature within the narrow range of about 1050-1100 ºC exhibit a current-limiting effect accompanied by low-frequency current oscillations. It is shown that the observed electrical properties are controlled by the grain-boundary barriers and the heat treatment in air at 200 ºC leads to the decrease in the barrier height. Electrical measurements, scanning electron microscopy and X-ray photoelectron spectroscopy results suggest that the current-limiting effect observed in In2O3-Bi2O3 can be explained in terms of the modified barrier model proposed earlier for the explanation of similar effect in In2O3-SrO ceramics

Sparkling touchdown

Diamond-like carbon combines the properties of graphite and diamond to provide an inert, hard wearing, low-friction, thin-film barrier coating that can be deposited uniformly over a large area. Medical and electronic applications – including surgical implants and hard-disk heads - currently benefit from this versatile material, which has recently emerged into the limelight on the latest razor blades, and for high-performance manufacturing applications. Researchers at Brunel University and Hawker Pacific Aerospace, collaborating as part of an EPSRC sponsored Environmental Technology Engineering Doctorate (EngD) scheme, are investigating diamond-like carbon as a hard wearing, anti-corrosion coating on aircraft components, as an alternative to current techniques that rely on heavy metals

Structure and tribological performance of diamond-like carbon based coatings for aerospace component processing

Copyright @ 2009 The Surface Science Society of JapanThis work examines diamond-like carbon (DLC) coatings deposited by plasma enhanced chemical vapour deposition (PECVD) as an environmentally friendly alternative to chromium plating in restoration of worn or damaged aircraft components. DLC coatings offer superior mechanical properties; however, high internal stresses and poor adhesion can prevent the deposition of thick films. This work examines a series of layered structures based on epoxy-resin interlayers with DLC applied as a surface film. Wear testing and examination with scanning electron microscopy and atomic force microscopy lead to the development of an optimum DLC/epoxy system with wear characteristics superior to those of chromium-plated steel. This new coating system has a great potential in restoring aircraft components in a more efficient and environmentally friendly manner.This work is funded via the Engineering and Physical Sciences Research Council (EPSRC)

Electronic properties of SnO2-based ceramics with double function of varistor and humidity sensor

This is the post-print version of the article. The official published version can be obtained from the link below - Copyright @ 2010 AD-Tech.Tin dioxide based varistor ceramics SnO2-Co3O4-Nb2O5-Cr2O3-xCuO (x=0; 0.05; 0.1 and 0.5) were made and their electrical properties were studied. The highest nonlinearity coefficient and electric field (at current density 10-3 A cm-2) were obtained for 0.1 mol.% CuO addition. It was observed that low-field electrical conductivity is increased with relative humidity, therefore, materials obtained exhibit double function of varistor and humidity sensor. The highest humidity sensitivity coefficient is found for SnO2-Co3O4-Nb2O5-Cr2O3 ceramics (without CuO). Observed varistor and humidity-sensitive properties are explained in the frames of grain-boundary double Schottky barrier concept as a decrease of the barrier height with electric field or relative humidity. Using suggested simple theory and data obtained on isothermal capacitance relaxation, the energy of the grain-boundary monoenergetic trapping states were estimated. These values are less than found for activation energy of electrical conduction (as a measure of the barrier height). These observations confirm the barrier concept.This work is funded by the Royal Society, United Kingdom (2007R1/R26999)

Energy Efficiency Improvements in Dry Drilling with Optimised Diamond-Like Carbon Coating

We demonstrate enhancements of performance and energy efficiency of cutting tools by deposition of diamond-like carbon (DLC) coatings on machine parts. DLC was deposited on steel drill bits, using plasma enhanced chemical vapour deposition (PECVD) with the acetylene precursor diluted with argon, to produce a surface with low friction and low wear rate. Drill bit performance in dry drilling of aluminium was quantified by analysis of power consumption and swarf flow. Optimised deposition conditions produced drill bits with greatly enhanced performance over uncoated drill bits, showing a 25% reduction in swarf clogging, a 36% reduction in power consumption and a greater than five-fold increase in lifetime. Surface analysis with scanning electron microscopy shows that DLC coated drills exhibit much lower aluminium build up on the trailing shank of the drill, enhancing the anti-adhering properties of the drill and reducing heat generation during operation, resulting in the observed improvements in efficiency. Variation of drilling efficiency with argon dilution of precursor is related to changes in the microstructure of the DLC coating

Current limiting and negative differential resistance in indium oxide based ceramics

Indium oxide based ceramics with bismuth oxide addition were sintered in air in the temperature range 800-1300 ºC. Current-voltage characteristics of In2O3-Bi2O3 ceramics sintered at different temperatures are weakly nonlinear. After an additional heat treatment in air at about 200 ºC samples sintered at a temperature within the narrow range of about 1050-1100 ºC exhibit a current-limiting effect accompanied by low-frequency current oscillations. It is shown that the observed electrical properties are controlled by the grain-boundary barriers and the heat treatment in air at 200 ºC leads to the decrease in the barrier height. Electrical measurements, scanning electron microscopy and X-ray photoelectron spectroscopy results suggest that the current-limiting effect observed in In2O3-Bi2O3 may be explained in terms of a modified barrier model; the observed current-limiting effect is the result of an increase of barrier height with increasing electric field, due to additional oxygen absorption. It is found that In2O3-Bi2O3-Co3O4-Cr2O3 ceramic exhibits current-voltage characteristics with negative differential resistance due to Joule micro heating.This study was performed in part in the frames of the project SEP-2003-C02-42821, CONACYT, México. Funding from the Royal Society, United Kingdom (2007R1/R26999) is gratefully acknowledged

Diamond-like carbon/epoxy low-friction coatings to replace electroplated chromium

A series of layered structures based on epoxy resins coated with diamond-like carbon (DLC) are examined as potential replacements for electroplated chromium in aerospace applications. Diamond-like carbon coatings can offer superior mechanical properties and tribological performance; however, in some applications high internal stresses and poor adhesion limit their practical use. A DLC/epoxy system is developed and studied utilising pin-on-disk testing, scanning electron microscopy and atomic force microscopy, resulting in an optimum system with characteristics superior to those of chromium-plated steel. This new coating system has a great potential in restoring worn or damaged aircraft components, without the health and environmental issues associated with chromium plating. The components can be rebuilt and improved over the original condition thus allowing an extension of service life and eliminating the need for costly replacements

Diamond-like carbon coating of alternative metal alloys for medical and surgical applications

The effectiveness of a plasma-deposited, diamond-like carbon (DLC) coating on aluminium alloy based surgical instruments is investigated. Surgical instruments must satisfy a number of important criteria including biocompatibility, functional performance, sterility and cleanability, structural integrity, and fatigue resistance. The integrity of the DLC layer and the diffusion barrier properties are of paramount importance due to biocompatibility considerations of the underlying aluminium metal. We investigate optimisation of the coating with incorporation of silicon and variation in negative self bias, and highlight the design and manufacture of a lightweight laparoscopic assist instrument from aluminium alloy coated with diamond-like carbon, which has been used successfully in the clinical environment to improve operations such as cholecystectomy (gall bladder removal) and exploratory techniques for the diagnosis of cancer